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ChemicalBook >> CAS DataBase List >>(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine

(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine

(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine Structure
(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine structure
CAS No.
185346-09-2
Chemical Name:
(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine
Synonyms
SF150006;(S,R)-In-Pybox;(3aS,8aR)-in-pybox;2,6-BIS((3AS,8AR)-8H-INDENO(1,2-D)OXAZO&;2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine;aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine;(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-I...;2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine;2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine;(-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine
CBNumber:
CB7448533
Molecular Formula:
C25H19N3O2
Molecular Weight:
393.44
MDL Number:
MFCD05861599
MOL File:
185346-09-2.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-09-12 18:54:57
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(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine Properties

Melting point 265°C (dec.)
alpha -364.0° (c 1.04, CH2Cl2)
Boiling point 633.0±55.0 °C(Predicted)
Density 1.50±0.1 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka 4.35±0.20(Predicted)
form Powder
color white to off-white
optical activity [α]20/D -375°, c = 1 in dichloromethane (typical)
InChI 1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m1/s1
InChIKey BZSJUFJXCHHRHW-LUKWVAJMSA-N
SMILES C1(C2=N[C@@]3([H])C4=C(C=CC=C4)C[C@@]3([H])O2)=NC(C2=N[C@@]3([H])C4=C(C=CC=C4)C[C@@]3([H])O2)=CC=C1
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P280-P305+P351+P338
Risk Statements  36/37/38
Safety Statements  26-36/37/39-36
WGK Germany  3
HS Code  29333990
Storage Class 11 - Combustible Solids
Hazard Classifications Aquatic Chronic 4

(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 673978 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine 185346-09-2 250mg $152 2026-04-30 Buy
Sigma-Aldrich 673978 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine 185346-09-2 1g $494 2026-04-30 Buy
Strem Chemicals 07-0280 (-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX min.97% 185346-09-2 250mg $283 2026-04-30 Buy
Strem Chemicals 07-0280 (-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX min.97% 185346-09-2 1g $848 2026-04-30 Buy
Strem Chemicals 07-1367 (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE 185346-09-2 250mg $120 2024-03-01 Buy
Product number Packaging Price Buy
673978 250mg $152 Buy
673978 1g $494 Buy
07-0280 250mg $283 Buy
07-0280 1g $848 Buy
07-1367 250mg $120 Buy

(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine Chemical Properties, Uses, Production

Reaction

  1. Ligand for Iridium-catalyzed enantio- and diastereoselective reductive aldol reactions
  2. Ligand for Scandium-catalyzed asymmetric Nazarov reactions
  3. Ligand for Scandium-catalyzed enantioselective pyrrole alkylations of α,β-unsaturated 2-acyl imidazoles
  4. Ligand for Scandium-catalyzed enantioselective Friedel-Crafts Alkylations
  5. Ligand for Nickel-catalyzed asymmetric cross-couplings of racemic propargyl groups with arylzinc reagents
  6. Ligand for Scandium-catalyzed enantioselective intramolecular carbonyl-ene reaction, the synthesis of (+)-triptophenolide
  7. Ligand for Scandium-catalyzed asymmetric synthesis of substituted 3-hydroxy-2-oxindoles
  8. Ligand for Indium-catalyzed enantio- and regioselective addition of pyrroles to isatins
  9. Ligand for Scandium-catalyzed asymmetric [3+2] annulation of allylsilanes with isatins in the synthesis of spirooxindoles
  10. Ligand for Scandium-catalyzed enantioselective allylation of isatins using allylsilanes
  11. Ligand for Scandium-catalyzed enantioselective carboannulation with allylsilanes
Reactions of 185346-09-2_1
Reactions of 185346-09-2_2
Reactions of 185346-09-2_3

Chemical Properties

White powder

Uses

Reactant involved in synthesis of:

  • Chiral ruthenium(II)-pybox complexes for use as intramolecular C-H amination catalysts
  • Bis(oxazolinyl_pyridine-scandium(III) triflate complex catalyst for enantioselective addition of pyrroles to indoles
  • Chiral N,N,N-tridentate pybos and pyboxazine ligands

(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine Suppliers

Global Suppliers ( 75)
Supplier Tel Email Country ProdList Advantage
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2280 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Nanjing Habo Medical Technology Co., Ltd. 13376080562 13376090521 sales@habotech.com China 724 60
HuiFeiChem(WuXi) PharmaTech Co.,Ltd 0510-0510-83593305 sales@huifeichem.com China 102 62
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 7909 65
Suzhou Guide Fine Material Co.Ltd. 0512-66627360 13914021065 706938434@qq.com China 202 60
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 4094 50
Shanghai Aladdin Bio-Chem Technology Co.,LTD 400-6206333 13167063860 anhua.mao@aladdin-e.com China 29985 65
Supplier Advantage
LaaJoo 58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Energy Chemical 61
Nanjing Habo Medical Technology Co., Ltd. 60
HuiFeiChem(WuXi) PharmaTech Co.,Ltd 62
Daicel Chiral Technologies (China)CO.,LTD 65
Suzhou Guide Fine Material Co.Ltd. 60
Tianjin Derchemist Science & Technology Co., Ltd. 50
Shanghai Aladdin Bio-Chem Technology Co.,LTD 65

(-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine Spectrum

(-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE(185346-09-2)1HNMR

185346-09-2 ((-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine) Related Search:

2,6-Bis((3aR,8aS)-8H-indeno(1,2-d)oxazo& (S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine 2,6-bis[(4R,5R)-4,5-dihydro-1-[(4-methylphenyl)sulfonyl]-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine 2-[(4R)-4,5-dihydro-4-(phenylMethyl)-2-oxazolyl]- Pyridine
2,6-bis[(4S,5S)-4,5-dihydro-4,5-diphenyl-1H-imidazol-2-yl]-Pyridine (S)-5-CF3-pyrox-tBu 2-[(4R)-4-(1,1-diMethylethyl)-4,5-dihydro-2-oxazolyl]-5-(trifluoroMethyl)-Pyridine 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine (-)-1,2-Bis((2R,5R)-2,5-diphenylphospholano)ethane
Methyl picolinimidate (-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine Pyridine-2-carboximidic acid ethyl ester (1S,2R)-(-)-cis-1-Amino-2-indanol

1of3

(-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine, min. 97% Indenyl-PYBOX 2,6-Bis((3aS,8aR)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,97% aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole],99%e.e. 2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine (3aS,8aR)-in-pybox 2,6-BIS((3AS,8AR)-8H-INDENO(1,2-D)OXAZO& (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aalpha,8aalpha)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine,min.97% (3aS,8aR)-in-pybox, (3aS,3μaS,8aR,8μaR)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aalpha:,8aalpha:)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine, min. 97% (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno [1,2-d]oxazole}]pyridine, min. 97%　 (-)-2,6-BIS[(3AS,8AR)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLIN-2-YL]PYRIDINE,MIN.97%INDENYL-PYBOX (3aR,8bS)-2-[6-[(3aR,8bS)-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridin-2-yl]-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazole SF150006 [3aS-[2(3'aRS,8'aSR),3aα,8aα]]-2,2'-(2,6-pyridinediyl)bis-[3a,8a-dihydro-8H-indeno[1,2-d]oxazole] (3aS,3'aS,8aR,8'aR)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole], 95%, (99% ee) (-)-2,6-Bis[2-[3as-(2(3'ar*,8'as*),3a alpha,8aalpha)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine 2,6-Bis[(3aS,8aR)-(-)-8H-indeno[1,2-d]oxazolin-2-yl)]pyridine, 98%, for synthesis 8H-Indeno[1,2-d]oxazole, 2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aS,3'aS,8aR,8'aR)- (S,R)-In-Pybox (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-I... (-)-2,6-Bis[2-{3aS-(2(3'aR*,8'aS*),3aα,8aα)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole}]pyridine (-)-2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine 2,6-Bis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine (-)-2,6-Bis[2-{3aS-(2(3aR*,8aS*),3Aalpha:,8Aalpha:)-3a,8a-Dihydro-8H-Indeno[1,2-d]Oxazole}]Pyridine (-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine (-)-2,6-Bis[2-[3aS-(2(3'aR*,8'aS*),3a,8a)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole]]pyridine 185346-09-2 BOX series Chiral Nitrogen organic amine