Naphthalin-2-thiol
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- CAS-Nr.
- 91-60-1
- Bezeichnung:
- Naphthalin-2-thiol
- Englisch Name:
- 2-Naphthalenethiol
- Synonyma:
- NAPHTHALENE-2-THIOL;rpa2;RPA 2;2-Naphthyl thiol;2-CHLOROBENZENEMETHANETHIOL;rpano.2;renacit1;usafcy-4;Rpa no. 2;Renacit 1
- CBNumber:
- CB8123370
- Summenformel:
- C10H8S
- Molgewicht:
- 160.24
- MOL-Datei:
- 91-60-1.mol
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Naphthalin-2-thiol Eigenschaften
- Schmelzpunkt:
- 79-81 °C (lit.)
- Siedepunkt:
- 286 °C (lit.)
- Dichte
- 1.22
- Brechungsindex
- 1.589-1.591
- FEMA
- 3314 | 2-NAPHTHALENTHIOL
- Flammpunkt:
- 69 °C
- storage temp.
- Inert atmosphere,Room Temperature
- Löslichkeit
- diethyl ether: very soluble(lit.)
- Aggregatzustand
- Powder
- pka
- 6+-.0.30(Predicted)
- Farbe
- Almost white to cream
- Geruch (Odor)
- at 0.10 % in propylene glycol. sulfurous rubbery meaty roasted woody creamy artichoke
- Geruchsart
- sulfurous
- Wasserlöslichkeit
- Soluble in alcohol, dipropylene glycol. Soluble in water 34.4 mg/L @ 25°C.
- Sensitive
- Air Sensitive
- Merck
- 14,6379
- JECFA Number
- 531
- BRN
- 636389
- InChI
- 1S/C10H8S/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7,11H
- InChIKey
- RFCQDOVPMUSZMN-UHFFFAOYSA-N
- SMILES
- Sc1ccc2ccccc2c1
- LogP
- 3.75
- CAS Datenbank
- 91-60-1(CAS DataBase Reference)
- NIST chemische Informationen
- 2-Naphthalenethiol(91-60-1)
- EPA chemische Informationen
- 2-Naphthalenethiol (91-60-1)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
| Kennzeichnung gefährlicher |
Xn,Xi |
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| R-Sätze: |
22-20/21/22 |
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| S-Sätze: |
36/37 |
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| RIDADR |
UN 3335 |
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| WGK Germany |
3 |
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| RTECS-Nr. |
QK3930000 |
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| F |
13 |
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| Hazard Note |
Harmful/Irritant |
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| TSCA |
TSCA listed |
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| HS Code |
29309070 |
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| Speicherklasse |
11 - Combustible Solids |
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| Hazard Classifications |
Acute Tox. 4 Oral |
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| Bildanzeige (GHS) |
 
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| Alarmwort |
Warnung
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| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H301 |
Giftig bei Verschlucken. |
Akute Toxizität oral |
Kategorie 3 |
Achtung |
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P264, P270, P301+P310, P321, P330,P405, P501 |
| H302 |
Gesundheitsschädlich bei Verschlucken. |
Akute Toxizität oral |
Kategorie 4 |
Warnung |
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P264, P270, P301+P312, P330, P501 |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
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P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
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P264, P280, P305+P351+P338,P337+P313P |
| H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizität (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
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| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
| P405 |
Unter Verschluss aufbewahren. |
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Naphthalin-2-thiol Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R22:Gesundheitsschädlich beim Verschlucken.
R20/21/22:Gesundheitsschädlich beim Einatmen,Verschlucken und Berührung mit der Haut.
S-Sätze Betriebsanweisung:
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
Beschreibung
2-Naphthalenthiol has a disagreeable mercaptan-like odor. May be prepared by catalytic hydrogenation of a sulfonic acid derivative of naphthalene; by reduction of naphthalenesulfonyl chloride with zinc.
Chemische Eigenschaften
Almost white to cream powder
Verwenden
2-Thionaphthol was used in the preparation of cholesterol monolayer and multilayer Langmuir- Blodgett (LB) films. The magnetic resonance shift for a self-assembled monolayer of 2-naphthalenethiol was studied that suggested considerable promise in flexible and transparent photonic devices for biological and chemical sensing.
synthetische
By catalytic hydrogenation of a sulfonic acid derivative of naphthalene; by reduction of naphthalenesulfonyl chloride with zinc.
Allgemeine Beschreibung
The magnetic resonance shift for a self-assembled monolayer of 2-naphthalenethiol was studied that suggested considerable promise in flexible and transparent photonic devices for biological and chemical sensing.
Sicherheitsprofil
Poison by ingestion and
intraperitoneal routes. A mosquito larvicide.
When heated to decomposition it emits
highly toxic fumes of SOx.
läuterung methode
It is steam volatile. It has to be distilled under Ar or N2, as it oxidises to the disulfide, and crystallises from EtOH. The S-methyl derivative has m 104-105o (from *C6H6/pet ether), and the S-ethyl derivative M 188.2, has m 16o and b 175-170.5o/15mm. The S-acetate has m 53.5o and b 191o/15mm, and the diethylamine salt forms yellow needles m 107o from dioxane. [Beilstein 6 H 657, 6 I 316, 6 II 610, 6 III 3006, 6 IV 4312.]
Naphthalin-2-thiol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Naphthalin-2-thiol Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 268)Lieferanten
91-60-1(Naphthalin-2-thiol)Verwandte Suche:
- 2-Metcaptonaphthalene
- 2-naphthylthiol
- beta-Mercaptonaphthalene
- beta-Naphthyl mercaptan
- beta-naphthylmercaptan
- mercaptanbeta-naphtalenique
- naphthalenethiol(non-specificname)
- Renacit 1
- renacit1
- RPA 2
- Rpa no. 2
- rpano.2
- Thio-2-naphthol (beta)
- Thionaphthol
- USAF cy-4
- usafcy-4
- Vulcamel TBN
- vulcameltbn
- Naphthalene-2-thiol 98%
- 2-Mercaptonaphthalene
Thio-2-naphthol
- 2-Thionaphthol 98%
- Naphthalene-2-thiol, 2-Naphthyl mercaptan, 2-Sulphanylnaphthalene
- 2-Naphthalenethiol, 99% 5GR
- 2- naphthalenedithiol
- SPECS AQ-917/40186368
- O-CHLOROTHIOANISOLE
- THIO-BETA-NAPHTHOL
- THIO-2-NAPHTHOL
- BETA-NAPHTHALENETHIOL
- BETA-THIONAPHTHOL
- 2-MERCAPTONAPHTHALENE
- 2-CHLOROBENZENEMETHANETHIOL
- 2-CHLOR-ALPHA-TOLUENETHIOL
- 2-NAPTHTHYL MERCAPTAN
- 2-NAPHTHYL MERCAPTAN
- 2-NAPHTHALENETHIOL
- 2-NAPHTHALENETHIOLE
- 2-THIONAPHTHOL
- 2-Thionaphthol, 98+%
- beta-Thionaphenol
- 2-Naphthalenethiol 99%
- 2-NAPHTHALENTHIOL
- Naphthalin-2-thiol
- SS-THIONAPHTHOL
- 2-Naphthyl mercaptan, Thio-2-naphthol (β)
- 2-Naphthalenethiol,99%
- 2-Naphthalenethiol>
- 2-Naphthalenethiol ISO 9001：2015 REACH
- β-Thionaphthol
- β-Naphthalenethiol
- 2-phthalenethiol
- 2-Naphthyl thiol
- NAPHTHALENE-2-THIOL
- rpa2
- 91-60-1
- 39178-00-8
- 90-60-1
- Sulfur Compounds
