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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Structure
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) structure
CAS No.
887919-35-9
Chemical Name:
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
Synonyms
Pd132;Pd(amphos)Cl2;Pd(Amphos)2Cl2;PdCl2(Amphos)2;PdAMPHOS;(A-taPhos)2PdCl2;pall;BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II);Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II);(AMPHOS)2PDCL2
CBNumber:
CB8972714
Molecular Formula:
C32H56Cl2N2P2Pd
Molecular Weight:
708.07
MDL Number:
MFCD09265123
MOL File:
887919-35-9.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 04:48:25
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Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Properties

storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Powder
color yellow
Water Solubility Insoluble in water.
InChI InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;
InChIKey AWOFSUFKCXRJMV-UHFFFAOYSA-N
SMILES P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)(C(C)(C)C)[Pd+2]([Cl-])([Cl-])P(C1C=CC(N(C)C)=CC=1)(C(C)(C)C)C(C)(C)C
UNSPSC Code 12352101
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
TSCA  TSCA listed
HS Code  28439000
Storage Class 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard Classifications Carc. 1B Inhalation
NFPA 704
1
2 0

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) price More Price(77)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 678740 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 95% 887919-35-9 1g $179 2026-04-30 Buy
Sigma-Aldrich 678740 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) 95% 887919-35-9 5g $852 2026-04-30 Buy
TCI Chemical B6255 Bis[di-tert-butyl(4-dimethylaminophenyl)phosphine]dichloropalladium(II) 887919-35-9 1G $105 2026-04-30 Buy
Strem Chemicals 46-0825 Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos min.98% 887919-35-9 250mg $56 2026-04-30 Buy
Strem Chemicals 46-0825 Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos min.98% 887919-35-9 1g $163 2026-04-30 Buy
Product number Packaging Price Buy
678740 1g $179 Buy
678740 5g $852 Buy
B6255 1G $105 Buy
46-0825 250mg $56 Buy
46-0825 1g $163 Buy

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Chemical Properties, Uses, Production

Reaction

  1. Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.
  2. Useful catalyst for the Suzuki Cross-Coupling of benzyloxyethyltrifluoroborate.
Reactions of 887919-35-9

Chemical Properties

Yellow powder

Uses

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium is useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides.

Uses

Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Synthesis

To a 500 mL reaction was added 10 g (1,5-cyclooctadiene) palladium dichloride, the reaction flask was replaced with a nitrogen atmosphere,19.6 g of di-tert-butyl-4-dimethylaminophenylphosphine and 200 mL of anhydrous tetrahydrofuran were added. The mixture was stirred at room temperature for 16 hours; There was a solid precipitation; filtration and drying gave a pale yellow powder product bis (di-tert-butyl-4-dimethylaminophenylphosphine) palladium chloride. The yield was 97 percent.

References

[1] Patent: CN105237568, 2017, B. Location in patent: Paragraph 0064-0066

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) synthesis

14592-56-4
932710-63-9
887919-35-9
Synthesis of Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) from Bis(acetonitrile)dichloropalladium(II) and Bis(di-tert-butyl)-4-dimethylaminophenylphosphine

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Preparation Products And Raw materials

Raw materials

Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Palladium, bis(acetonitrile)dichloro-, (SP-4-1)- Dichloro(1,5-cyclooctadiene)palladium(II) Bis(acetonitrile)dichloropalladium(II)

Preparation Products

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Suppliers

Global Suppliers ( 357)
Supplier Tel Email Country ProdList Advantage
Xinxiang Runyu Material Co., Ltd. 166-166-37336996 15690792173 chenxi.song@runvmat.com China 282 55
Shaanxi Rock New Materials Co., Ltd. 0917-8888777 18691786767 liuwei@bjrock.com China 309 62
Beijing Guofang Dingsheng Technology Co., Ltd. 18610472091 gfdskj@163.com China 496 58
Wuhan Jiade Ruifeng New Materials Co., Ltd 18271874579 / 18971104330 18971104330 Xiaowei@JDchem.com.cn China 268 58
Leshan Bangsheng New Materials Co., Ltd 0833-2599138 19162614312 lsbangsheng@126.com China 558 58
BeiJing Greenchem Technology Co.,Ltd. 131-21959385 18804271668 chemrocking@bjgreenchem.com China 272 58
Sinocompound Catalysts Co., Ltd. 0512-67216630 67216634 sales@sinocompound.com China 252 64
Luoyang Heyi New Materials Co., Ltd 13674998441 18203623319 12409005@qq.com China 17 58
Chenzhou Gaoxin Platinum Industry Co., Ltd. 0735-2390599 13574551630;15073547586 1156989506@qq.com China 78 58
Wuhan Tuochuangda Technology Co., LTD 18627850571 tuochuangda@163.com China 89 58
Supplier Advantage
Xinxiang Runyu Material Co., Ltd. 55
Shaanxi Rock New Materials Co., Ltd. 62
Beijing Guofang Dingsheng Technology Co., Ltd. 58
Wuhan Jiade Ruifeng New Materials Co., Ltd 58
Leshan Bangsheng New Materials Co., Ltd 58
BeiJing Greenchem Technology Co.,Ltd. 58
Sinocompound Catalysts Co., Ltd. 64
Luoyang Heyi New Materials Co., Ltd 58
Chenzhou Gaoxin Platinum Industry Co., Ltd. 58
Wuhan Tuochuangda Technology Co., LTD 58

View Latest Price from Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium (II) pictures 2026-09-02 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium (II)
887919-35-9
 $8.00 1KG 99% Henan Fengda Chemical Co., Ltd
Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladium(II) pictures 2026-08-18 Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladium(II)
887919-35-9
 1KG 98% 100KG /month Shanghai Daken Advanced Materials Co.,Ltd
Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) pictures 2026-08-08 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
887919-35-9
 99.0%min 200kg Hangzhou ICH Biofarm Co., Ltd

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) Spectrum

BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(887919-35-9)1HNMRBIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(887919-35-9)31PNMR

887919-35-9 (Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)) Related Search:

(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole (S,S)-[2-(4'-i-Propyloxazolin-2'-yl)ferrocenyldiphenylphosphine, min. 97% Ruthenium(II) chloride mesitylene dimer Bis(diphenylphosphinophenyl)ether palladium (II) dichloride BrettPhos Pd G4
XPhos Pd G2 SPhos Pd G2 Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II), min. 98% Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II) (R)-(-)-1-[(S)-2-(Di(3,5-bis-trifluoromethylphenyl)phosphino)ferrocenyl]ethyldi(3,5-dimethylphenyl)phosphine
Dichloro(N,N,N',N'-tetramethylethylenediamine)palladium(II) (alphaR,alphaR)-1,1'-Bis[alpha-(dimethylamino)benzyl]-(S,S)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene Dichlorobis(tri-o-tolylphosphine)palladium(II) Dichlorobis(indenyl)titanium(IV) Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
dichlorobis(di-tert-butylphenylphosphine)palladium(II) Di-tert-butylphenylphosphine Bis(di-tert-butyl)-4-dimethylaminophenylphosphine

1of4

Pd(aMphos)Cl2, 15% Pd, Product of UMicore Bis[4-[bis(1,1-diMethylethyl)phosphino-κ… Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)- palladium(2+) ion bis(4-(di-tert-butylphosphanyl)-N,N-dimethylaniline) dichloride Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride 95+% Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% PdAmphos Pd(amphos)Cl2 / Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) palladium(2+) io Bis[4-[bis(1,1-diMethylethyl)phosphino-Palladium,bis[4-[bis(1,1-dimethylethyl)phosphino-kP]-N,N-dimethylbenzenamine]dichloro-, (SP-4-1)- Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II), min. 98% BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) Dichlorobis(di-tert-butyl-4-dimethylaminophenylphosphine)palladium(11) (SP-4-1)-Palladium dichloro-bis[4-[bis(1,1-dimethylethyl)phosphino-P]-N,N-dimethylbenzenamine] BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) PdCl2(AMphos)2 Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphino]palladiuM(II), Pd 15% Bis(di-tert-butyl(4-diMethyl Bis[(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine] palladiuM(II) chloride Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II), Pd 15% Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}dichloropalladium(II), Bis{4-[bis(tert-butyl)phosphanyl]-N,N-dimethylaniline}dichloropalladium(II) Bis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]dichloropalladiuM, 95% Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II) Dichlorobis[di-t-butyl(p-dimethylaminophenyl)phosphino]palladium(Ⅱ) Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) adium Bis[di-tert-butyL BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM ISO 9001：2015 REACH Bis(di-tert-butyl(4-methylaminophenyl)phosphine)dichloropalladium(II) Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphino]pa... Bis{bis(tert-butyl)[4-(dimethylamino)phenyl]phosphine}palladium(II) chloride (Pd-132) TIANFU-CHEM -BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM(II) bis[4- [bis(1,1-dimethylethyl)phosphino-kP]-N,N- dimethylbenzenamine]dichloro-palladium(II) Dichlorodi-tert-butyl - (4-dimethylaminophenyl) phosphopalladium (II) Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphino]palladium(II) (SP-4-1)-Bis[4-[bis(1,1-dimethylethyl)phosphino-κP]-N,N-dimethylbenzenamine]dichloropalladium (SP-4-1)-Bis[4-[bis(1,1-dimethylethyl)phosphino-κP]-N,N-dimethylbenzenamine]dichloropalladium (ACI) Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) ChemBeads Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) bis[4-bis(1,1-dimethylethylphosphino-kP]-N,N-dimethybenzenamine]dichloro-palladium(II) Di-tert-butyl-(4-dimethylaminophenyl)phosphine palladium(II) dichloride BIS(DI-TERT-BUTYL(4-DIMETHYLAMINOPHENYL)PHOSPHINE)DICHLOROPALLADIUM (AMPHOS)2PDCL2 (A-taPhos)2PdCl2 Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline) Dichlorobis[di-tert-butyl(4-diMethylaMinophenyl)phosphine]palladiuM(II) Dichlorobis[di-tert-butyl(p-dimethylaminophenyl)phosphino]palladium(II) pall Pd132 PdAMPHOS PdCl2(Amphos)2 Pd(amphos)Cl2 Pd(Amphos)2Cl2 887919-35-9 887918-35-9 C32H56Cl2N2P2Pd Pd