Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>Methyl 3-amino-4-fluorobenzenecarboxylate

Methyl 3-amino-4-fluorobenzenecarboxylate

Methyl 3-amino-4-fluorobenzenecarboxylate Structure
Methyl 3-amino-4-fluorobenzenecarboxylate structure
CAS No.
369-26-6
Chemical Name:
Methyl 3-amino-4-fluorobenzenecarboxylate
Synonyms
Methyl 3-amino-4-fluorobenzoate;2-Fluoro-5-(methoxycarbonyl)aniline;Methyl 3-amino-4-fluorobenzoate 99%;Methyl 3-amino-4-fluorobenzenecarboxylate;Benzoic acid, 3-amino-4-fluoro-, methyl ester;methyl 3-amino-4-fluorobenzoate(SALTDATA: HCl 0.7H2O);3-amino-4-fluoro-Benzoic acid methyl ester (8CI 9CI ACI);Benzoic acid, 3-amino-4-fluoro-, methyl ester (8CI, 9CI, ACI)
CBNumber:
CB7830853
Molecular Formula:
C8H8FNO2
Molecular Weight:
169.15
MDL Number:
MFCD08689743
MOL File:
369-26-6.mol
MSDS File:
SDS
Last updated:2026-09-12 18:55:07
Request For Quotation

Methyl 3-amino-4-fluorobenzenecarboxylate Properties

Melting point 66-69
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form crystalline solid
color Beige

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
HazardClass  IRRITANT
HS Code  2922498590

Methyl 3-amino-4-fluorobenzenecarboxylate price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Apolloscientific PC7646 Methyl 3-amino-4-fluorobenzoate 99% 369-26-6 1g $21 2026-06-04 Buy
Apolloscientific PC7646 Methyl 3-amino-4-fluorobenzoate 99% 369-26-6 5g $24 2026-06-04 Buy
Apolloscientific PC7646 Methyl 3-amino-4-fluorobenzoate 99% 369-26-6 25g $63 2026-06-04 Buy
Activate Scientific AS23360 Methyl 3-Amino-4-fluorobenzoate 98% 369-26-6 1g $26 2026-06-04 Buy
Activate Scientific AS23360 Methyl 3-Amino-4-fluorobenzoate 98% 369-26-6 5g $54 2026-06-04 Buy
Product number Packaging Price Buy
PC7646 1g $21 Buy
PC7646 5g $24 Buy
PC7646 25g $63 Buy
AS23360 1g $26 Buy
AS23360 5g $54 Buy

Methyl 3-amino-4-fluorobenzenecarboxylate Chemical Properties, Uses, Production

Synthesis

Methyl 4-fluoro-3-nitrobenzoate

329-59-9

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE

369-26-6

Step B: Synthesis of methyl 3-amino-4-fluorobenzoate; Methyl 4-fluoro-3-nitrobenzoate (6.57 g, 33 mmol) was dissolved in EtOAc (75 mL) and 10% palladium carbon catalyst (0.66 g) was added. The reaction mixture was transferred to a Fisher-Porter flask and mounted on a hydrogenation unit. The flask was charged with hydrogen (25 psi) and the reaction mixture was stirred overnight at room temperature. Upon completion of the reaction, the catalyst was removed by filtration through a diatomaceous earth pad, followed by concentration of the filtrate to give a yellow oily product which deepened in color on standing and in quantitative yield (5.51 g, 33 mmol). Mass spectrometry (ESI) showed m/z = 170 [M + H]+.

References

[1] Patent: WO2009/76140, 2009, A1. Location in patent: Page/Page column 186
[2] Journal of Organic Chemistry, 1990, vol. 55, # 7, p. 2034 - 2044
[3] Synlett, 2010, # 20, p. 3019 - 3022
[4] Patent: WO2010/126922, 2010, A1. Location in patent: Page/Page column 62
[5] Zhurnal Organicheskoi Khimii, 1972, vol. 8, p. 803,804; engl. Ausg. S. 813, 814

Methyl 3-amino-4-fluorobenzenecarboxylate Preparation Products And Raw materials

Raw materials

Methanol Methyl 4-fluoro-3-nitrobenzoate 3-Amino-4-fluorobenzoic acid Ethyl acetate Hydrogen

Preparation Products

Methyl 3-amino-4-fluorobenzenecarboxylate Suppliers

Global Suppliers ( 96)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35884 56
Nanjing Chemlin Chemical Co., Ltd 025-83697070 13770331960 info@chemlin.com.cn China 16305 64
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shanghai civi chemical technology co.,Ltd 86-21-34053660 sale@labgogo.com China 9853 52
9ding chemical ( Shanghai) Limited 4009209199 sales@9dingchem.com China 18201 56
Shanghai Raise Chemical Technology Co.,Ltd +86-021-50935922 China 7854 55
Bide Pharmatech Ltd. 400-164-7117 18317119277 product02@bidepharm.com China 40000 60
Wuxi Zhongkun Biochemical Technology Co., Ltd. 0510-85629785 18013409632; sales@reading-chemicals.com China 15165 58
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Energy Chemical 61
Wuhan Chemwish Technology Co., Ltd 56
Nanjing Chemlin Chemical Co., Ltd 64
Shanghai Hanhong Scientific Co.,Ltd. 64
Shanghai civi chemical technology co.,Ltd 52
9ding chemical ( Shanghai) Limited 56
Shanghai Raise Chemical Technology Co.,Ltd 55
Bide Pharmatech Ltd. 60
Wuxi Zhongkun Biochemical Technology Co., Ltd. 58

View Latest Price from Methyl 3-amino-4-fluorobenzenecarboxylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methyl 3-amino-4-fluorobenzoate pictures 2026-08-25 Methyl 3-amino-4-fluorobenzoate
369-26-6
 $3.00-9.00 99% ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Methyl3-amino-4-fluorobenzenecarboxylate pictures 2026-02-02 Methyl3-amino-4-fluorobenzenecarboxylate
369-26-6
 5mg 99%HPLC 2000tons Shaanxi Dideu Medichem Co. Ltd
4-Chloro-5-(chlorosulfonyl)-2-fluorobenzoic acid pictures 2026-02-02 4-Chloro-5-(chlorosulfonyl)-2-fluorobenzoic acid
56447-54-2
 5mg 99%HPLC 2000tons Shaanxi Dideu Medichem Co. Ltd

Methyl 3-amino-4-fluorobenzenecarboxylate Spectrum

METHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE(369-26-6)1HNMRMETHYL 3-AMINO-4-FLUOROBENZENECARBOXYLATE(369-26-6)19FNMR

369-26-6 (Methyl 3-amino-4-fluorobenzenecarboxylate) Related Search:

3-Amino-2-piperidinone hydrochloride 2,6-Dioxopiperidine-3-ammonium chloride 3-Amino-1H-pyrrole-2,4-dicarboxylic acid diethyl ester Methyl 3-amino-4-fluorobenzenecarboxylate Methyl 4-amino-3-fluorobenzenecarboxylate
4-Fluoro-3-nitromethylbenzoate, [carbonyl-14C]- Methyl 2-chloro-4-fluoro-5-nitrobenzoate 2,4-Difluoro-5-nitrobenzoic acid methyl ester methyl 4-fluoro-3-(3-oxobutanamido)benzoate Methyl 5-amino-2,4-difluorobenzoate
Methyl 4-fluoro-3-nitrobenzoate Ethyl 3-amino-4-fluorobenzoate

1of3

Methyl 3-amino-4-fluorobenzoate 99% methyl 3-amino-4-fluorobenzoate(SALTDATA: HCl 0.7H2O) 2-Fluoro-5-(methoxycarbonyl)aniline Benzoic acid, 3-amino-4-fluoro-, methyl ester Benzoic acid, 3-amino-4-fluoro-, methyl ester (8CI, 9CI, ACI) 3-amino-4-fluoro-Benzoic acid methyl ester (8CI 9CI ACI) Methyl 3-amino-4-fluorobenzoate Methyl 3-amino-4-fluorobenzenecarboxylate 369-26-6