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4-(Trifluoromethoxy)phenylmagnesium bromide

4-(Trifluoromethoxy)phenylmagnesium bromide Structure
4-(Trifluoromethoxy)phenylmagnesium bromide structure
CAS No.
169222-42-8
Chemical Name:
4-(Trifluoromethoxy)phenylmagnesium bromide
Synonyms
4-(Trifluoromethoxy)phenylmagnesium bromide;Magnesium, bromo[4-(trifluoromethoxy)phenyl]-;4-(Trifluoromethoxy)phenylmagnesium bromide solution ;4-(Trifluoromethoxy)phenylmagnesium bromide 0.5M in THF;4-(Trifluoromethoxy)phenylmagnesium bromide 0.5M in 2-MeTHF;(4-(Trifluoromethoxy)phenyl)magnesium bromide, 0.50 M in THF;(4-(Trifluoromethoxy)phenyl)magnesium bromide, 0.50 M in 2-MeTHF;4-(Trifluoromethoxy)phenylmagnesium bromide solution 0.5 M in THF;4-(Trifluoromethoxy)phenylmagnesium bromide, 0.50 M in THF - [T31805]
CBNumber:
CB92095489
Molecular Formula:
C7H4BrF3MgO
Molecular Weight:
265.3102696
MDL Number:
MFCD09842767
MOL File:
169222-42-8.mol
MSDS File:
SDS
Last updated:2026-05-28 04:57:09
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4-(Trifluoromethoxy)phenylmagnesium bromide Properties

Density 0.975 g/mL at 25 °C
Flash point -30 °C
form liquid
InChI 1S/C7H4F3O.BrH.Mg/c8-7(9,10)11-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1
InChIKey UFMHNMPAQCQXMW-UHFFFAOYSA-M
SMILES FC(F)(F)Oc1ccc([Mg]Br)cc1
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02, GHS05, GHS07, GHS08
Signal word  Danger
Hazard statements  H225-H302-H314-H335-H351
Precautionary statements  P210-P260-P280-P305+P351+P338-P370+P378-P403+P235
target organs Respiratory system
Hazard Codes  F,C
Risk Statements  11-14-19-34-40-37
Safety Statements  16-26-36/37/39-45
RIDADR  UN 2924 3/PG 2
WGK Germany  3
Storage Class 3 - Flammable liquids
Hazard Classifications Acute Tox. 4 Oral
Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3

4-(Trifluoromethoxy)phenylmagnesium bromide price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 687901 4-(Trifluoromethoxy)phenylmagnesium bromide solution 0.5M in THF 169222-42-8 50ml $561 2026-04-30 Buy
Synthonix T31805 4-(Trifluoromethoxy)phenylmagnesium bromide, 0.50 M in THF 169222-42-8 50ml $110 2026-05-06 Buy
Synthonix T31805 4-(Trifluoromethoxy)phenylmagnesium bromide, 0.50 M in THF 169222-42-8 100ml $175 2026-05-06 Buy
Synthonix T31805 4-(Trifluoromethoxy)phenylmagnesium bromide, 0.50 M in THF 169222-42-8 500ml $560 2026-05-06 Buy
Rieke Metals G0527 (4-(trifluoromethoxy)phenyl)magnesium bromide 169222-42-8 50mL $641 2026-05-06 Buy
Product number Packaging Price Buy
687901 50ml $561 Buy
T31805 50ml $110 Buy
T31805 100ml $175 Buy
T31805 500ml $560 Buy
G0527 50mL $641 Buy

4-(Trifluoromethoxy)phenylmagnesium bromide Chemical Properties, Uses, Production

Uses

Reactant for:

  • Preparation of chromanol derivatives as novel class of CETP inhibitors for treatment of cardiovascular disease
  • Pd-catalyzed cross coupling
  • Preparation of indazole-pyridine derivatives as protein kinase B/Akt inhibitors with reduced hypotension, via Stille coupling, Mitsunobu reaction and copper-catalyzed aziridine ring-opening reaction

reaction suitability

reaction type: Grignard Reaction

4-(Trifluoromethoxy)phenylmagnesium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

4-(Trifluoromethoxy)benzoic acid

4-(Trifluoromethoxy)phenylmagnesium bromide Suppliers

Global Suppliers ( 21)
Supplier Tel Email Country ProdList Advantage
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Shanghai YuanYe Biotechnology Co., Ltd. 15026964105 2881489226@qq.com China 89667 60
Amadis Chemical Company Limited 571-89925085 sales@amadischem.com China 131885 58
Hefei TNJ Chemical Industry Co.,Ltd. +86-0551-65418684 +86-18949823763 sales@tnjchem.com China 25333 58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. 025-025-66113011 15955137747 cb5@aikonchem.com China 10354 58
Auonsi (Shanghai) Biology Technology Co., Ltd. 400-1107768 15058188853 478133536@qq.com China 8546 58
Huangshi Bo’Er Chemical Co., Ltd. 0714-6401888 18671400300 273568016@qq.com China 567 58
Shanghai Aladdin Biochemical Technology Co.,Ltd. 6206333 13167063860 anhua.mao@aladdin-e.com China 43486 58
Pushan Industry (Shaanxi) Co., Ltd 029-81310890 18165209495 2929288192@qq.com China 9768 58
Supplier Advantage
Shanghai Hanhong Scientific Co.,Ltd. 64
Sigma-Aldrich 80
Shanghai YuanYe Biotechnology Co., Ltd. 60
Amadis Chemical Company Limited 58
Hefei TNJ Chemical Industry Co.,Ltd. 58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd. 58
Auonsi (Shanghai) Biology Technology Co., Ltd. 58
Huangshi Bo’Er Chemical Co., Ltd. 58
Shanghai Aladdin Biochemical Technology Co.,Ltd. 58
Pushan Industry (Shaanxi) Co., Ltd 58

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4-(Trifluoromethoxy)phenylmagnesium bromide (4-(Trifluoromethoxy)phenyl)magnesium bromide, 0.50 M in THF (4-(Trifluoromethoxy)phenyl)magnesium bromide, 0.50 M in 2-MeTHF 4-(Trifluoromethoxy)phenylmagnesium bromide solution 4-(Trifluoromethoxy)phenylmagnesium bromide solution 0.5 M in THF Magnesium, bromo[4-(trifluoromethoxy)phenyl]- 4-(Trifluoromethoxy)phenylmagnesium bromide 0.5M in 2-MeTHF 4-(Trifluoromethoxy)phenylmagnesium bromide, 0.50 M in THF - [T31805] 4-(Trifluoromethoxy)phenylmagnesium bromide 0.5M in THF 169222-42-8 C7H4BrF3MgO Grignard Reagent Aryl Grignard Reagents Organometallic Reagents