Benzyl thiocyanate
- CAS No.
- 3012-37-1
- Chemical Name:
- Benzyl thiocyanate
- Synonyms
- Troeolin;solvat14;Solvat 14;Tropeolin;Benzylrhodonid;BENZYL RHODANIDE;Benzylthiocyanide;Beazyl thiocyanate;BENZYL THIOCYANATE;a-Thiocyanatotoluene
- CBNumber:
- CB6774554
- Molecular Formula:
- C8H7NS
- Molecular Weight:
- 149.21
- MDL Number:
- MFCD00001832
- MOL File:
- 3012-37-1.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 39-41 °C (lit.) 39-41 °C |
|---|---|
| Boiling point | 230-235 °C (lit.) |
| Density | 1.32 |
| refractive index | 1.6000 (estimate) |
| Flash point | >230 °F |
| storage temp. | Store at <= 20°C. |
| solubility | diethyl ether: soluble0.5g/10 mL, clear to very faintly turbid, colorless to almost colorless |
| form | Solid |
| color | Orange-red crystals or solid |
| Water Solubility | insoluble |
| Sensitive | Moisture Sensitive |
| BRN | 1859726 |
| InChI | 1S/C8H7NS/c9-7-10-6-8-4-2-1-3-5-8/h1-5H,6H2 |
| InChIKey | ABNDFSOIUFLJAH-UHFFFAOYSA-N |
| SMILES | N#CSCc1ccccc1 |
| CAS DataBase Reference | 3012-37-1(CAS DataBase Reference) |
| FDA UNII | YX8TAO9O90 |
| NIST Chemistry Reference | Thiocyanic acid benzyl ester(3012-37-1) |
| EPA Substance Registry System | Thiocyanic acid, phenylmethyl ester (3012-37-1) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302+H332-H314-H320-H335 | |||||||||
| Precautionary statements | P501-P260-P270-P271-P264-P280-P337+P313-P305+P351+P338-P303+P361+P353-P301+P330+P331-P363-P301+P312+P330-P304+P340+P310-P403+P233-P405 | |||||||||
| PPE | dust mask type N95 (US), Eyeshields, Gloves | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-32 | |||||||||
| Safety Statements | 13-36/37-50A | |||||||||
| RIDADR | UN 1759 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | XK8155000 | |||||||||
| TSCA | TSCA listed | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29309070 | |||||||||
| Storage Class | 8A - Combustible corrosive hazardous materials | |||||||||
| Hazard Classifications | Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral Aquatic Chronic 3 |
|||||||||
| Toxicity | LDLo ipr-rat: 40 mg/kg ARZNAD 16,870,66ipr-mus LD50:17 mg/kg PCBPBS 2,95,72scu-mus LD50:100 mg/kg JJPAAZ 3,99,54 | |||||||||
| NFPA 704 |
|
Benzyl thiocyanate price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 13929 | Benzyl thiocyanate ≥95.0% (GC) | 3012-37-1 | 100g | $69.6 | 2026-04-30 | Buy |
| TCI Chemical | T0198 | Benzyl Thiocyanate >99.0%(GC) | 3012-37-1 | 25g | $17 | 2026-04-30 | Buy |
| TCI Chemical | T0198 | Benzyl Thiocyanate >99.0%(GC) | 3012-37-1 | 500g | $80 | 2026-04-30 | Buy |
| Usbiological | 003864 | Benzyl Thiocyanate | 3012-37-1 | 5g | $531 | 2026-06-03 | Buy |
| Chem-Impex | 37197 | Benzyl thiocyanate ≥99%(GC) | 3012-37-1 | 25G | $22.03 | 2026-05-19 | Buy |
Benzyl thiocyanate Chemical Properties, Uses, Production
Description
Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.
Chemical Properties
ALMOST WHITE TO YELLOW CRYSTALS OR CRYST. POWDER
Uses
Benzyl Thiocyanate is found to increase the protein production of Streptomyces aureofaciens. Inhibits methylazoxymethanol acetate-induced intestinal carcinogenesis and reduces unscheduled DNA synthesi s for some genotoxic carcinogens in rats.
Uses
Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.
Application
Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.
Definition
ChEBI: Benzyl thiocyanate is a member of thiocyanates.
Synthesis Reference(s)
Synthesis, p. 184, 1977
Tetrahedron Letters, 18, p. 4417, 1977 DOI: 10.1016/S0040-4039(01)83524-3
General Description
Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.
Hazard
Strong irritant to skin, tissue. Moderate fire hazard.
Safety Profile
Poison by subcutaneous andintraperitoneal routes. Whenheated to decomposition it emits very toxic fumes ofNOx, SOx, and CN.
Purification Methods
Crystallise the thiocyanate from EtOH or aqueous EtOH. [Beilstein 6 H 460, 6 IV 2680.]
Benzyl thiocyanate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| JinYan Chemicals(ShangHai) Co.,Ltd. | 13817811078 | sales@jingyan-chemical.com | China | 9963 | 60 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Chemsky（shanghai）International Co.,Ltd. | 021-50135380 | shchemsky@sina.com | China | 32273 | 50 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Maya High Purity Chemicals | +86 (573) 82222445 (0)18006601000 452520369 | sales@maya-r.com | China | 11693 | 57 |
| Thermo Fisher Scientific | 800-810-5118 | cnchemical@thermofisher.com | China | 17752 | 75 |
| Beijing innoChem Science & Technology Co.,Ltd. | 400-810-7969 010-59572699 | ningzi.li@inno-chem.com.cn | China | 6122 | 55 |
View Latest Price from Benzyl thiocyanate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | Benzyl thiocyanate
3012-37-1
|
$1.00 | 1KG | 98% | 1kg,5kg,100kg | Career Henan Chemical Co |
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- Benzyl thiocyanate
3012-37-1
- $1.00
- 98%
- Career Henan Chemical Co
