4-Methoxy-3-buten-2-one
- CAS No.
- 51731-17-0
- Chemical Name:
- 4-Methoxy-3-buten-2-one
- Synonyms
- 4-methoxy-3-butene-2-one;TRANS-4-METHOXY-3-BUTEN-2-ONE;Einecs 257-364-0;4-Methoxy-3-buten-2-one;Trans 4-Methoxy Butenone;(E)-4-methoxy-3-buten-2-one;(3E)-4-Methoxy-3-buten-2-one;(3E)-4-Methoxybut-3-en-2-one;TRANS-1-METHOXY-1-BUTEN-3-ONE;3-Buten-2-one,4-methoxy-, (3E)-
- CBNumber:
- CB7449808
- Molecular Formula:
- C5H8O2
- Molecular Weight:
- 100.12
- MDL Number:
- MFCD00008778
- MOL File:
- 51731-17-0.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 0℃ |
|---|---|
| Boiling point | 200 °C (lit.) |
| Density | 0.982 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 146 °F |
| storage temp. | 2-8°C |
| solubility | sol THF, ether, acetonitrile, benzene. |
| form | liquid |
| Appearance | Colorless to light yellow Liquid |
| BRN | 2070991 |
| InChI | InChI=1S/C5H8O2/c1-5(6)3-4-7-2/h3-4H,1-2H3/b4-3+ |
| InChIKey | VLLHEPHWWIDUSS-ONEGZZNKSA-N |
| SMILES | CC(=O)/C=C/OC |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) | ![]() GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H227-H302-H315-H319-H335 |
| Precautionary statements | P210-P235-P261-P280-P302+P352-P304+P340-P305+P351+P338-P370+P378-P403+P235 |
| PPE | Eyeshields, Gloves, type ABEK (EN14387) respirator filter |
| Risk Statements | 10 |
| Safety Statements | 23-24/25 |
| RIDADR | 1224 |
| WGK Germany | 3 |
| F | 10-21 |
| Storage Class | 10 - Combustible liquids |
4-Methoxy-3-buten-2-one price More Price(9)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 122068 | trans-4-Methoxy-3-buten-2-one technical grade, 90% | 51731-17-0 | 10g | $108 | 2026-04-30 | Buy |
| Sigma-Aldrich | 122068 | trans-4-Methoxy-3-buten-2-one technical grade, 90% | 51731-17-0 | 50g | $328 | 2026-04-30 | Buy |
| aablocks | AA0035N6 | trans-4-Methoxy-3-buten-2-one 90%GC | 51731-17-0 | 250mg | $8 | 2026-05-28 | Buy |
| aablocks | AA0035N6 | trans-4-Methoxy-3-buten-2-one 90%GC | 51731-17-0 | 1g | $10 | 2026-05-28 | Buy |
| aablocks | AA0035N6 | trans-4-Methoxy-3-buten-2-one 90% | 51731-17-0 | 5g | $11 | 2026-05-28 | Buy |
4-Methoxy-3-buten-2-one Chemical Properties, Uses, Production
Uses
4-Methoxy-3-buten-2-one is a versatile four-carbon synthon; precursor to the Danishefsky diene; Diels-Alder dienophile; dipolarophile; electrophilic four-carbon synthon subject to conjugate addition at C-4 followed by elimination of the methoxide anion; its enolate is a nucleophilic four-carbon building block.
storage
4-Methoxy-3-buten-2-one may be harmful by inhalation, ingestion, or skin absorption; may cause skin and eye irritation; in addition to standard safety practice, mechanical exhaust is required. Do not breathe vapor. Store in refrigerator under nitrogen or argon.
4-Methoxy-3-buten-2-one Preparation Products And Raw materials
Raw materials
Preparation Products
4-Methoxy-3-buten-2-one Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Tianjin Rongshen Chemical Co., Ltd | 18317763565; 18317763565 | 18317763565@163.com | China | 9878 | 58 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 | cdhxsj@163.com | China | 11674 | 57 |
| Anhui Shite Pharmaceutical Technology Co., LTD | 086-21-50829787 13621628489 | sales1@stepuppharm.com | China | 253 | 55 |
| Shanghai Topbiochem Technology Co., Ltd | 021-58170097 | info@topbiochem.com | China | 9510 | 58 |
| 9ding chemical ( Shanghai) Limited | 4009209199 | sales@9dingchem.com | China | 22497 | 55 |
| Shanghai Aladdin Bio-Chem Technology Co.,LTD | 400-6206333 13167063860 | anhua.mao@aladdin-e.com | China | 29985 | 65 |
| Beijing Universal Century Technology Co., Ltd. | hysj_bj.com | China | 3576 | 55 |





