ChemicalBook >> CAS DataBase List >>Carbonylbis(triphenylphosphine)rhodium(I) chloride
Carbonylbis(triphenylphosphine)rhodium(I) chloride
- CAS No.
- 13938-94-8
- Chemical Name:
- Carbonylbis(triphenylphosphine)rhodium(I) chloride
- Synonyms
- CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)RHODIUM(I);Carbonylbis(tripheny;Bis(Triphenylphosphine)rhodium(I) carbon;BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I;Carbonylbis(triphenylphosphine)rhodium(I);Carbonychlorobis(triphenylphosphine)rhodium;carbonylchlorobis(triphenylphosphine)rhodium;Carbonyl diphenyl phosphine rhodium chloride;Carbonylbis(triphenylphosphine)rhodium(I)chlo;Chlorocarbonyl bis(triphenylphosphine) rhodium
- CBNumber:
- CB7376852
- Molecular Formula:
- C37H30ClOP2Rh
- Molecular Weight:
- 690.94
- MDL Number:
- MFCD00044273
- MOL File:
- 13938-94-8.mol
- MSDS File:
- SDS
- TDS File:
- TDS
Last updated:2026-05-28 05:51:58
| Melting point | 224-227 °C (dec.)(lit.) |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in acetone, chloroform, ethanol |
| form | crystal |
| color | yellow |
| BRN | 4618896 |
| Exposure limits |
ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3 NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| InChI | 1S/2C18H15P.CO.ClH.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h2*1-15H;;1H;/q;;;;+1/p-1 |
| InChIKey | SGULOPRLUCGLSH-UHFFFAOYSA-M |
| SMILES | Cl[Rh].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6 |
| CAS DataBase Reference | 13938-94-8(CAS DataBase Reference) |
| FDA UNII | 100LRS254G |
| UNSPSC Code | 12352300 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P280a-P305+P351+P338-P321-P332+P313-P337+P313-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| PPE | Eyeshields, Gloves, type N95 (US) | |||||||||
| Hazard Codes | Xn,T | |||||||||
| Risk Statements | 20/21/22 | |||||||||
| Safety Statements | 22-24/25 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 28439090 | |||||||||
| Storage Class | 11 - Combustible Solids | |||||||||
| NFPA 704 |
|
Carbonylbis(triphenylphosphine)rhodium(I) chloride price More Price(51)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 204242 | Bis(triphenylphosphine)rhodium(I) carbonyl chloride 99.9% | 13938-94-8 | 1g | $336 | 2022-05-15 | Buy |
| TCI Chemical | B1692 | Carbonylbis(triphenylphosphine)rhodium(I) Chloride | 13938-94-8 | 1g | $257 | 2026-04-30 | Buy |
| Strem Chemicals | 45-0350 | Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99% 99% | 13938-94-8 | 250mg | $85 | 2026-04-30 | Buy |
| Strem Chemicals | 45-0350 | Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99% 99% | 13938-94-8 | 1g | $250 | 2026-04-30 | Buy |
| Strem Chemicals | 45-0350 | Chlorocarbonylbis(triphenylphosphine)rhodium(I), 99% 99% | 13938-94-8 | 5g | $1003 | 2026-04-30 | Buy |
Carbonylbis(triphenylphosphine)rhodium(I) chloride Chemical Properties, Uses, Production
Chemical Properties
yellow crystals
Uses
Used for cyclometallation.
Application
Used as catalyst for carbonylation，decarbonylation, carbonyl exchange, reduction, hydrometalation, and C-H activation reactions; reagent for alkylation of acid chlorides.
reaction suitability
core: rhodium
reagent type: catalyst
Synthesis
To a solution of RhCl3.3H2O (2 g, 7.6 mmol) in 70 mL of absolute ethanol is slowly added triphenylphosphine (7.2 g, 2.75 mmol) in 300 mL of boiling absolute ethanol. The solution becomes clear within 5 min, at which point sufficient (10-20 mL) 37% formaldehyde solution is added, causing the red solution to become pale yellow. After several minutes, yellow microcrystals precipitate. Upon cooling, the resulting crystals are washed with ethanol and diethyl ether, dried (4.5 g, 85%) and recrystallized from hot toluene.
storage
The complex is air-stable as a crystalline solid and can be stored without special precautions. In solution it readily reacts with oxygen, which therefore must be excluded during preparation and use of this reagent.
Carbonylbis(triphenylphosphine)rhodium(I) chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Global Suppliers ( 235)
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| INTATRADE GmbH | +49 3493/605464 | sales@intatrade.de | Germany | 3563 | 66 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
| Maya High Purity Chemicals | +86 (573) 82222445 (0)18006601000 452520369 | sales@maya-r.com | China | 11693 | 57 |
| Chengdu Ai Keda Chemical Technology Co., Ltd. | 4008-755-333 18080918076 | 800078821@qq.com | China | 9706 | 55 |
View Latest Price from Carbonylbis(triphenylphosphine)rhodium(I) chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-25 | Carbonylbis(triphenylphosphine)rhodium(I) chloride
13938-94-8
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2020-11-19 | Carbonylbis(triphenylphosphine)rhodium(I) chloride
13938-94-8
|
$20.00 | 1KG | 99% | 10000KG | Longyan Tianhua Biological Technology Co., Ltd | |
 |
2019-07-06 | Carbonylbis(triphenylphosphine)rhodium(I) chloride
13938-94-8
|
$1.00 | 1kg | 95%-99% | 100kg | Career Henan Chemical Co |
-
- Carbonylbis(triphenylphosphine)rhodium(I) chloride
13938-94-8
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- Carbonylbis(triphenylphosphine)rhodium(I) chloride
13938-94-8
- $20.00
- 99%
- Longyan Tianhua Biological Technology Co., Ltd
-
- Carbonylbis(triphenylphosphine)rhodium(I) chloride
13938-94-8
- $1.00
- 95%-99%
- Career Henan Chemical Co
13938-94-8 (Carbonylbis(triphenylphosphine)rhodium(I) chloride) Related Search:
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carbonylchlorobis(triphenylphosphine)rhodium
CARBONYLCHLORO-BIS-(TRIPHENYLPHOSPHANO)RHODIUM(I)
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Bis(triphenylphosphine) rhodium carbonyl chloride
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CARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I ) CHLORIDE, 99.99%
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Bis(triphenylphosphine)carbonylrhodium(I) Chloride
Carbonylchlorobis(triphenylphosphine)rhodium(I)
Bis(triphenylphosphine)carbonylrhodiuM chloride
Carbonylbis(tripheny
BIS(TRIPHENYLPHOSPHINE)CARBONYLRHODIUM(I
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Carbonylbis(triphenylphosphine)rhodium(I) chloride ISO 9001：2015 REACH
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rhodium(I)
Carbonylbis(triphenylphosphine)rhodium(I)
Bis(triphenylphosphine)carbonylchlororhodium(I)
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
13938-94-8
C37H31ClOP2Rh
RhClCOPC6H532
RhClCOPPh32
C6H53P2RhClCO
C37H30ClOP2Rh
2C18H15PCOClRh
Catalysis and Inorganic Chemistry
Metal Complexes
Transition Metal Compounds
Homogeneous Catalysts
Catalysts for Organic Synthesis
Rh (Rhodium) Compounds
Classes of Metal Compounds
metal carbonyl complexes
Rh
chemical reaction,pharm,electronic,materials
Catalysts for Organic Synthesis
