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2-Bromo-5-methoxybenzaldehyde

2-Bromo-5-methoxybenzaldehyde structure

CAS No.: 7507-86-0

Chemical Name:: 2-Bromo-5-methoxybenzaldehyde

Synonyms: 2-BROMO-4-METHOXYBENZALDEHYDE;EOS-60499;AKOS B004279;4-Bromo-3-formylanisole;2-Bromo-5-methoxybenzaL;2-Bromo-5-methoxybenzalde;2-BROMO-5-METHOXYBENZALDEHYDE;3-Methoxy-6-bromobenzaldehyde;Benzaldehyde, 2-bromo-5-methoxy-;2-Bromo-5-methoxybenzaldehyde 97%

CBNumber:: CB8418364

Molecular Formula:: C8H7BrO2

Molecular Weight:: 215.04

MDL Number:: MFCD00463817

MOL File:: 7507-86-0.mol

MSDS File:: SDS

TDS File:: TDS

Last updated:2026-05-28 05:08:04

Product description	Number	Pack Size	Price
2-Bromo-5-methoxybenzaldehyde 97%	702390	1g	$31.7
2-Bromo-5-methoxybenzaldehyde 97%	702390	5g	$141
2-Bromo-4-methoxybenzaldehyde 97%	777544	1g	$47.02
2-Bromo-5-methoxybenzaldehyde min. 98.0 %	B6657	5G	$125
2-Bromo-5-methoxybenzaldehyde min. 98.0 %	B6657	25G	$374
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2-Bromo-5-methoxybenzaldehyde Properties

Melting point	71-76 °C
Boiling point	284.3±20.0 °C(Predicted)
Density	1.522±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Acetonitrile (Slightly), Chloroform (Slightly)
form	Solid
color	White to Off-White
InChI	InChI=1S/C8H7BrO2/c1-11-7-2-3-8(9)6(4-7)5-10/h2-5H,1H3
InChIKey	XNHKTMIWQCNZST-UHFFFAOYSA-N
SMILES	C(=O)C1=CC(OC)=CC=C1Br
CAS DataBase Reference	7507-86-0(CAS DataBase Reference)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302
Precautionary statements	P264-P270-P301+P312-P501
PPE	dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes	Xi,Xn
Risk Statements	36/37/38-22
Safety Statements	26-36/37/39
WGK Germany	3
HazardClass	IRRITANT
HS Code	2913000090
Storage Class	13 - Non Combustible Solids
Hazard Classifications	Acute Tox. 4 Oral

2-Bromo-5-methoxybenzaldehyde price More Price(82)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	702390	2-Bromo-5-methoxybenzaldehyde 97%	7507-86-0	1g	$31.7	2026-04-30	Buy
Sigma-Aldrich	702390	2-Bromo-5-methoxybenzaldehyde 97%	7507-86-0	5g	$141	2026-04-30	Buy
Sigma-Aldrich	777544	2-Bromo-4-methoxybenzaldehyde 97%	7507-86-0	1g	$47.02	2025-07-31	Buy
TCI Chemical	B6657	2-Bromo-5-methoxybenzaldehyde min. 98.0 %	7507-86-0	5G	$125	2026-04-30	Buy
TCI Chemical	B6657	2-Bromo-5-methoxybenzaldehyde min. 98.0 %	7507-86-0	25G	$374	2026-04-30	Buy

Product number	Packaging	Price	Buy
702390	1g	$31.7	Buy
702390	5g	$141	Buy
777544	1g	$47.02	Buy
B6657	5G	$125	Buy
B6657	25G	$374	Buy

2-Bromo-5-methoxybenzaldehyde Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

2-Bromo-5-methoxybenzaldehyde is used in preparation of Benzimidazole Quinolines. Also, used in preparation of Cyclopentenes, Polycycles, Benzocarbocycles/N-Heterocycle derivatives.

Synthesis

591-31-1

7507-86-0

3-Methoxybenzaldehyde (6.06 g, 44.6 mmol, 1.0 eq.) was used as a starting material, which was dissolved in acetic acid (10 mL), followed by slow dropwise addition of bromine (2.75 mL, 53.6 mmol, 1.2 eq.). The reaction mixture was stirred at 25°C for 36 hours. Upon completion of the reaction, the reaction was quenched with saturated sodium sulfite solution (50 mL), the mixture was poured into water (20 mL) and extracted with ether (5 x 30 mL). The organic layers were combined, washed sequentially with water (3 x 25 mL) and brine (30 mL), dried over anhydrous magnesium sulfate and concentrated to give the target product 2-bromo-5-methoxybenzaldehyde (9.49 g, 99% yield) as a dark yellow solid. Alternatively, the aldehyde was commercially available. Next, 2-bromo-5-methoxybenzaldehyde (9.49 g, 44.2 mmol, 1.0 eq.) was dissolved in acetonitrile (200 mL), and this solution was added to stirring phosphonate (14.9 g, 44.2 mmol, 1.0 eq.), lithium chloride (2.44 g, 57.4 mmol, 1.3 eq.), and 1,8-diazabicyclo[5.4. 0]undec-7-ene (DBU, 6.59 mL, 44.2 mmol, 1.0 equiv) in a mixture. The resulting dark yellow solution was stirred at 25°C for 12 hours. Upon completion of the reaction, the reaction was quenched by addition of saturated ammonium chloride solution (100 mL) and concentrated to remove the organic solvent. The residue was redissolved in ethyl acetate (50 mL), poured into water (50 mL) and extracted with ethyl acetate (3 x 50 mL). The organic extracts were combined, washed sequentially with water (50 mL) and brine (50 mL), dried over anhydrous magnesium sulfate and concentrated to give the diester product (17.5 g, 99% yield) as a yellow oil. The product was characterized as follows: rf = 0.57 (silica gel plate, hexane/ethyl acetate, 4:1); IR (thin film) 2979, 2936, 1724, 1643, 1590, 1569, 1465, 1285, 1238, 1194, 1156, 1097, 1019 cm^-1; ^1H NMR (400 MHz, CDCl3) δ 7.80 (s, 1H), 7.47 (d, J = 8.8 Hz, 1H), 6.94 (d, J = 2.8 Hz, 1H), 6.77 (dd, J = 8.8, 2.8 Hz, 1H), 4.29 (q, J = 7.2 Hz, 2H), 3.76 (s, 3H), 3.33 (s, 2H), 1.45 (s, 9H), 1.35 (t, J = 7.2 Hz, 3H); ^13C NMR (75 MHz, CDCl3) δ 170.2, 166.9, 158.7, 140.6, 136.3, 133.3, 128.3, 116.5, 115.0, 114.3, 81.1, 61.2, 55.5, 35.2, 28.0, 14.2; HRMS (MALDI-FTMS) calculated value C18H23BrO5 [M+] 398.0729, measured value 398.0746.

References

[1] Angewandte Chemie - International Edition, 2010, vol. 49, # 30, p. 5146 - 5150
[2] Patent: WO2011/103442, 2011, A2. Location in patent: Page/Page column 62-63
[3] Patent: KR2015/107357, 2015, A. Location in patent: Paragraph 0063-0065
[4] Tetrahedron Letters, 2010, vol. 51, # 10, p. 1383 - 1385
[5] Heterocycles, 1986, vol. 24, # 2, p. 297 - 302

2-Bromo-5-methoxybenzaldehyde synthesis

Synthesis of 2-Bromo-5-methoxybenzaldehyde from 2-BROMO-5-HYDROXYBENZALDEHYDE and Iodomethane

2-Bromo-5-methoxybenzaldehyde Preparation Products And Raw materials

Raw materials

2-BROMO-5-HYDROXYBENZALDEHYDE 2-BROMO-5-METHOXYBENZYL ALCOHOL Iodomethane 3-Methoxybenzaldehyde

Preparation Products

5-METHOXY-1H-INDAZOLE 2-(4-FLUOROPHENYL)-5-METHOXYBENZO[B]THIOPHENE-3-CARBOXYLIC ACID tolciclate 2-BROMO-5-METHOXYBENZOIC ACID 2-BROMO-5-METHOXYBENZYLAMINE

2-formyl-4-methoxybenzonitrile

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2-Bromo-5-methoxybenzaldehyde Suppliers

Global( 223)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Changzhou Chontech Baocheng Chemical Co.,Ltd	+86-51982698291; +86-15295095616	info@hhbhswkj.com	China	131	58
Kindchem(Nanjing)Co.,Ltd	+86-025-025-85281586 18651653755	sales@kindchem.cn	China	1226	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21585	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8497	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED		sales@conier.com	China	49979	58
career henan chemical co	+86-0371-86658258	factory@coreychem.com	China	29807	58
Fuxin Pharmaceutical	+86-021-021-50872116	contact@fuxinpharm.com	China	9976	58
Shanghai Safer Pharmaceutical Technology Co., Ltd.	021-31761238	sales@saferph.com	CHINA	897	58

Supplier	Advantage
Changzhou Chontech Baocheng Chemical Co.,Ltd	58
Kindchem(Nanjing)Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
Jinan Carbotang Biotech Co.,Ltd.	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
career henan chemical co	58
Fuxin Pharmaceutical	58
Shanghai Safer Pharmaceutical Technology Co., Ltd.	58

View Lastest Price from 2-Bromo-5-methoxybenzaldehyde manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2026-06-30	2-Bromo-5-methoxybenzaldehyde 7507-86-0		1KG	97.0%	10000KGS	Shaanxi Dideu New Materials Co. Ltd
2024-06-11	2-Bromo-5-methoxybenzaldehyde 7507-86-0		1kg	98%	100	Kindchem(Nanjing)Co.,Ltd
2020-01-13	2-Bromo-5-methoxybenzaldehyde 7507-86-0	$1.00	1g	99%	10000KGS	Career Henan Chemical Co

2-Bromo-5-methoxybenzaldehyde
7507-86-0
97.0%
Shaanxi Dideu New Materials Co. Ltd

2-Bromo-5-methoxybenzaldehyde
7507-86-0
98%
Kindchem(Nanjing)Co.,Ltd

2-Bromo-5-methoxybenzaldehyde
7507-86-0
$1.00
99%
Career Henan Chemical Co

2-Bromo-5-methoxybenzaldehyde Spectrum

2-Bromo-5-methoxybenzaldehyde(7507-86-0)¹HNMR

7507-86-0(2-Bromo-5-methoxybenzaldehyde)Related Search:

o-Anisaldehyde 2,5-Dimethoxybenzaldehyde 2-Methoxyethanol 4-Dimethylaminobenzaldehyde 2,4-Dimethoxybenzaldehyde

Anisole 3-Methoxybenzaldehyde 2,6-Dimethoxybenzaldehyde (Trifluoromethoxy)benzene Veratraldehyde

3-(METHOXYMETHOXY)BENZALDEHYDE p-Anisaldehyde Benzaldehyde 2-BROMO-5-METHOXYBENZOIC ACID 2-Nitrobenzaldehyde

4-Hydroxybenzaldehyde 3,5-Dimethoxybenzaldehyde 2,3-Dimethoxybenzaldehyde

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3-Methoxy-6-bromobenzaldehyde 2-BROMO-5-METHOXYBENZALDEHYDE AKOS B004279 4-Bromo-3-formylanisole 4-Bromo-3-formylanisole, 6-Bromo-m-anisaldehyde 2-Bromo-5-methoxybenzaldehyde 97% EOS-60499 2-Bromo-5-methoxybenzalde 2-Bromo-5-methoxybenzaL Benzaldehyde, 2-bromo-5-methoxy- 2-BROMO-4-METHOXYBENZALDEHYDE 7507-86-0 aldehyde| alkyl bromide Aromatic Aldehydes & Derivatives (substituted) Benzaldehyde Aryl Halogenated Organohalides Adehydes, Acetals & Ketones Anisoles, Alkyloxy Compounds & Phenylacetates Bromine Compounds