ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate
- CAS No.
- 6742-26-3
- Chemical Name:
- ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate
- Synonyms
- ethyl 1-oxo-3,4-dihydro-2H-naphthalene-2-carboxylate;ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate;2-Naphthalenecarboxylic acid, 1,2,3,4-tetrahydro-1-oxo-, ethyl ester
- CBNumber:
- CB71247694
- Molecular Formula:
- C13H14O3
- Molecular Weight:
- 218.25
- MDL Number:
- MFCD00973033
- MOL File:
- 6742-26-3.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319 |
| Precautionary statements | P261-P305+P351+P338 |
ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate price More Price(24)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Matrix Scientific | 133473 | Ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate | 6742-26-3 | 250.00mg | $27 | 2026-05-18 | Buy |
| Matrix Scientific | 133473 | Ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate | 6742-26-3 | 1.00g | $87 | 2026-05-18 | Buy |
| Matrix Scientific | 133473 | Ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate | 6742-26-3 | 5.00g | $267 | 2026-05-18 | Buy |
| aablocks | AA00FFAA | ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate ≥95% | 6742-26-3 | 100mg | $10 | 2026-05-28 | Buy |
| aablocks | AA00FFAA | ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate 95% | 6742-26-3 | 250mg | $20 | 2026-05-28 | Buy |
ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate Chemical Properties, Uses, Production
Synthesis
529-34-0
105-58-8
6742-26-3
GENERAL STEPS: Anhydrous THF (50 mL) solution of α-tetralone (6, 11.7 g, 80 mmol) was added slowly and dropwise under nitrogen protection to a stirred THF (150 mL) suspension of NaH (60%, 6.40 g, 160 mmol) and diethyl carbonate (150 mL). The reaction mixture was heated to reflux overnight and subsequently cooled in an ice bath and acidified with 1 M HCl (100 mL). The reaction solution was extracted with Et2O (3 × 200 mL), and the organic phases were combined, washed sequentially with NaHCO3 (200 mL) and brine (200 mL), dried over MgSO4, filtered, and concentrated under reduced pressure to give a light brown oily product (17.46 g, 99% yield), which could be used for the next reaction without further purification. The product was characterized by 1H NMR (400 MHz, CDCl3) and 13C NMR (100 MHz, CDCl3), and the data were consistent with those reported in the literature.
References
[1] European Journal of Organic Chemistry, 2016, vol. 2016, # 5, p. 918 - 920
[2] Tetrahedron Asymmetry, 2014, vol. 25, # 3, p. 238 - 244
[3] Journal of the American Chemical Society, 1986, vol. 108, p. 1617
[4] Bulletin des Societes Chimiques Belges, 1980, vol. 89, # 1, p. 57 - 66
[5] Journal of Organic Chemistry, 2009, vol. 74, # 6, p. 2467 - 2475
ethyl 1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
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