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Methyl 3-(bromomethyl)benzoate

Methyl 3-(bromomethyl)benzoate Structure
Methyl 3-(bromomethyl)benzoate structure
CAS No.
1129-28-8
Chemical Name:
Methyl 3-(bromomethyl)benzoate
Synonyms
TIMTEC-BB SBB005793;METHYL ALPHA-BROMO-M-TOLUATE;M-CARBOMETHOXYBENZYL BROMIDE;3-CARBOMETHOXYBENZYL BROMIDE;Methyl 3-(bromomethyl)benzoat;METHYL 3-(BROMOMETHYL)BENZOATE;Methyle3-(bromomethyl)benzoate;Methyl 3-aMino-4-fluorobezoate;Methyl m-(Bromomethyl)benzoate;3-(BROMOMETHYL)PHENYLACETICACID
CBNumber:
CB0331184
Molecular Formula:
C9H9BrO2
Molecular Weight:
229.07
MDL Number:
MFCD00051437
MOL File:
1129-28-8.mol
MSDS File:
SDS
Last updated:2026-06-04 16:00:12
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Methyl 3-(bromomethyl)benzoate Properties

Melting point 46-47 °C(lit.)
Boiling point 112-114 °C3 mm Hg(lit.)
Density 1,47 g/cm3
Flash point 115°C/0.8mm
storage temp. 2-8°C
form Crystals or Crystalline Powder
color White
Water Solubility Slightly soluble in water.
BRN 638569
InChI InChI=1S/C9H9BrO2/c1-12-9(11)8-4-2-3-7(5-8)6-10/h2-5H,6H2,1H3
InChIKey YUHSMQQNPRLEEJ-UHFFFAOYSA-N
SMILES C(OC)(=O)C1=CC=CC(CBr)=C1
CAS DataBase Reference 1129-28-8(CAS DataBase Reference)
NIST Chemistry Reference Methyl 3-bromomethylbenzoate(1129-28-8)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H314-H317
Precautionary statements  P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338
PPE Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes  C,Xi
Risk Statements  22-34-43
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  2
F  19
Hazard Note  Irritant/Corrosive
HazardClass  8
PackingGroup  III
HS Code  29163990
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Acute Tox. 4 Oral
Skin Corr. 1B
Skin Sens. 1
REACH Registrations Inactive
Limited Quantities 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
0
3 0

Methyl 3-(bromomethyl)benzoate price More Price(59)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 648116 Methyl 3-(bromomethyl)benzoate 97% 1129-28-8 5g $58.2 2026-04-30 Buy
Sigma-Aldrich 648116 Methyl 3-(bromomethyl)benzoate 97% 1129-28-8 25g $261 2026-04-30 Buy
TCI Chemical B2224 Methyl 3-(Bromomethyl)benzoate >97.0%(GC) 1129-28-8 5g $47 2026-04-30 Buy
TCI Chemical B2224 Methyl 3-(Bromomethyl)benzoate >97.0%(GC) 1129-28-8 25g $142 2026-04-30 Buy
Usbiological 455088 Methyl 3-(Bromomethyl)benzoate 1129-28-8 1g $319 2026-06-03 Buy
Product number Packaging Price Buy
648116 5g $58.2 Buy
648116 25g $261 Buy
B2224 5g $47 Buy
B2224 25g $142 Buy
455088 1g $319 Buy

Methyl 3-(bromomethyl)benzoate Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder or crystals

Uses

Methyl 3-(bromomethyl)benzoate is used in organic synthesis of other chemicals.

Synthesis

Methyl 3-methylbenzoate

99-36-5

Methyl 3-(bromomethyl)benzoate

1129-28-8

General procedure for the synthesis of methyl 3-bromomethylbenzoate from methyl m-methylbenzoate: 30 mL of carbon tetrachloride (CCl4) and 7.9 g of methyl m-methylbenzoate were added to a dry 100 mL three-necked flask, and after dissolution, 0.23 g of AIBN (azobisisobutyronitrile) and 9.36 g of NBS (N-bromosuccinimide) were sequentially added in three additions (with an interval of about 2-3 hours). The reaction system was heated to 70°C and the color of the reaction solution was observed to change gradually from yellow to orange and finally to white. The reaction was monitored by TLC (eluent: cyclohexane/ethyl acetate = 5:1) until the reaction was almost complete. At the end of the reaction, the resulting succinimide and unreacted N-bromosuccinimide were removed by filtration. The filtrate was rotary evaporated to give 11.5 g of a yellow oily product, methyl 3-bromomethylbenzoate, in 95% yield.

References

[1] Organic and Biomolecular Chemistry, 2003, vol. 1, # 14, p. 2506 - 2511
[2] Patent: CN106146413, 2016, A. Location in patent: Paragraph 0027; 0028
[3] European Journal of Medicinal Chemistry, 2009, vol. 44, # 1, p. 7 - 17
[4] Molecules, 2016, vol. 21, # 12,
[5] Patent: WO2018/169777, 2018, A1. Location in patent: Paragraph 0227

Methyl 3-(bromomethyl)benzoate Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Carbon tetrachloride Methyl 3-methylbenzoate Petroleum ether
3-Hydroxymethyl-benzoic acid methyl ester Methanol 3-(broMoMethyl)benzoyl chloride 3-(BROMOMETHYL)BENZOIC ACID AIBN

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Preparation Products

Methyl 3-((piperidin-4-yl)methyl)benzoate 3-((1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)METHYL)BENZOIC ACID Methyl 3-(aminomethyl)benzoate hydrochloride DI-TERT-BUTYL HYDRAZODICARBOXYLATE Methyl 3-[(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl]benzoate
Methyl 3-[4-(tert-butoxycarbonylamino)piperidin-1-yl]methylbenzoate Methyl 3-[(3-Formylphenoxy)methyl]benzoate METHYL 3-(1H-1,2,4-TRIAZOL-1-YLMETHYL)BENZOATE methyl 3-((diethoxyphosphoryl)methyl)benzoate

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Methyl 3-(bromomethyl)benzoate Suppliers

Global( 294)Suppliers
Supplier Tel Email Country ProdList Advantage
Changzhou Tianrui Pharmaceutical Technology Co., Ltd. 0519-85386832 13382812559 sales@cztrchem.com China 1211 56
Hangzhou Copiore Chemical Co., Ltd. 17300981287 13757145729 sales@copiore.com China 289 58
Anhui Yongsheng Pharmaceutical Technology Co., Ltd 3307 18017383231 983544897@qq.com China 941 58
Shanghai Aoyeah Chemical Technology Co., Ltd. 021-021-64367138 15900495324 sales@aoyeahchem.com China 196 55
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 China 18187 66
Supplier Advantage
Changzhou Tianrui Pharmaceutical Technology Co., Ltd. 56
Hangzhou Copiore Chemical Co., Ltd. 58
Anhui Yongsheng Pharmaceutical Technology Co., Ltd 58
Shanghai Aoyeah Chemical Technology Co., Ltd. 55
J & K SCIENTIFIC LTD. 76
Alfa Aesar 84
TCI (Shanghai) Development Co., Ltd. 81
Energy Chemical 61
Wuhan Chemwish Technology Co., Ltd 56
Capot Chemical Co., Ltd 66

View Lastest Price from Methyl 3-(bromomethyl)benzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 3-(bromomethyl)benzoate pictures 2026-03-20 Methyl 3-(bromomethyl)benzoate
1129-28-8
 $10.00 1KG 99% 5tons Hebei Chuanghai Biotechnology Co., Ltd
Methyl 3-(bromomethyl)benzoate pictures 2025-12-24 Methyl 3-(bromomethyl)benzoate
1129-28-8
 1KG 98.0% 10 Shaanxi Dideu Medichem Co. Ltd
Methyl 3-(bromomethyl)benzoate pictures 2025-12-24 Methyl 3-(bromomethyl)benzoate
1129-28-8
 1KG 99.0% 1000MT Shaanxi Dideu Medichem Co. Ltd

Methyl 3-(bromomethyl)benzoate Spectrum

Methyl 3-(bromomethyl)benzoate(1129-28-8)MSMethyl 3-(bromomethyl)benzoate(1129-28-8)1HNMRMethyl 3-(bromomethyl)benzoate(1129-28-8)IR1Methyl 3-(bromomethyl)benzoate(1129-28-8)IR2

1129-28-8(Methyl 3-(bromomethyl)benzoate)Related Search:

Methyl 3-bromo-5-(bromomethyl)benzoate Methyl 3,4-bis(bromomethyl)benzoate 3-Bromotoluene Methyl 3-bromobenzoate 3-Bromobenzoic acid
3-(BROMOMETHYL)BENZOIC ACID METHYL 2-BROMOMETHYL BENZOATE Methyl 4-(bromomethyl)benzoate METHYL 3,3,5-TRIBROMO-OXINDOLE-7-CARBOXYLATE SALOR-INT L168661-1EA
Methyl 3-bromomethyl-4-cyanobenzoate METHYL-3-BROMOMETHYL-5-METHOXYBENZOATE Methyl 3-(bromomethyl)benzoate METHYL 3,3-DIBROMO-OXINDOLE-7-CARBOXYLATE

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Methyle3-(bromomethyl)benzoate TIMTEC-BB SBB005793 METHYL 3-(BROMOMETHYL)BENZOATE M-CARBOMETHOXYBENZYL BROMIDE METHYL ALPHA-BROMO-M-TOLUATE ALPHA-BROMO-M-TOLUIC ACID METHYL ESTER 3-(BROMOMETHYL)BENZOIC ACID METHYL ESTER 3-CARBOMETHOXYBENZYL BROMIDE Methyl 3-(bromomethyl)benzoat 3-(BROMOMETHYL)PHENYLACETICACID Methyl 3-(bromomethyl)benzoate ,97% Methyl 3-(bromomethyl)benzoate,95% Methyl 3-aMino-4-fluorobezoate Methyl 3-(broMoMethyl)benzoate, 95% 5GR 3-(Bromomethyl)benzoic Acid Methyl Ester alpha-Bromo-m-toluic Acid Methyl Ester Methyl alpha-Bromo-m-toluate Benzoic acid, 3-(broMoMethyl)-, Methyl ester Methyl m-(Bromomethyl)benzoate Methyl 3-(Bromomethyl)benzoate > Methyl 3-(bromomethyl)phenylacetate 1129-28-8 1129-28-2 Esters Organic Building Blocks Building Blocks Carbonyl Compounds BENZYL HALIDE C8 to C9 Building Blocks C8 to C9 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Esters Phenyls & Phenyl-Het Aromatic Halides (substituted)