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4'-Bromo-3'-methylacetophenone

4'-Bromo-3'-methylacetophenone structure

CAS No.: 37074-40-1

Chemical Name:: 4'-Bromo-3'-methylacetophenone

Synonyms: Fluralaner Impurity 29;3-Methyl-4-bromoacetophenone;NSC 405623;Fluralaner-003;4-Bromo-3-methylacetophenone;4-bromo-3-methylbenzenethylone;4'-Bromo-3'-methylacetophenone;Ethanone, 1-(4-broMo-3-Methylphenyl)-

CBNumber:: CB7947102

Molecular Formula:: C9H9BrO

Molecular Weight:: 213.07

MDL Number:: MFCD00045017

MOL File:: 37074-40-1.mol

MSDS File:: SDS

Last updated:2026-05-28 03:09:46

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4'-Bromo-3'-methylacetophenone Properties

Melting point	31-32 °C
Boiling point	157-159 °C(Press: 19 Torr)
Density	1.388±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
form	fused solid
color	Pale lemon

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P271-P260-P280
HS Code	2914390090

4'-Bromo-3'-methylacetophenone price More Price(47)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
TRC	TRC-B697460-1G	1-(4-Bromo-3-methylphenyl)ethanone	37074-40-1	1g	$96	2026-06-03	Buy
Biosynth	FB70251	4'-Bromo-3'-methylacetophenone, 98%	37074-40-1	1g	$150	2026-06-04	Buy
Biosynth	FB70251	4'-Bromo-3'-methylacetophenone, 98%	37074-40-1	2g	$171.62	2026-06-04	Buy
Biosynth	FB70251	4'-Bromo-3'-methylacetophenone, 98%	37074-40-1	5g	$285.75	2026-06-04	Buy
Biosynth	FB70251	4'-Bromo-3'-methylacetophenone, 98%	37074-40-1	10g	$952.6	2026-06-04	Buy

Product number	Packaging	Price	Buy
TRC-B697460-1G	1g	$96	Buy
FB70251	1g	$150	Buy
FB70251	2g	$171.62	Buy
FB70251	5g	$285.75	Buy
FB70251	10g	$952.6	Buy

4'-Bromo-3'-methylacetophenone Chemical Properties, Uses, Production

Uses

4'-Bromo-3'-methylacetophenone is a versatile building block that is used in the synthesis of many complex compounds. It can be used as a reactant, reagent, or speciality chemical.

Synthesis

A solution of 4-bromo-3-methylbenzaldehyde (4 g, 20 mmol) in dry tetrahydrofuran (40 mL) was cooled to 0C under nitrogen atmosphere, and then methyl magnesium bromide (20 mL, 1N in tetrahydrofuran) was added dropwise. The ice bath was removed, and the mixture was stirred for 2 hours. Ammonium chloride aqueous (40 mL) was added and the mixture was extracted with dichloromethane (20 mL * 3). The organic phase was dried by sodium sulphate, filtered and concentrated to give a residue. The residue was purified by column chromatography (silica gel, petroleum ether/ethyl acetate = 5:1) to give 1-(4-bromo-3-methylphenyl)ethanol. Colorless oil, yield 4.0 g, 93%. Pyridinium chlorochromate (48 g, 223 mmol) was added to a solution of 1-(4-bromo-3-methylphenyl)ethanol (31.9 g, 148 mmol) in dichloromethane (800 mL). The mixture was stirred at room temperature for 2 hours. The mixture was concentrated to give a residue. The residue was purified by column chromatography (silica gel, petroleum ether/ethyl acetate = 25:1) to give 4'-Bromo-3'-methylacetophenone. Yield 27.3 g, 87%.
Synthesis_37074-40-1 Figure Synthesis of 4'-Bromo-3'-methylacetophenone

References

[1] Patent: WO2015/1024, 2015, A1. Location in patent: Page/Page column 68-69

4'-Bromo-3'-methylacetophenone synthesis

Synthesis of 4'-Bromo-3'-methylacetophenone from Ethanone, 1-(4-amino-3-methylphenyl)- (9CI)

4'-Bromo-3'-methylacetophenone Preparation Products And Raw materials

Raw materials

Benzenemethanol, 4-bromo-α,3-dimethyl- N-(4-acetyl-2-methylphenyl)acetamide 4-Bromo-n-methoxy-n,3-dimethylbenzamide Ethanone, 1-(4-amino-3-methylphenyl)- (9CI) 4-Bromo-3-methyl-benzaldehyde

4-Bromo-3-methylbenzonitrile 4-Bromo-3-methylbenzoic acid Methyllithium Acetyl chloride Methylmagnesium Bromide

2-Methylacetanilide Methylmagnesium iodide

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Preparation Products

4-acetyl-2-methylbenzoic acid

4'-Bromo-3'-methylacetophenone Suppliers

Global Suppliers ( 96)

Supplier	Tel	Email	Country	ProdList	Advantage
Nanjing Chemlin Chemical Co., Ltd	025-83697070 13770331960	info@chemlin.com.cn	China	16305	64
Shandong Xiya Chemical Co., Ltd	13355009207 13355009207	3007715519@qq.com	China	18722	57
Hangzhou Sage Chemical Co., Ltd.	+86057186818502 13588463833	info@sagechem.com	China	10265	58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	025-66113011 13913916777	cfzhang@aikonchem.com	China	19902	55
9ding chemical ( Shanghai) Limited	4009209199	sales@9dingchem.com	China	18201	56
Shanghai Aladdin Bio-Chem Technology Co.,LTD	400-6206333 13167063860	anhua.mao@aladdin-e.com	China	29985	65
SynAsst Chemical.	021-60343070		China	12731	55
Shanghai Raise Chemical Technology Co.,Ltd	+86-021-50935922		China	7854	55
EnliPharma Technology Co., Ltd	0551-66399836 18955197623	sales@enlipharma.com	China	1875	55
CEG Chemical Science&Technology Co., Ltd.	Mobile:13665161512		China	1784	58

Supplier	Advantage
Nanjing Chemlin Chemical Co., Ltd	64
Shandong Xiya Chemical Co., Ltd	57
Hangzhou Sage Chemical Co., Ltd.	58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.	55
9ding chemical ( Shanghai) Limited	56
Shanghai Aladdin Bio-Chem Technology Co.,LTD	65
SynAsst Chemical.	55
Shanghai Raise Chemical Technology Co.,Ltd	55
EnliPharma Technology Co., Ltd	55
CEG Chemical Science&Technology Co., Ltd.	58

Unveiling the Versatility of 4'-Bromo-3'-methylacetophenone: A Catalyst for Innovation in Chemical Synthesis and Application
4'-Bromo-3'-methylacetophenone, a notable compound in the realm of organic chemistry, exemplifies versatility and efficacy.
May 8,2024

4'-Bromo-3'-methylacetophenone:Synthesis,Applications
4'-Bromo-3'-methylacetophenone is a white organic compound which can serve as an intermediate in the applications of various b....
Mar 6,2023

View Latest Price from 4'-Bromo-3'-methylacetophenone manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-03-20	4'-Bromo-3'-methylacetophenone 37074-40-1	$10.00	1KG	99%	10 mt	Hebei Chuanghai Biotechnology Co., Ltd
2024-04-24	4'-Bromo-3'-methylacetophenone 37074-40-1	$30.00-100.00	1kg	99.93%	1000kg per week	Ouhuang Engineering Materials (Hubei) Co., Ltd
2019-07-14	4'-Bromo-3'-methylacetophenone 37074-40-1	$1.00	1KG	99%	100kg	Career Henan Chemical Co

4'-Bromo-3'-methylacetophenone
37074-40-1
$10.00
99%
Hebei Chuanghai Biotechnology Co., Ltd

4'-Bromo-3'-methylacetophenone
37074-40-1
$30.00-100.00
99.93%
Ouhuang Engineering Materials (Hubei) Co., Ltd

4'-Bromo-3'-methylacetophenone
37074-40-1
$1.00
99%
Career Henan Chemical Co

4'-Bromo-3'-methylacetophenone Spectrum

4'-Bromo-3'-methylacetophenone(37074-40-1)¹HNMR

37074-40-1 (4'-Bromo-3'-methylacetophenone ) Related Search:

4'-Chloro-2',5'-difluoroacetophenone 1-(4-Chloro-2-trifluoromethyl-phenyl)-ethanone 4'-BroMo-2',5'-difluoroacetophenone 1-(3-Fluoro-5-hydroxyphenyl)ethanone 4-Acetyl-2-methylbenzonitrile

Ethanone, 1-[3-hydroxy-4-(phenylMethoxy)phenyl]- 1-(4-Bromo-2-chlorophenyl)propan-1-one 1-(3-Hydroxy-5-Methylphenyl)ethanone 1-(3-broMo-5-nitrophenyl)ethan-1-one 5-BroMo-2-hydroxy-4-Methylacetophenone

4'-Bromo-3'-methylacetophenone 1-(4-Bromo-3-methylphenyl)-5-chloro-1-oxopentane 6-Bromo-5-methylisatin 1-(4-Bromo-3-methylphenyl)-7-chloro-1-oxoheptane 1-(4-Bromo-3-methylphenyl)-6-chloro-1-oxohexane

6-Bromo-5-ethylisatin 4-Bromo-5-methylisatinic acid sodium salt 2-Bromo-3-methylanthraquinone

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Ethanone, 1-(4-broMo-3-Methylphenyl)- NSC 405623 Fluralaner-003 4'-Bromo-3'-methylacetophenone 4-Bromo-3-methylacetophenone 4-bromo-3-methylbenzenethylone 3-Methyl-4-bromoacetophenone Fluralaner Impurity 29 37074-40-1 Aromatic Acetophenones & Derivatives (substituted)