Methyl 2-bromomethyl-3-methoxybenzoate
- CAS No.
- 71887-28-0
- Chemical Name:
- Methyl 2-bromomethyl-3-methoxybenzoate
- Synonyms
- 2-bromethyl-3-methoxymethyl benzoate;METHYL 2-BROMOMETHYL-3-METHOXY-BENZOATE;2-Bromomethyl-3-methoxybenzoic acid methyl ester;Benzoic acid, 2-(bromomethyl)-3-methoxy-, methyl ester
- CBNumber:
- CB6767264
- Molecular Formula:
- C10H11BrO3
- Molecular Weight:
- 259.1
- MDL Number:
- MFCD04114320
- MOL File:
- 71887-28-0.mol
- MSDS File:
- SDS
- TDS File:
- TDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H227 |
| Precautionary statements | P501-P210-P280-P370+P378-P403+P235 |
Methyl 2-bromomethyl-3-methoxybenzoate price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Matrix Scientific | 300678 | Methyl 2-(bromomethyl)-3-methoxybenzoate | 71887-28-0 | 250.00mg | $25 | 2026-05-19 | Buy |
| Matrix Scientific | 300678 | Methyl 2-(bromomethyl)-3-methoxybenzoate | 71887-28-0 | 1.00g | $62 | 2026-05-19 | Buy |
| Matrix Scientific | 300678 | Methyl 2-(bromomethyl)-3-methoxybenzoate | 71887-28-0 | 5.00g | $239 | 2026-05-19 | Buy |
| Synthonix | M52655 | Methyl 2-(bromomethyl)-3-methoxybenzoate 95+% | 71887-28-0 | 250mg | $54 | 2026-05-06 | Buy |
| Synthonix | M52655 | Methyl 2-(bromomethyl)-3-methoxybenzoate 95+% | 71887-28-0 | 1g | $60 | 2026-05-06 | Buy |
Methyl 2-bromomethyl-3-methoxybenzoate Chemical Properties,Uses,Production
Synthesis
42981-93-1
71887-28-0
General procedure for the synthesis of methyl 2-bromomethyl-3-methoxybenzoate from methyl 3-methoxy-2-methylbenzoate: to a solution of CHCl3 (2-5 mL/mmol) or CCl4 (5 mL/mmol) containing methyl 3-methoxy-2-methylbenzoate (1.00 eq.), N-bromosuccinimide (NBS, 1.10- 2.20 eq.) and azobisisobutyronitrile (AIBN, 0.02-0.04 eq.). The reaction mixture was heated to reflux for 2-22 hours and subsequently cooled to room temperature. Upon completion of the reaction, the solvent is removed by evaporation under reduced pressure if CHCl3 is used as solvent, or by distillation if CCl4 is used, to give the target product methyl 2-bromomethyl-3-methoxybenzoate. Precautions: CHCl3 and CCl4 are highly toxic and carcinogenic, protective gloves should be worn and the operation should be carried out in a fume hood.
References
[1] Tetrahedron, 2018, vol. 74, # 2, p. 224 - 239
[2] Journal of Organic Chemistry, 1980, vol. 45, # 1, p. 12 - 15
[3] Patent: WO2004/26875, 2004, A1. Location in patent: Page 38
[4] Patent: US2004/106791, 2004, A1. Location in patent: Page 9
[5] Chinese Chemical Letters, 2012, vol. 23, # 1, p. 9 - 12
Methyl 2-bromomethyl-3-methoxybenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 2-bromomethyl-3-methoxybenzoate Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
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| Wuhan graphe Pharmaceutical Technology Co., Ltd. | 18995639250 | huangxq@graphe-tech.com | China | 500 | 55 |
| SHANGHAI FDC-CHEMICAL CO.,LTD | 021-61469567 13774476675 | sales@fdc-chemical.com | China | 10000 | 58 |
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