1-ETHYNYL-2,6-DIMETHOXY-BENZENE
- CAS No.
- 126829-31-0
- Chemical Name:
- 1-ETHYNYL-2,6-DIMETHOXY-BENZENE
- Synonyms
- 2,6-Dimethoxyphenylacetylene;2-Ethynyl-1,3-diMethoxybenzene;1,3-Dimethoxy-2-ethynylbenzene;1-ETHYNYL-2,6-DIMETHOXY-BENZENE;Benzene, 2-ethynyl-1,3-diMethoxy-
- CBNumber:
- CB7845457
- Molecular Formula:
- C10H10O2
- Molecular Weight:
- 162.19
- MDL Number:
- MFCD08703538
- MOL File:
- 126829-31-0.mol
- MSDS File:
- SDS
1-ETHYNYL-2,6-DIMETHOXY-BENZENE price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | E932205 | 2-Ethynyl-1,3-dimethoxybenzene | 126829-31-0 | 50mg | $130 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | CHM0371587 | 1-ETHYNYL-2,6-DIMETHOXY-BENZENE 95.00% | 126829-31-0 | 5MG | $496.95 | 2021-12-16 | Buy |
| Matrix Scientific | 120028 | 2-Ethynyl-1,3-dimethoxybenzene 95+% | 126829-31-0 | 1g | $990 | 2021-12-16 | Buy |
| Matrix Scientific | 120028 | 2-Ethynyl-1,3-dimethoxybenzene 95+% | 126829-31-0 | 250mg | $396 | 2021-12-16 | Buy |
| Ambeed | A410574 | 2-Ethynyl-1,3-dimethoxybenzene 95% | 126829-31-0 | 1g | $418 | 2021-12-16 | Buy |
1-ETHYNYL-2,6-DIMETHOXY-BENZENE Chemical Properties,Uses,Production
Synthesis Reference(s)
Tetrahedron Letters, 31, p. 6753, 1990 DOI: 10.1016/S0040-4039(00)97162-4
Synthesis
1242030-69-8
126829-31-0
GENERAL PROCEDURE: To a 25 mL round-bottomed flask, (2,6-dimethoxyphenyl)ethynyltrimethylsilane (1 mmol) and 5 mL of anhydrous tetrahydrofuran were added under nitrogen protection. Subsequently, tert-butylammonium fluoride (0.5 mmol) in 1 M tetrahydrofuran solution was slowly added to this solution. During the reaction, the colorless solution gradually changed to light to dark brown. The reaction mixture was stirred at room temperature for 2 hours. After completion of the reaction, silica gel (500 mg) was added to the mixture, followed by evaporation of the solvent under reduced pressure to obtain a silica gel plug. This silica plug was loaded on a silica gel column (2 cm × 5 cm) and eluted using hexane solution containing 5% ethyl acetate. The eluate corresponding to the product spot was collected and the solvent was evaporated under reduced pressure to finally obtain the target product 2-alkynyl-1,3-dimethoxybenzene.
References
[1] Bioorganic and Medicinal Chemistry, 2011, vol. 19, # 14, p. 4355 - 4365
[2] Advanced Synthesis and Catalysis, 2010, vol. 352, # 1, p. 201 - 211
[3] Organic Letters, 2014, vol. 16, # 3, p. 948 - 951
1-ETHYNYL-2,6-DIMETHOXY-BENZENE Preparation Products And Raw materials
1-ETHYNYL-2,6-DIMETHOXY-BENZENE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-2158073036 | info@dakenam.com | China | 12934 | 58 |
| Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8826 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 12274 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| ShenZhen Trendseen Biological Technology Co.,Ltd. | 13417589054 | trendseenbio@gmail.com | China | 11681 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49980 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52924 | 58 | |
| Amadis Chemical Company Limited | 571-89925085 | sales@amadischem.com | China | 131957 | 58 |
| Shanghai Longsheng chemical Co.,Ltd. | 021-58099652-8005 13585536065 | bin.wu@shlschem.com | China | 9810 | 59 |
