METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE
![METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE Structure](CAS/GIF/65695-05-8.gif)
- CAS No.
- 65695-05-8
- Chemical Name:
- METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE
- Synonyms
- Methyl 4-(N-hydroxycarbaMiMidoyl)benzoate;Methyl 4-(N-hydroxycarbamimidoyl);methyl 4-(N'-hydroxycarbamimidoyl)benzoate;Methyl 4-[(hydroxyamino)iminomethyl]benzoate;Methyl 4-[amino(hydroxyimino)methyl]benzoate;(E)-Methyl 4-(N'-hydroxycarbaMiMidoyl)benzoate;methyl 4-[(Z)-N'-hydroxycarbamimidoyl]benzoate;METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE;METHYL 4-[AMINO(HYDROXYIMINO)METHYL]BENZENECARBOXYLATE;4-[(HYDROXYAMINO)IMINOMETHYL]-BENZOIC ACID, METHYL ESTER
- CBNumber:
- CB7715095
- Molecular Formula:
- C9H10N2O3
- Molecular Weight:
- 194.19
- MDL Number:
- MFCD08689689
- MOL File:
- 65695-05-8.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Methyl 4-[amino(hydroxyimino)methyl]-benzenecarboxylate | QCA69505 | 10g | $472 |
| Methyl 4-(N-hydroxycarbamimidoyl)benzoate 97% | AS47955 | 1g | $38 |
| Methyl 4-(N-hydroxycarbamimidoyl)benzoate 97% | AS47955 | 5g | $137 |
| Methyl 4-[amino(hydroxyimino)methyl]-benzenecarboxylate | 046883 | 1.00g | $33 |
| Methyl 4-[amino(hydroxyimino)methyl]-benzenecarboxylate | 046883 | 5.00g | $103 |
| More product size | |||
METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE price More Price(38)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Biosynth | QCA69505 | Methyl 4-[amino(hydroxyimino)methyl]-benzenecarboxylate | 65695-05-8 | 10g | $472 | 2026-06-04 | Buy |
| Activate Scientific | AS47955 | Methyl 4-(N-hydroxycarbamimidoyl)benzoate 97% | 65695-05-8 | 1g | $38 | 2026-06-04 | Buy |
| Activate Scientific | AS47955 | Methyl 4-(N-hydroxycarbamimidoyl)benzoate 97% | 65695-05-8 | 5g | $137 | 2026-06-04 | Buy |
| Matrix Scientific | 046883 | Methyl 4-[amino(hydroxyimino)methyl]-benzenecarboxylate | 65695-05-8 | 1.00g | $33 | 2026-05-18 | Buy |
| Matrix Scientific | 046883 | Methyl 4-[amino(hydroxyimino)methyl]-benzenecarboxylate | 65695-05-8 | 5.00g | $103 | 2026-05-18 | Buy |
METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE Chemical Properties,Uses,Production
Synthesis
1129-35-7
![METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE](/CAS/GIF/65695-05-8.gif)
65695-05-8
General procedure for the synthesis of methyl 4-(N-hydroxyformamidinyl)benzoate (IV) from methyl 4-cyanobenzoate (III): methyl 4-cyanobenzoate (III) (2.50kg, 1wt) was dissolved in methanol (7.5L, 3vol) and diluted with methyl tert-butyl ether (9.3kg, 3.7wt). Aqueous hydroxylamine (50% solution; 1.23 kg, 0.5 wt, 1.2 eq.) was added slowly over about 0.5 h at 20-25 °C. The dosing line was flushed with methanol (1 kg, 0.4 wt) and the reaction was kept at 20-25 °C for about 12 hours. Upon completion of the reaction, the reaction mixture was cooled to 5±5°C and aged at this temperature for 3 hours. The product, methyl 4-(N'-hydroxyformamidinyl)benzoate (IV), was isolated by filtration, washed with methyl tert-butyl ether (2 x 5.5 kg, 2 x 2.2 wt) and dried under a stream of nitrogen for about 4 h to give the product (2.38 kg, 93% yield).
References
[1] Patent: WO2017/220446, 2017, A1. Location in patent: Page/Page column 26
[2] Journal of Labelled Compounds and Radiopharmaceuticals, 2012, vol. 55, # 2, p. 71 - 79
[3] Organic Letters, 2017, vol. 19, # 11, p. 2885 - 2888
METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Career Henan Chemica Co | +86-0371-86658258 +86-13203830695 | laboratory@coreychem.com | China | 30203 | 58 |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131885 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Hunan Hui Bai Shi Biotechnology Co., Ltd. | 0731-85526065 13308475853 | ivy@hnhbsj.com | China | 7236 | 62 |
| Shanghai XinKai Chemical Technology Co., Ltd. | 021-58930698 15921516558 | zhangyichao84@126.com | China | 971 | 55 |
| Nanjing XiZe Biotechnology CO., Ltd. | 025-66023220 15250997978 | 1511893459@qq.com | China | 4777 | 55 |
| Shanghai YuanYe Biotechnology Co., Ltd. | 15026964105 | 2881489226@qq.com | China | 89667 | 60 |
| Changzhou Hopschain Chemical Co.,Ltd. | 85528066 13775048983 | sales@hopschem.com | China | 31548 | 55 |
| Aikon International Limited | 025-66113011 19370895928 | qzhang@aikonchem.com | China | 15390 | 58 |
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