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Phthaloyl dichloride

CAS No.
88-95-9
Chemical Name:
Phthaloyl dichloride
Synonyms
PHTHALOYL CHLORIDE;PHTHALYL CHLORIDE;Phthalic dichloride;benzene-1,2-dicarbonyl chloride;Phthalic chloride;Phthaloyl chlorid;thaloyl dichloride;Phthalyl dichloride;o-Phtaloyl chloride;o-Phthalyl chloride
CBNumber:
CB7273160
Molecular Formula:
C8H4Cl2O2
Molecular Weight:
203.02
MDL Number:
MFCD00000666
MOL File:
88-95-9.mol
MSDS File:
SDS
Last updated:2026-05-28 05:51:35
Product description Number Pack Size Price
Phthaloyl chloride 90% P40409 100g $69.1
Phthaloyl chloride 90% P40409 500g $82.3
Phthaloyl dichloride for synthesis 8.21029 50mL $46.1
Phthaloyl dichloride for synthesis 8.21029 250ML $136
Phthaloyl Chloride >98.0%(T) P0405 25g $27
More product size

Phthaloyl dichloride Properties

Melting point 6-12 °C(lit.)
Boiling point 269-271 °C(lit.)
Density 1.409 g/mL at 25 °C(lit.)
vapor pressure 30 mm Hg ( 47 °C)
refractive index n20/D 1.568(lit.)
Flash point >230 °F
storage temp. Store below +30°C.
solubility Miscible with ether.
form Liquid
color Clear yellow
Water Solubility decomposes
Sensitive Moisture Sensitive
Merck 14,7375
BRN 608200
Stability Moisture Sensitive
InChI 1S/C8H4Cl2O2/c9-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H
InChIKey FYXKZNLBZKRYSS-UHFFFAOYSA-N
SMILES ClC(=O)c1ccccc1C(Cl)=O
CAS DataBase Reference 88-95-9(CAS DataBase Reference)
FDA UNII 8S64APH24W
NIST Chemistry Reference 1,2-Benzenedicarbonyl dichloride(88-95-9)
EPA Substance Registry System 1,2-Benzenedicarbonyl dichloride (88-95-9)
UNSPSC Code 12352106
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Corrosion (GHS05)
GHS05
Signal word  Danger
Hazard statements  H314-H290
Precautionary statements  P501-P234-P264-P280-P390-P301+P330+P331-P363-P405
PPE Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3265 8/PG 2
WGK Germany  3
21
TSCA  TSCA listed
HazardClass  8
PackingGroup  II
HS Code  29173980
Storage Class 8A - Combustible corrosive hazardous materials
Hazard Classifications Skin Corr. 1B
REACH Registrations Inactive
Limited Quantities 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)
Excepted Quantities Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
NFPA 704
3 0

Phthaloyl dichloride price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich P40409 Phthaloyl chloride 90% 88-95-9 100g $69.1 2026-04-30 Buy
Sigma-Aldrich P40409 Phthaloyl chloride 90% 88-95-9 500g $82.3 2026-04-30 Buy
Sigma-Aldrich 8.21029 Phthaloyl dichloride for synthesis 88-95-9 50mL $46.1 2026-04-30 Buy
Sigma-Aldrich 8.21029 Phthaloyl dichloride for synthesis 88-95-9 250ML $136 2026-04-30 Buy
TCI Chemical P0405 Phthaloyl Chloride >98.0%(T) 88-95-9 25g $27 2026-04-30 Buy
Product number Packaging Price Buy
P40409 100g $69.1 Buy
P40409 500g $82.3 Buy
8.21029 50mL $46.1 Buy
8.21029 250ML $136 Buy
P0405 25g $27 Buy

Phthaloyl dichloride Chemical Properties,Uses,Production

Chemical Properties

colorless or clear yellow oily liquid. decompose with water and alcohol, soluble in ether, chloroform and benzene.

Uses

Phthaloyl chloride is used for the preparation of volatile acid chlorides from the acids. It acts as a trapping agent for the nitrite ion in the fluorodenitration of aromatic substrates with potassium fluoride. It serves as an additive in polymers and fibers to improve the color stability. It is used as an ingredient in ceramic mold binders, as a stabilizer for polymers and in reverse osmosis membranes.

Uses

o-Phthaloyl Dichloride is used in the phthaloylation of hemicelluloses as an efficient way to improve their lipophilicity and hydrophilicity. Phthaloylation of hemicelluloses is also a key precursor to preparing polysaccharide derivatives.

Preparation

Synthesis of phthaloyl dichloride: Mix 148g of phthalic anhydride with 220g of phosphorus pentachloride, heat, gradually increase the temperature to 250°C, escape the phosphorus oxychloride, distill the reaction product under reduced pressure, collect the 131-133°C (1.2-1.33kPa) fraction to obtain 187g of phthaloyl dichloride.

General Description

equilibrium mixture (phthaloyl chloride ~80% and pseudochloride ~10%) both components show equal chemical behaviour

Global( 228)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21585 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29812 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49979 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
+86-021-61551413 +8618813727289 contact@trustwe.com China 5746 58
SIMAGCHEM CORP
+86-5922680277 +86-13806087780 sale@simagchem.com China 17346 58
Career Henan Chemica Co
+86-0371-86658258 +8613203830695 laboratory@coreychem.com China 30224 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Dayang Chem (Hangzhou) Co.,Ltd.
+86-0571-88938639 +8617705817739 info@dycnchem.com China 52704 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 17259 58
sgtlifesciences pvt ltd
+8617013299288 dj@sgtlifesciences.com China 12373 58

View Lastest Price from Phthaloyl dichloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Phthaloyl dichloride pictures 2019-07-06 Phthaloyl dichloride
88-95-9
$1.00 1kg 96%-99% Career Henan Chemical Co
benzenedioylchloride Phthalic chloride Phthalic dichloride Phthalyl dichloride 1,2-Bis(chlorocarbonyl)benzene o-Phtaloyl chloride o-Phthalic acid dichloride O-Phthaloyl dichloride, 90%, remainder mainly phthalic acid 1,2-Benzenebis(carbonyl chloride) 1,2-Benzenedicarboxylic acid dichloride sym-o-Phthalic dichloride o-Phthaloyl dichloride,97%,pract. Phthaloyl chloride,Phthaloyl dichloride o-Phthaloyl dichloride, reMainder Mainly phthalic acid, 90% 100ML Phthaloyl chlorid The adjacent benzene twobenzoyl chloride Phthaloyl Chloride , 98.0%(T) Phthaloyl chloride technical, >=90% Phthaloyl dichloride for synthesis 1,2-BENZENEDICARBONYL CHLORIDE 1,2-BENZENEDICARBONYL DICHLORIDE PHTHALIC ACID DICHLORIDE PHTHALOYL DICHLORIDE PHTHALYL CHLORIDE O-PHTHALOYL CHLORIDE O-PHTHALOYL DICHLORIDE ORTHO-PHTHALOYL CHLORIDE Benzene-1,2-dicarbonyl chloride~Phthaloyl dichloride O-Pathaloyl Dichloride Phthaloyl Dichloride/Phthaloyl chloride PHTHALOYL CHLORIDE, DIST. o-Phthalyl chloride o-Phthaloyl dichloride, pract., 97% o-Phthaloyl dichloride, remainder mainly phthalic acid, 90% benzene-1,2-dicarbonyl chloride o-benzenedicarbonyl chloride 2-PHTHALOYLDICHLORIDE 1,2-phthaloyl dichloride PHTHALICACIDCHLORIDE PhthaloylChloride> Phthaloyl Dichloride,>95% thaloyl dichloride Phthaloyl chloride,98% Isophthaloylchloride/Terephthaloylchloride PHTHALOYL CHLORIDE 88-95-9 C6H4COCl3 C6H412COCl2 Building Blocks Carbonyl Compounds Acid Halides Organic Building Blocks ACID CHLORIDES o-Phthaloyl Dichloride, o-Diacetyl Chloride K00001 bc0001