5-Bromo-2-methoxybenzyl alcohol
- CAS No.
- 80866-82-6
- Chemical Name:
- 5-Bromo-2-methoxybenzyl alcohol
- Synonyms
- RARECHEM AL BD 0053;5-BROMO-O-ANISYL ALCOHOL;5-Brom-2-methoxybenzyl alcohol;5-Bromo-2-methoxybenzyl alcohol;4-BROMO-2-(HYDROXYMETHYL)ANISOLE;5-Bromo-2-methoxybenzenemethanol;5-Bromo-2-methoxybenzyl alcohol,97%;(5-BROMO-2-METHOXY-PHENYL)-METHANOL;5-Bromo-2-methoxybenzyl alcohol 98%;BenzeneMethanol, 5-broMo-2-Methoxy-
- CBNumber:
- CB7691229
- Molecular Formula:
- C8H9BrO2
- Molecular Weight:
- 217.06
- MDL Number:
- MFCD00004630
- MOL File:
- 80866-82-6.mol
- MSDS File:
- SDS
| Melting point | 68-71 °C (lit.) |
|---|---|
| Boiling point | 192.5°C (rough estimate) |
| Density | 1.4816 (rough estimate) |
| refractive index | 1.4930 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| form | powder to crystal |
| color | White to Light yellow |
| InChI | 1S/C8H9BrO2/c1-11-8-3-2-7(9)4-6(8)5-10/h2-4,10H,5H2,1H3 |
| InChIKey | HAOOGRLZVQWDBY-UHFFFAOYSA-N |
| SMILES | COc1ccc(Br)cc1CO |
| CAS DataBase Reference | 80866-82-6(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302-H315-H319-H335 |
| Precautionary statements | P271-P261-P280 |
| PPE | Eyeshields, Gloves, type N95 (US) |
| Hazard Codes | Xn,Xi |
| Risk Statements | 36/37/38-22 |
| Safety Statements | 37/39-26-24/25 |
| WGK Germany | 3 |
| Hazard Note | Irritant |
| HS Code | 29094990 |
| Storage Class | 11 - Combustible Solids |
5-Bromo-2-methoxybenzyl alcohol price More Price(45)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 189693 | 5-Bromo-2-methoxybenzyl alcohol 97% | 80866-82-6 | 1g | $43.6 | 2023-06-20 | Buy |
| TCI Chemical | B3369 | 5-Bromo-2-methoxybenzyl Alcohol >98.0%(GC) | 80866-82-6 | 5g | $72 | 2026-04-30 | Buy |
| TCI Chemical | B3369 | 5-Bromo-2-methoxybenzyl Alcohol >98.0%(GC) | 80866-82-6 | 25g | $216 | 2026-04-30 | Buy |
| Usbiological | 261984 | 5-Bromo-2-methoxybenzyl alcohol Asreported | 80866-82-6 | 5g | $382 | 2026-06-03 | Buy |
| Usbiological | 261984 | 5-Bromo-2-methoxybenzyl alcohol Asreported | 80866-82-6 | 10g | $526 | 2026-06-03 | Buy |
5-Bromo-2-methoxybenzyl alcohol Chemical Properties, Uses, Production
Chemical Properties
white to light yellow crystal powder
Uses
5-Bromo-2-methoxybenzyl alcohol has been used in the synthesis of 5-bromo-2-methoxyphenylacetic acid.
Synthesis
612-16-8
80866-82-6
GENERAL METHODS: Lithium bromide monohydrate (0.2 mmol) and iodobenzene diacetate (0.2 mmol) were added to a solution of 2-methoxybenzenemethanol (0.2 mmol) in trifluoroethanol (1 mL) and the reaction was carried out at room temperature. The progress of the reaction was monitored by thin layer chromatography (TLC). Upon completion of the reaction, the reaction was quenched by the addition of saturated aqueous sodium sulfite solution. The mixture was extracted with dichloromethane and the combined organic layers were washed with saturated brine and dried over anhydrous sodium sulfate. The organic phase was concentrated under reduced pressure and the residue was purified by silica gel column chromatography to afford the target product 5-bromo-2-methoxybenzyl alcohol.
References
[1] Synlett, 2018, vol. 29, # 17, p. 2275 - 2278
[2] Tetrahedron Letters, 2000, vol. 41, # 46, p. 8881 - 8885
[3] Synthetic Communications, 2007, vol. 37, # 9, p. 1571 - 1577
5-Bromo-2-methoxybenzyl alcohol Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Capot Chemical Co., Ltd | +86 (0) 571 85 58 67 18 | China | 18187 | 66 | |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Sinopharm Chemical Reagent Co,Ltd. | 86-21-63210123 | sj_scrc@sinopharm.com | China | 9791 | 79 |
| Aemon Chemical | 0086-755-86198205 | acinfo@aemonchem.com | China | 1928 | 57 |
| Jinan Bond Chemical Technology Co., Ltd. | 86-531-88280989 | mymail1996@126.com | China | 254 | 55 |
| Beijing innoChem Science & Technology Co.,Ltd. | 400-810-7969 010-59572699 | ningzi.li@inno-chem.com.cn | China | 6122 | 55 |
View Latest Price from 5-Bromo-2-methoxybenzyl alcohol manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-14 | 5-BROMO-2-METHOXYBENZYL ALCOHOL
80866-82-6
|
$1.00 | 1g | 99% | 200kg | Career Henan Chemical Co | |
 |
2020-01-10 | (5-Bromo-2-methoxyphenyl)methanol
80866-82-6
|
$1.00 | 1g | 95-99% | 1ton | Career Henan Chemical Co | |
|
|
2020-01-10 | (5-Bromo-2-methoxyphenyl)methanol
80866-82-6
|
$1.00 | 1g | 95-99% | 1ton | Career Henan Chemical Co |
-
- 5-BROMO-2-METHOXYBENZYL ALCOHOL
80866-82-6
- $1.00
- 99%
- Career Henan Chemical Co
-
- (5-Bromo-2-methoxyphenyl)methanol
80866-82-6
- $1.00
- 95-99%
- Career Henan Chemical Co
-
- (5-Bromo-2-methoxyphenyl)methanol
80866-82-6
- $1.00
- 95-99%
- Career Henan Chemical Co
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