Methyl 2-bromomethyl-3-methoxybenzoate
- CAS No.
- 71887-28-0
- Chemical Name:
- Methyl 2-bromomethyl-3-methoxybenzoate
- Synonyms
- METHYL 2-BROMOMETHYL-3-METHOXY-BENZOATE;2-Bromomethyl-3-methoxybenzoic acid methyl ester;Benzoic acid, 2-(bromomethyl)-3-methoxy-, methyl ester
- CBNumber:
- CB6767264
- Molecular Formula:
- C10H11BrO3
- Molecular Weight:
- 259.1
- MDL Number:
- MFCD04114320
- MOL File:
- 71887-28-0.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Methyl2-bromomethyl-3-methoxybenzoate 97% | J15272 | 1g | $50 |
| Methyl2-bromomethyl-3-methoxybenzoate | 7381AH | 250mg | $123 |
| Methyl2-bromomethyl-3-methoxybenzoate 97% | J15272 | 5g | $150 |
| Methyl2-bromomethyl-3-methoxybenzoate | 7381AH | 1g | $213 |
| METHYL-2-BROMOMETHYL-3-METHOXY-BENZOATE 98.00% | HCH0142425 | 5MG | $502.73 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H227 |
| Precautionary statements | P501-P210-P280-P370+P378-P403+P235 |
Methyl 2-bromomethyl-3-methoxybenzoate price More Price(14)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Frontier Specialty Chemicals | J15272 | Methyl2-bromomethyl-3-methoxybenzoate 97% | 71887-28-0 | 1g | $50 | 2021-12-16 | Buy |
| AK Scientific | 7381AH | Methyl2-bromomethyl-3-methoxybenzoate | 71887-28-0 | 250mg | $123 | 2021-12-16 | Buy |
| Frontier Specialty Chemicals | J15272 | Methyl2-bromomethyl-3-methoxybenzoate 97% | 71887-28-0 | 5g | $150 | 2021-12-16 | Buy |
| AK Scientific | 7381AH | Methyl2-bromomethyl-3-methoxybenzoate | 71887-28-0 | 1g | $213 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | HCH0142425 | METHYL-2-BROMOMETHYL-3-METHOXY-BENZOATE 98.00% | 71887-28-0 | 5MG | $502.73 | 2021-12-16 | Buy |
Methyl 2-bromomethyl-3-methoxybenzoate Chemical Properties,Uses,Production
Synthesis
42981-93-1
71887-28-0
General procedure for the synthesis of methyl 2-bromomethyl-3-methoxybenzoate from methyl 3-methoxy-2-methylbenzoate: to a solution of CHCl3 (2-5 mL/mmol) or CCl4 (5 mL/mmol) containing methyl 3-methoxy-2-methylbenzoate (1.00 eq.), N-bromosuccinimide (NBS, 1.10- 2.20 eq.) and azobisisobutyronitrile (AIBN, 0.02-0.04 eq.). The reaction mixture was heated to reflux for 2-22 hours and subsequently cooled to room temperature. Upon completion of the reaction, the solvent is removed by evaporation under reduced pressure if CHCl3 is used as solvent, or by distillation if CCl4 is used, to give the target product methyl 2-bromomethyl-3-methoxybenzoate. Precautions: CHCl3 and CCl4 are highly toxic and carcinogenic, protective gloves should be worn and the operation should be carried out in a fume hood.
References
[1] Tetrahedron, 2018, vol. 74, # 2, p. 224 - 239
[2] Journal of Organic Chemistry, 1980, vol. 45, # 1, p. 12 - 15
[3] Patent: WO2004/26875, 2004, A1. Location in patent: Page 38
[4] Patent: US2004/106791, 2004, A1. Location in patent: Page 9
[5] Chinese Chemical Letters, 2012, vol. 23, # 1, p. 9 - 12
Methyl 2-bromomethyl-3-methoxybenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 2-bromomethyl-3-methoxybenzoate Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
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| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30229 | 58 |
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| Nanjing Chalf-Pharm Technology Co., Ltd. | 025-57018978 18251899859 | sales@chalf-pharm.com | China | 5669 | 50 |
