Bis(acetonitrile)dichloropalladium(II)
- CAS No.
- 14592-56-4
- Chemical Name:
- Bis(acetonitrile)dichloropalladium(II)
- Synonyms
- (MeCN)2PdCl2;Palladium, bis(acetonitrile)dichloro-;DICHLOROBIS(ACETONITRILE)PALLADIUM(II);bis(acetonitrile)dichloropalladium;BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;BIS(ACETONITRILE)PALLADIUM(II) DICHLORIDE;TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;e)dichL;Bis(acetonitriL;Bis(Acetonitrile)Pd(II)
- CBNumber:
- CB8245652
- Molecular Formula:
- C4H6Cl2N2Pd
- Molecular Weight:
- 259.43
- MDL Number:
- MFCD00013122
- MOL File:
- 14592-56-4.mol
- MSDS File:
- SDS
- TDS File:
- TDS
| Melting point | 300 °C |
|---|---|
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in acetonitrile, acetone, chloroform |
| form | Fine Crystalline Powder |
| color | Orange to rust-brown |
| Water Solubility | insoluble |
| InChI | InChI=1S/2C2H3N.2ClH.Pd/c2*1-2-3;;;/h2*1H3;2*1H;/q;;;;+2/p-2 |
| InChIKey | RBYGDVHOECIAFC-UHFFFAOYSA-L |
| SMILES | C(#N)C.C(#N)C.[Pd](Cl)Cl |
| CAS DataBase Reference | 14592-56-4(CAS DataBase Reference) |
| UNSPSC Code | 12161600 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H311+H331 | |||||||||
| Precautionary statements | P280-P301+P310+P330-P302+P352+P312-P304+P340+P311 | |||||||||
| PPE | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges | |||||||||
| Hazard Codes | T,Xn | |||||||||
| Risk Statements | 23/24/25-36/37/38-20/21/22 | |||||||||
| Safety Statements | 16-27-36/37-45-36-26 | |||||||||
| RIDADR | UN 3077 9/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 28439090 | |||||||||
| Storage Class | 6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects |
|||||||||
| Hazard Classifications | Acute Tox. 3 Dermal Acute Tox. 3 Inhalation Acute Tox. 3 Oral |
|||||||||
| Limited Quantities | 5.0 kg (11 lbs) (solid) | |||||||||
| Excepted Quantities | Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L) | |||||||||
| NFPA 704 |
|
Bis(acetonitrile)dichloropalladium(II) price More Price(74)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 225657 | Bis(acetonitrile)dichloropalladium(II) 99% | 14592-56-4 | 500mg | $84.6 | 2026-04-30 | Buy |
| Sigma-Aldrich | 225657 | Bis(acetonitrile)dichloropalladium(II) 99% | 14592-56-4 | 5g | $551 | 2026-04-30 | Buy |
| TCI Chemical | B1676 | Bis(acetonitrile)palladium(II) Dichloride >98.0%(T) | 14592-56-4 | 1g | $237 | 2026-04-30 | Buy |
| TCI Chemical | B1676 | Bis(acetonitrile)palladium(II) Dichloride >98.0%(T) | 14592-56-4 | 5g | $889 | 2026-04-30 | Buy |
| Strem Chemicals | 46-0370 | Dichlorobis(acetonitrile)palladium(II), min. 97% min.97% | 14592-56-4 | 1g | $109 | 2026-04-30 | Buy |
Bis(acetonitrile)dichloropalladium(II) Chemical Properties, Uses, Production
Reaction
- Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
- Catalyst for the aza-Michael reaction of carbamates with enones.
- Catalyst for the rearrangement of allylic imidates to allylic amides.
- Catalyst for the Nazarov cyclization of α-alkoxy dienones.
- Catalyst for the diamination of conjugated dienes.
- Three component Michael addition, cyclization, cross-coupling reaction.
- C-H activation of indoles.
- Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.
Chemical Properties
Light yellow to Brown powder to crystaline.
Physical properties
Bis(acetonitrile)dichloropalladium(II) is a yellow-brown solid that is soluble in organic solvents. It is a reagent and a catalyst for reactions that require soluble Pd(II).The compound is similar to bis(benzonitrile)palladium dichloride.
Uses
suzuki reaction
Uses
It is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters.
Uses
Catalyst used in an ether-directed aza-Claisen rearrangement.
Preparation
Bis(acetonitrile)palladium dichloride is prepared by reacting two acetonitrile ligands and palladium(II) chloride.
Application
Synthesis of Oxindoles
To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), Bis(acetonitrile)dichloropalladium(II)
(3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred
at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to
room temperature, the reaction is diluted with EtOAc and filtered with a
glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.
General Description
This product has been enhanced for catalytic efficiency.
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Bis(acetonitrile)dichloropalladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Rock New Materials Co., Ltd. | 0917-8888777 18691786767 | liuwei@bjrock.com | China | 309 | 62 |
| Shanghai Bihe Biochemical Technology Co., Ltd | 13816464724 | colin@bihebio.com | China | 937 | 58 |
| Shandong Carbene New Material Technology Co., Ltd | 17829912583 17392550121 | sdcarbene@163.com | China | 825 | 58 |
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| ShangHai DEMO Chemical Co.,Ltd | 400-021-7337 2355568890 | sales@demochem.com | China | 2569 | 57 |
| Beijing HwrkChemical Technology Co., Ltd | 89508211 18501085097 | sales.bj@hwrkchemical.com | China | 9407 | 55 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
View Latest Price from Bis(acetonitrile)dichloropalladium(II) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-25 | Acetonitrile-dichloropalladium (2:1)
14592-56-4
|
$2.00-5.00 | 1kg | 99% | 100kg | ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD | |
 |
2026-03-20 | Bis(acetonitrile)dichloropalladium(II)
14592-56-4
|
$10.00 | 1KG | 99% | 5tons | Hebei Chuanghai Biotechnology Co., Ltd | |
 |
2024-04-27 | Acetonitrile-dichloropalladium
14592-56-4
|
$5.00 | 1kg | 99.92% | 50000tons | Ouhuang Engineering Materials (Hubei) Co., Ltd |
-
- Acetonitrile-dichloropalladium (2:1)
14592-56-4
- $2.00-5.00
- 99%
- ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
-
- Bis(acetonitrile)dichloropalladium(II)
14592-56-4
- $10.00
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Acetonitrile-dichloropalladium
14592-56-4
- $5.00
- 99.92%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
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