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(S,S)-I-Pr-duphos

(S,S)-I-Pr-duphos Structure
(S,S)-I-Pr-duphos structure
CAS No.
147253-69-8
Chemical Name:
(S,S)-I-Pr-duphos
Synonyms
(S,S)-I-Pr-duphos;(-)-1,2-BIS((2S,5S)-2,5-DIISOPROPYLPHOSPHOLANO)BENZENE;(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE;1,2-bis((2S,5S)-2,5-diisopropylphospholan-1-yl)benzene;(?)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene;(-)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene;1,2-Bis[(2S,5S)-2,5-diisopropyl-1-phospholanyl]benzene, 97+%;(?)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene;(-)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene, Kanata purity;(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene (S,S)-i-Pr-DUPHOS
CBNumber:
CB7128464
Molecular Formula:
C26H44P2
Molecular Weight:
418.58
MDL Number:
MFCD02684550
MOL File:
147253-69-8.mol
MSDS File:
SDS
Last updated:2026-09-12 18:54:27
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(S,S)-I-Pr-duphos Properties

Melting point 40°C
alpha -85° (c 1, hexane)
Boiling point 502.0±20.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form crystal
color white
Sensitive Air Sensitive
InChI 1S/C26H44P2/c1-17(2)21-13-14-22(18(3)4)27(21)25-11-9-10-12-26(25)28-23(19(5)6)15-16-24(28)20(7)8/h9-12,17-24H,13-16H2,1-8H3/t21-,22-,23-,24-/m0/s1
InChIKey RBVGOQHQBUPSGX-ZJZGAYNASA-N
SMILES CC(C)[C@@H]1CC[C@@H](C(C)C)P1c2ccccc2P3[C@@H](CC[C@H]3C(C)C)C(C)C
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Danger
Hazard statements  H332-H315-H302-H312-H319
Precautionary statements  P280-P302+P352-P312-P322-P363-P501-P261-P271-P304+P340-P312-P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P-P264-P270-P301+P312-P330-P501
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
Storage Class 13 - Non Combustible Solids
NFPA 704
1
0 0

(S,S)-I-Pr-duphos price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 668176 (?)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene kanata purity 147253-69-8 100mg $125 2023-06-20 Buy
Strem Chemicals 15-0411 (-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene, 98+% (S,S)-i-Pr-DUPHOS 98+% 147253-69-8 100mg $85 2026-04-30 Buy
Strem Chemicals 15-0411 (-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene, 98+% (S,S)-i-Pr-DUPHOS 98+% 147253-69-8 500mg $292 2026-04-30 Buy
American Custom Chemicals Corporation ING0001092 (-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE 95.00% 147253-69-8 100MG $649.18 2021-12-16 Buy
American Custom Chemicals Corporation ING0001092 (-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE 95.00% 147253-69-8 2G $1836.45 2021-12-16 Buy
Product number Packaging Price Buy
668176 100mg $125 Buy
15-0411 100mg $85 Buy
15-0411 500mg $292 Buy
ING0001092 100MG $649.18 Buy
ING0001092 2G $1836.45 Buy

(S,S)-I-Pr-duphos Chemical Properties,Uses,Production

Reaction

  1. The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
  2. Forms superior catalysts for asymmetric reductive aminations.
  3. Catalyst used for the asymmetric hydrogenation of enol phosphonates.
  4. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
  5. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
  6. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
  7. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
  8. Palladium catalyzed asymmetric phosphination.
  9. Catalytic enantioselective allylation of ketones.
  10. Enantioselective synthesis of cyclopropylborates.
  11. Ligand used in gold catalyzed rearrangement of cyclopropylidene.
Reactions of 147253-69-8_1
Reactions of 147253-69-8_2
Reactions of 147253-69-8_3
Reactions of 147253-69-8_4

Uses

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

(S,S)-I-Pr-duphos Preparation Products And Raw materials

Raw materials

Preparation Products

(S,S)-I-Pr-duphos Suppliers

Global( 31)Suppliers
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29985 65
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2280 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 420970979@qq.com China 5978 58
Shanghai Thoreco Novel Material Co. Ltd 021-34202258 19391107643 Sales@thoreco.com China 183 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Alfa Aesar 84
Energy Chemical 61
Shanghai Aladdin Bio-Chem Technology Co.,LTD 65
Sigma-Aldrich 80
Shanghai YuanYe Biotechnology Co., Ltd. 60
LaaJoo 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 58
Shanghai Thoreco Novel Material Co. Ltd 58

147253-69-8((S,S)-I-Pr-duphos)Related Search:

(S,S)-I-Pr-duphos (-)-1,2-Bis((2S,5S)-2,5-di-I-propylphospholano)benzene(1,5-cyclooctadiene)rhodium (I) tetrafluoroborate (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene (-)-1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene (+)-1,2-Bis((2R,5R)-2,5-di-I-propylphospholano)benzene)1,5-cyclooctadiene)rhodium (I) tetrafluoroborate
Di-I-butylphosphine Benzene (-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(S,S)-i-Pr-DUPHOS-Rh (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

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(-)-1,2-BIS((2S,5S)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE (-)-1,2-BIS((2S,5S)-2,5-DIISOPROPYLPHOSPHOLANO)BENZENE (-)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene, Kanata purity (-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene,98+%(S,S)-i-Pr-DUPHOS (-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene (S,S)-i-Pr-DUPHOS 1,2-bis((2S,5S)-2,5-diisopropylphospholan-1-yl)benzene 1,2-Bis[(2S,5S)-2,5-diisopropyl-1-phospholanyl]benzene, 97+% Phospholane, 1,1'-(1,2-phenylene)bis[2,5-bis(1-methylethyl)-, (2S,2'S,5S,5'S)- (-)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene (?)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene (?)-1,2-Bis[(2S,5S)-2,5-diisopropylphospholano]benzene (S,S)-I-Pr-duphos 147253-69-8 DuPhos/BPE Privileged Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis organophosphine ligand