2,4-Dinitrobenzenesulfenyl chloride
- CAS No.
- 528-76-7
- Chemical Name:
- 2,4-Dinitrobenzenesulfenyl chloride
- Synonyms
- 2,4-DINITROPHENYLSULFENYL CHLORIDE;KHARASCH REAGENT;DNP-SULFENYL CHLORIDE;LABOTEST-BB LT00453936;2,4-Dinitrophenylthio chloride;(2,4-Dinitrophenylthio) chloride;2,4-dinitro-benzenesulfenylchlorid;2,4-dinitrophenyl hypochlorothioite;2,4-Dinitrobenzenesulfenyl chloride;2,4-Dinitrobenzenesulphenyl chloride
- CBNumber:
- CB8349604
- Molecular Formula:
- C6H3ClN2O4S
- Molecular Weight:
- 234.62
- MDL Number:
- MFCD00007129
- MOL File:
- 528-76-7.mol
- MSDS File:
- SDS
| Melting point | 94-97 °C(lit.) |
|---|---|
| Boiling point | 430.1±35.0 °C(Predicted) |
| Density | 1.700 (estimate) |
| refractive index | 1.6000 (estimate) |
| storage temp. | 2-8°C |
| solubility | benzene: soluble |
| form | solid |
| color | Light orange to Yellow to Green |
| Merck | 14,3274 |
| BRN | 405600 |
| InChI | 1S/C6H3ClN2O4S/c7-14-6-2-1-4(8(10)11)3-5(6)9(12)13/h1-3H |
| InChIKey | GPXDNWQSQHFKRB-UHFFFAOYSA-N |
| SMILES | [O-][N+](=O)c1ccc(SCl)c(c1)[N+]([O-])=O |
| CAS DataBase Reference | 528-76-7(CAS DataBase Reference) |
| FDA UNII | 6XLF60A5YM |
| EPA Substance Registry System | Benzenesulfenyl chloride, 2,4-dinitro- (528-76-7) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS07 |
|---|---|
| Signal word | Danger |
| Hazard statements | H314-H228-H302+H312+H332 |
| Precautionary statements | P280-P305+P351+P338-P310-P210-P240-P241-P260-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P370+P378-P405-P501 |
| PPE | Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges |
| Hazard Codes | C |
| Risk Statements | 34-37 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| F | 8-9-19-21 |
| TSCA | TSCA listed |
| HS Code | 2930.90.2900 |
| HazardClass | 8 |
| PackingGroup | III |
| Storage Class | 8A - Combustible corrosive hazardous materials |
| Hazard Classifications | Eye Dam. 1 Skin Corr. 1B |
2,4-Dinitrobenzenesulfenyl chloride price More Price(19)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TCI Chemical | D1463 | 2,4-Dinitrophenylsulfenyl Chloride >96.0%(T) | 528-76-7 | 5g | $44 | 2026-04-30 | Buy |
| Usbiological | 274641 | 2,4-Dinitrophenylsulfenyl Chloride Asreported | 528-76-7 | 5g | $303 | 2026-06-03 | Buy |
| Usbiological | 274641 | 2,4-Dinitrophenylsulfenyl Chloride Asreported | 528-76-7 | 10g | $412 | 2026-06-03 | Buy |
| Usbiological | 274641 | 2,4-Dinitrophenylsulfenyl Chloride Asreported | 528-76-7 | 25g | $576 | 2026-06-03 | Buy |
| Usbiological | 274641 | 2,4-Dinitrophenylsulfenyl Chloride Asreported | 528-76-7 | 50g | $778 | 2026-06-03 | Buy |
2,4-Dinitrobenzenesulfenyl chloride Chemical Properties, Uses, Production
Uses
2,4-Dinitrobenzenesulfenyl chloride was used in preparation of chlorine and bromine biphenyls.
Preparation
CAUTION: This reaction should be carried out in a hood behind a safety shield. The product decomposes explosively if heated above 90-100°C .
To a 500-ml, three-necked flask equipped with a mechanical stirrer, distillation column, and distillation head is added 100 gm (0.25 mole) of dry 2,4-dinitrophenyl disulfide and 250 ml of ethylene chloride. The contents are heated with an oil bath at 125°C until 30-40 ml of the solvent is collected by distillation. The contents are cooled and the distillation head replaced by a gas inlet and exit tube connected to an alkali trap. Then 0.15 gm (0.002 mole) of Merck "Iron by Hydrogen" powder is added as a catalyst [51a-c], and dry chlorine gas is slowly bubbled into the reaction. In a few minutes, the reaction warms up, and the flask is surrounded with a 20°C water bath. The chlorine gas is bubbled in at such a rate that 18 gm (0.25 mole) is added over a 1-1½-hr period. After this time, the suspended disulfide should gradually disappear, and a clear, amber-red solution results. The flow of chlorine gas is stopped, the solution stirred for 1 hr, filtered through diatomaceous earth, the filtrate aspirated to remove excess chlorine, and then 400 ml of anhydrous ether is added. Within ½ hr, most of the product crystallizes by cooling the flask in an ice-salt-water bath for 3-4 hr. The product is filtered, washed with 100 ml of cold ether, and then dried to afford 70 gm (60%) of brilliant yellow needles, m.p. 95-95.5°C.
Synthesis Reference(s)
Journal of the American Chemical Society, 72, p. 1796, 1950 DOI: 10.1021/ja01160a108
General Description
2,4-Dinitrobenzenesulfenyl chloride undergoes addition reactions with transannularly substituted cycloalkenes and norbornenes. 2,4-Dinitrobenzenesulfenyl chloride can convert allylic alcohols to dienes by 1,4-elimination.
Purification Methods
Crystallise the sulfenyl chloride from CCl4. [Beilstein 6 II 316.]
2,4-Dinitrobenzenesulfenyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
2,4-Dinitrobenzenesulfenyl chloride Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24512 | 81 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Shanghai Longsheng chemical Co.,Ltd. | 58099637 13585536065 | sales@shlschem.com | China | 9880 | 59 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42917 | 64 |
| Shandong Xiya Chemical Co., Ltd | 13355009207 13355009207 | 3007715519@qq.com | China | 18722 | 57 |
| Syntechem Co.,Ltd | info@syntechem.com | China | 12973 | 57 | |
| Beijing Taiya Jie Technology Development Co., Ltd. | 021-33690831-8001 13552411790;18616022633 | postmaster@tyjchem.cn | China | 1541 | 55 |
| TOKYO CHEMICAL INDUSTRY CO., LTD. | 03-36680489 | Sales-JP@TCIchemicals.com | Japan | 28364 | 80 |
View Latest Price from 2,4-Dinitrobenzenesulfenyl chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-02-02 | 2,4-Dinitrophenylsulfenyl Chloride
528-76-7
|
10mg | 99%HPLC | 2000tons | Shaanxi Dideu Medichem Co. Ltd | ||
 |
2020-01-10 | 2,4-DINITROBENZENESULFENYL CHLORIDE
528-76-7
|
$9.80 | 1g | ≥99% | 100kg | Career Henan Chemical Co | |
 |
2019-11-08 | 2,4-DINITROBENZENESULFENYL CHLORIDE
528-76-7
|
1g | 99.5%min | 20kg/week | Nanjing jinheyou Trading Co., Ltd. |
-
- 2,4-Dinitrophenylsulfenyl Chloride
528-76-7
- 99%HPLC
- Shaanxi Dideu Medichem Co. Ltd
-
- 2,4-DINITROBENZENESULFENYL CHLORIDE
528-76-7
- $9.80
- ≥99%
- Career Henan Chemical Co
-
- 2,4-DINITROBENZENESULFENYL CHLORIDE
528-76-7
- $0.00
- 99.5%min
- Nanjing jinheyou Trading Co., Ltd.
