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TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)

CAS No.
41836-21-9
Chemical Name:
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)
Synonyms
Ceriumtrisbistrimethylsilylamide;Cerium(3+) bis(trimethylsilyl)amide;Cerium(III) bis(trimethylsilyl)amide;HEXAMETHYLDISILAZANE CERIUM(III) SALT;cerium iii tris(hexamethyldisilazide);bis(trimethylsilyl)azanide,cerium(3+);CERIUM III TRIS[BIS(METHYLSILYLAMIDE)];N,N-BIS(TRIMETHYLSILYLAMINE)CERIUM(III);CERIUM III TRIS(BIS(TRIMETHYLSILYLAMIDE));Tris(bis(trimethylsilyl)amino)cerium(III)
CBNumber:
CB7680047
Molecular Formula:
C6H19CeNSi2
Molecular Weight:
301.51
MDL Number:
MFCD03411241
MOL File:
41836-21-9.mol
MSDS File:
SDS
Last updated:2026-05-28 05:58:39

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Properties

Melting point 132-140 °C(lit.)
Boiling point 95-9°C/10-4mmHg
Flash point 36 °F
storage temp. Flammables + water-Freezer (-20°C)e area
form Powder
Water Solubility Soluble in water, protic solvents.
Sensitive Moisture Sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
Hazard statements  H228-H261-H314-H318
Precautionary statements  P210-P280-P305+P351+P338-P309-P310-P402+P404
Hazard Codes  F,C
Risk Statements  11-14/15-34
Safety Statements  16-26-36/37/39-43-45-7/8
RIDADR  UN 3396 4.3/PG 2
WGK Germany  3
TSCA  No
HazardClass  4.1
PackingGroup  III

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Chemical Properties,Uses,Production

Chemical Properties

Bright yellow crystalline powder

Uses

Tris[N,N-bis(trimethylsilyl)amide]cerium(III) is used as a reactant for synthesis of amidocerium(IV) oxides, Sterically encumbered N-heterocyclic carbene ligands, Lanthanide imidodiphosphinate complexes with electroluminescent properties, Lanthanide complexes of an oxazoline-phenoxide hybrid chelate. Some of the other applications include it is used as a reactant for One-electron oxidation to produce tetravalent cerium compounds, Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes.

1070-89-9
76089-77-5
41836-21-9
Synthesis of TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) from Sodium bis(trimethylsilyl)amide and CERIUM(III) TRIFLUOROMETHANESULFONATE

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Preparation Products And Raw materials

Global( 29)Suppliers
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INTATRADE GmbH +49 3493/605464 sales@intatrade.de Germany 3572 66
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41836-21-9(TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III))Related Search:

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