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2-Naphthalenethiol

CAS No.
91-60-1
Chemical Name:
2-Naphthalenethiol
Synonyms
NAPHTHALENE-2-THIOL;rpa2;RPA 2;2-Naphthyl thiol;2-CHLOROBENZENEMETHANETHIOL;rpano.2;renacit1;usafcy-4;Rpa no. 2;Renacit 1
CBNumber:
CB8123370
Molecular Formula:
C10H8S
Molecular Weight:
160.24
MDL Number:
MFCD00004086
MOL File:
91-60-1.mol
MSDS File:
SDS
Last updated:2026-05-28 03:33:00
Product description Number Pack Size Price
2-Naphthalenethiol 99% 270849 5g $72.4
2-Naphthalenethiol 99% 270849 25g $224
2-Naphthalenethiol >98.0%(GC)(T) N0020 25g $213
2-Naphthalenethiol >98.0%(GC)(T) N0020 250g $1913
RPA2 Purifiedbyimmunoaffinitychromatography. 527844 100ul $736
More product size

2-Naphthalenethiol Properties

Melting point 79-81 °C (lit.)
Boiling point 286 °C (lit.)
Density 1.22
refractive index 1.589-1.591
FEMA 3314 | 2-NAPHTHALENTHIOL
FLAVIS Number 12.033 | Naphthalene-2-thiol
Flash point 69 °C
storage temp. Inert atmosphere,Room Temperature
solubility diethyl ether: very soluble(lit.)
form Powder
pka 6+-.0.30(Predicted)
color Almost white to cream
Odor at 0.10 % in propylene glycol. sulfurous rubbery meaty roasted woody creamy artichoke
Odor Type sulfurous
Water Solubility Soluble in alcohol, dipropylene glycol. Soluble in water 34.4 mg/L @ 25°C.
Sensitive Air Sensitive
Merck 14,6379
JECFA Number 531
BRN 636389
InChI 1S/C10H8S/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7,11H
InChIKey RFCQDOVPMUSZMN-UHFFFAOYSA-N
SMILES Sc1ccc2ccccc2c1
LogP 3.75
CAS DataBase Reference 91-60-1(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) 2-NAPHTHALENTHIOL
EWG's Food Scores 1
FDA UNII SZ5U1S741V
NIST Chemistry Reference 2-Naphthalenethiol(91-60-1)
EPA Substance Registry System 2-Naphthalenethiol (91-60-1)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)Skull and Crossbones (GHS06)
GHS07,GHS06
Signal word  Warning
Hazard statements  H301-H315-H319-H335-H302
Precautionary statements  P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xn,Xi
Risk Statements  22-20/21/22
Safety Statements  36/37
RIDADR  UN 3335
WGK Germany  3
RTECS  QK3930000
13
Hazard Note  Harmful/Irritant
TSCA  TSCA listed
HS Code  29309070
Storage Class 11 - Combustible Solids
Hazard Classifications Acute Tox. 4 Oral
NFPA 704
1
1 0

2-Naphthalenethiol price More Price(55)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 270849 2-Naphthalenethiol 99% 91-60-1 5g $72.4 2026-04-30 Buy
Sigma-Aldrich 270849 2-Naphthalenethiol 99% 91-60-1 25g $224 2026-04-30 Buy
TCI Chemical N0020 2-Naphthalenethiol >98.0%(GC)(T) 91-60-1 25g $213 2026-04-30 Buy
TCI Chemical N0020 2-Naphthalenethiol >98.0%(GC)(T) 91-60-1 250g $1913 2026-04-30 Buy
Usbiological 527844 RPA2 Purifiedbyimmunoaffinitychromatography. 100ul $736 2026-06-03 Buy
Product number Packaging Price Buy
270849 5g $72.4 Buy
270849 25g $224 Buy
N0020 25g $213 Buy
N0020 250g $1913 Buy
527844 100ul $736 Buy

2-Naphthalenethiol Chemical Properties,Uses,Production

Description

2-Naphthalenthiol has a disagreeable mercaptan-like odor. May be prepared by catalytic hydrogenation of a sulfonic acid derivative of naphthalene; by reduction of naphthalenesulfonyl chloride with zinc.

Chemical Properties

2-Naphthyl mercaptan has a disagreeable sulfurous, mushroom, meaty odor

Chemical Properties

Almost white to cream powder

Uses

2-Thionaphthol was used in the preparation of cholesterol monolayer and multilayer Langmuir- Blodgett (LB) films. The magnetic resonance shift for a self-assembled monolayer of 2-naphthalenethiol was studied that suggested considerable promise in flexible and transparent photonic devices for biological and chemical sensing.

Preparation

By catalytic hydrogenation of a sulfonic acid derivative of naphthalene; by reduction of naphthalenesulfonyl chloride with zinc.

Definition

ChEBI: 2-Naphthalenethiol is a member of naphthalenes.

Taste threshold values

Taste characteristics at 10 ppm: sulfurous, meaty, brown, roasted, chicken, eggy with a slight nutty nuance

Synthesis Reference(s)

The Journal of Organic Chemistry, 31, p. 3980, 1966 DOI: 10.1021/jo01350a023
Tetrahedron Letters, 37, p. 4523, 1996 DOI: 10.1016/0040-4039(96)00873-8

General Description

The magnetic resonance shift for a self-assembled monolayer of 2-naphthalenethiol was studied that suggested considerable promise in flexible and transparent photonic devices for biological and chemical sensing.

Safety Profile

Poison by ingestion and intraperitoneal routes. A mosquito larvicide. When heated to decomposition it emits highly toxic fumes of SOx.

Purification Methods

It is steam volatile. It has to be distilled under Ar or N2, as it oxidises to the disulfide, and crystallises from EtOH. The S-methyl derivative has m 104-105o (from *C6H6/pet ether), and the S-ethyl derivative M 188.2, has m 16o and b 175-170.5o/15mm. The S-acetate has m 53.5o and b 191o/15mm, and the diethylamine salt forms yellow needles m 107o from dioxane. [Beilstein 6 H 657, 6 I 316, 6 II 610, 6 III 3006, 6 IV 4312.]

580-13-2
91-60-1
Synthesis of 2-Naphthalenethiol from 2-Bromonaphthalene
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2-Naphthalenethiol pictures 2026-07-09 2-Naphthalenethiol
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$2.00-10.00 1KG 99% Henan Fengda Chemical Co., Ltd
2-Naphthalenethiol  pictures 2025-12-29 2-Naphthalenethiol
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1kg 90% 10mt per month Changzhou waston chemical technology Co.,Ltd
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$2400.00 1Kg 98 500 Kg R&D Scientific Inc.
2-Metcaptonaphthalene 2-naphthylthiol beta-Mercaptonaphthalene beta-Naphthyl mercaptan beta-naphthylmercaptan mercaptanbeta-naphtalenique naphthalenethiol(non-specificname) Renacit 1 renacit1 RPA 2 Rpa no. 2 rpano.2 Thio-2-naphthol (beta) Thionaphthol USAF cy-4 usafcy-4 Vulcamel TBN vulcameltbn Naphthalene-2-thiol 98% 2-Mercaptonaphthalene Thio-2-naphthol 2-Thionaphthol 98% Naphthalene-2-thiol, 2-Naphthyl mercaptan, 2-Sulphanylnaphthalene 2-Naphthalenethiol, 99% 5GR 2- naphthalenedithiol SPECS AQ-917/40186368 O-CHLOROTHIOANISOLE THIO-BETA-NAPHTHOL THIO-2-NAPHTHOL BETA-NAPHTHALENETHIOL BETA-THIONAPHTHOL 2-MERCAPTONAPHTHALENE 2-CHLOROBENZENEMETHANETHIOL 2-CHLOR-ALPHA-TOLUENETHIOL 2-NAPTHTHYL MERCAPTAN 2-NAPHTHYL MERCAPTAN 2-NAPHTHALENETHIOL 2-NAPHTHALENETHIOLE 2-THIONAPHTHOL 2-Thionaphthol, 98+% beta-Thionaphenol 2-Naphthalenethiol 99% 2-NAPHTHALENTHIOL Naphthalin-2-thiol SS-THIONAPHTHOL 2-Naphthyl mercaptan, Thio-2-naphthol (β) 2-Naphthalenethiol,99% 2-Naphthalenethiol> 2-Naphthalenethiol ISO 9001:2015 REACH β-Thionaphthol β-Naphthalenethiol 2-phthalenethiol 2-Naphthyl thiol NAPHTHALENE-2-THIOL rpa2 91-60-1 39178-00-8 90-60-1 Sulfur Compounds