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2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID

CAS No.
332099-14-6
Chemical Name:
2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID
Synonyms
2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID;4H-Thieno[3,2-b]pyrrole-5-carboxylic acid, 2-methyl-
CBNumber:
CB8759850
Molecular Formula:
C8H7NO2S
Molecular Weight:
181.21
MDL Number:
MFCD08277221
MOL File:
Mol file
Last updated:2026-05-28 05:47:02

2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID Properties

storage temp. 2-8°C(protect from light)
Appearance Off-white to light brown Solid

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338

2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Biosynth HNA09914 2-Methyl-4h-thieno[3,2-b]pyrrole-5-carboxylic acid 332099-14-6 2.5g $413 2026-06-04 Buy
Matrix Scientific 204569 2-Methyl-4H-thieno[3,2-b]pyrrole-5-carboxylic acid 332099-14-6 250.00mg $20 2026-05-18 Buy
Matrix Scientific 204569 2-Methyl-4H-thieno[3,2-b]pyrrole-5-carboxylic acid 332099-14-6 1.00g $66 2026-05-18 Buy
Matrix Scientific 204569 2-Methyl-4H-thieno[3,2-b]pyrrole-5-carboxylic acid 332099-14-6 5.00g $330 2026-05-18 Buy
Synthonix M48494 2-Methyl-4H-thieno[3,2-b]pyrrole-5-carboxylic acid 95+% 332099-14-6 100mg $22 2026-05-06 Buy
Product number Packaging Price Buy
HNA09914 2.5g $413 Buy
204569 250.00mg $20 Buy
204569 1.00g $66 Buy
204569 5.00g $330 Buy
M48494 100mg $22 Buy

2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID Chemical Properties,Uses,Production

Synthesis

4H-Thieno[3,2-b]pyrrole-5-carboxylic acid, 2-methyl-, ethyl ester

238749-54-7

2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID

332099-14-6

General procedure for the synthesis of 2-methyl-4H-thieno[3,2-b]pyrrole-5-carboxylic acid from compound (CAS:238749-54-7): compound 3 (1.82 g, 8.70 mmol, 1 equiv.) was dissolved in ethanol (100 mL), followed by the addition of an aqueous sodium hydroxide solution (50 mL containing 5.35 g NaOH 134 mmol, 15.4 equiv). The reaction mixture was stirred under reflux conditions for 30 minutes. After completion of the reaction, the mixture was cooled and 6N aqueous hydrochloric acid solution was slowly added to neutralize the reaction system. The resulting precipitate was collected by filtration, the precipitate was washed well with water and finally dried under vacuum to afford the target product 2-methyl-4H-thieno[3,2-b]pyrrole-5-carboxylic acid (4) as a white solid (1.41 g, 89.5% yield). Thin layer chromatography (TLC) analysis (silica gel plate, unfolding reagent: hexane/ethyl acetate = 1:1): Rf = 0.2.

References

[1] Patent: EP2022794, 2009, A1. Location in patent: Page/Page column 11; 12

238749-54-7
332099-14-6
Synthesis of 2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID from 4H-Thieno[3,2-b]pyrrole-5-carboxylic acid, 2-methyl-, ethyl ester

2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID Preparation Products And Raw materials

2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID Suppliers

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2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID Spectrum

2-METHYL-4H-THIENO[3,2-B]PYRROLE-5-CARBOXYLIC ACID 4H-Thieno[3,2-b]pyrrole-5-carboxylic acid, 2-methyl- 332099-14-6