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2,5-Dibromohydroquinone

CAS No.
14753-51-6
Chemical Name:
2,5-Dibromohydroquinone
Synonyms
2,5-Dibromobenzene-1,4-diol;2,5-dibromo-1,4-hydroquinone;2,5-Dibromoquinol;2,5-Dibromohydroquine;5-DIBROMOHYDROQUINONE;2,5-Dibromohydroquinone;2,5-Dibromohydroquinone>2,5-DibroMohydroquinone 97%;2,5-Dibromo-1,4-benzenediol;1,4-Benzenediol,2,5-dibromo-
CBNumber:
CB8455077
Molecular Formula:
C6H4Br2O2
Molecular Weight:
267.9
MDL Number:
MFCD00192664
MOL File:
14753-51-6.mol
MSDS File:
SDS
Last updated:2026-09-12 18:55:43

2,5-Dibromohydroquinone Properties

Melting point 191-194 °C
Boiling point 283.4±35.0 °C(Predicted)
Density 2.257±0.06 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in methanol
pka 7.90±0.23(Predicted)
form powder to crystal
color White to Light yellow to Light orange
InChI InChI=1S/C6H4Br2O2/c7-3-1-5(9)4(8)2-6(3)10/h1-2,9-10H
InChIKey VALXCIRMSIFPFN-UHFFFAOYSA-N
SMILES C1(O)=CC(Br)=C(O)C=C1Br
UNSPSC Code 12162002
NACRES NA.23

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  29081990
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
NFPA 704
1
2 0

2,5-Dibromohydroquinone price More Price(63)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 574619 2,5-Dibromohydroquinone 97% 14753-51-6 5g $86.8 2026-04-30 Buy
Sigma-Aldrich 574619 2,5-Dibromohydroquinone 97% 14753-51-6 25g $301 2026-04-30 Buy
TCI Chemical D4067 2,5-Dibromohydroquinone >98.0%(GC)(T) 14753-51-6 5g $54 2026-04-30 Buy
TCI Chemical D4067 2,5-Dibromohydroquinone >98.0%(GC)(T) 14753-51-6 25g $184 2026-04-30 Buy
Usbiological 273306 2,5-Dibromohydroquinone Asreported 14753-51-6 1g $303 2026-06-03 Buy
Product number Packaging Price Buy
574619 5g $86.8 Buy
574619 25g $301 Buy
D4067 5g $54 Buy
D4067 25g $184 Buy
273306 1g $303 Buy

2,5-Dibromohydroquinone Chemical Properties,Uses,Production

Chemical Properties

Class white to Gray Crystal

Uses

It is an important pharmaceutical intermediate.

Synthesis

Hydroquinone

123-31-9

2,5-DIBROMOHYDROQUINONE

14753-51-6

The general procedure for the synthesis of 2,5-dibromo-1,4-benzenediol from hydroquinone was as follows: hydroquinone (20 g, 182 mmol) and 200 mL of glacial acetic acid were added to a 1 L three-necked flask fitted with a nitrogen inlet and a gas outlet under nitrogen protection. The flask was placed in an ice bath and the passage of nitrogen gas was initiated. Bromine (60.9 g, 381 mmol) was slowly added dropwise through a dropping funnel over 20 min. During the dropwise addition, a white solid gradually precipitated from the reaction mixture. After completion of the dropwise addition, the reaction mixture was continued to be stirred at room temperature for 12 hours. Upon completion of the reaction, the mixture was cooled in an ice bath, the white solid was collected by filtration and washed to neutrality with cold water. The final white solid product 2,5-dibromo-1,4-benzenediol (41.4 g, 85% yield) was obtained. The product was dried under vacuum and characterized by 1H NMR (300 MHz, CDCl3): δ 7.14 (2H, s), 5.2 (2H, br, s).

References

[1] Journal of Chemical Research - Part S, 2002, # 6, p. 272 - 275
[2] Patent: US9981887, 2018, B1. Location in patent: Page/Page column 8
[3] Chemistry Letters, 1987, p. 627 - 630
[4] Journal of Materials Chemistry A, 2015, vol. 3, # 5, p. 1920 - 1924
[5] Chinese Journal of Chemistry, 2017, vol. 35, # 4, p. 447 - 456

123-31-9
14753-51-6
Synthesis of 2,5-Dibromohydroquinone from Hydroquinone
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View Lastest Price from 2,5-Dibromohydroquinone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,5-DIBROMOHYDROQUINONE pictures 2026-09-02 2,5-DIBROMOHYDROQUINONE
14753-51-6
$2.00-10.00 1KG 99% Henan Fengda Chemical Co., Ltd
2,5-DIBROMOHYDROQUINONE pictures 2019-07-06 2,5-DIBROMOHYDROQUINONE
14753-51-6
$1.00 1KG 40%-99% 1000kg Career Henan Chemical Co
2,5-DibroMohydroquinone 97% 1,4-Benzenediol,2,5-dibromo- 2,5-Dibromo-1,4-benzenediol 2,5-Dibromohydroquine 2,5-Dibromoquinol 2,5-Dibromohydroquinone> 5-DIBROMOHYDROQUINONE 2,5-Dibromobenzene-1,4-diol 2,5-dibromo-1,4-hydroquinone 2,5-Dibromohydroquinone 14753-51-6 C6H4Br2O2 Br2C6H2OH2 Alcohols Monomers Polymer Science