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1,3-Bis(diphenylphosphinomethyl)benzene

CAS No.
89756-88-7
Chemical Name:
1,3-Bis(diphenylphosphinomethyl)benzene
Synonyms
α,α′-Bis(diphenylphosphino)-m-xylene;1,3-Bis(diphenylphosphinomethyl)benzene;[1,3-Phenylenebis(methylene)]bis[diphenyl]phosphine;Phosphine, 1,1'-[1,3-phenylenebis(methylene)]bis[1,1-diphenyl-
CBNumber:
CB92524547
Molecular Formula:
C32H28P2
Molecular Weight:
474.51
MDL Number:
MFCD16621402
MOL File:
89756-88-7.mol
MSDS File:
SDS
Last updated:2026-05-28 05:39:05

1,3-Bis(diphenylphosphinomethyl)benzene Properties

Melting point 50-55°C
Boiling point 605.0±48.0 °C(Predicted)
Flash point >110℃
form powder
InChI 1S/C32H28P2/c1-5-16-29(17-6-1)33(30-18-7-2-8-19-30)25-27-14-13-15-28(24-27)26-34(31-20-9-3-10-21-31)32-22-11-4-12-23-32/h1-24H,25-26H2
InChIKey QLSOZHFOFHARBJ-UHFFFAOYSA-N
SMILES C(P(c1ccccc1)c2ccccc2)c3cccc(CP(c4ccccc4)c5ccccc5)c3
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
WGK Germany  3
Storage Class 13 - Non Combustible Solids
Hazard Classifications Aquatic Chronic 4

1,3-Bis(diphenylphosphinomethyl)benzene price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Crysdot CD51000175 1,3-Bis((diphenylphosphino)methyl)benzene 95+% 89756-88-7 5g $470 2026-05-27 Buy
American Custom Chemicals Corporation OPC0001077 1,3-BIS(DIPHENYLPHOSPHINOMETHYL)BENZENE 95.00% 89756-88-7 1G $675.38 2021-12-16 Buy
Arctom AS598212 1,3-Bis((diphenylphosphino)methyl)benzene 98% 89756-88-7 1g $125 2021-12-16 Buy
Arctom AS598212 1,3-Bis((diphenylphosphino)methyl)benzene 98% 89756-88-7 5g $378 2021-12-16 Buy
Alichem 89756887 1,3-Bis((diphenylphosphino)methyl)benzene 89756-88-7 5g $403.2 2021-12-16 Buy
Product number Packaging Price Buy
CD51000175 5g $470 Buy
OPC0001077 1G $675.38 Buy
AS598212 1g $125 Buy
AS598212 5g $378 Buy
89756887 5g $403.2 Buy

1,3-Bis(diphenylphosphinomethyl)benzene Chemical Properties, Uses, Production

Uses

Reactant for:

  • Cyclometalation of pincer ligands
  • Insertion of carbon dioxide into (PCP)PDII-Me Bonds
  • Synthesis of iridium complexes containing bidentate phosphine ligands
  • Transcyclometalation processes
  • Synthesis of vinylidene and carbyne complexes

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

1,3-Bis(diphenylphosphinomethyl)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

1,3-Bis(diphenylphosphinomethyl)benzene Suppliers

Global Suppliers ( 20)
Supplier Tel Email Country ProdList Advantage
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44850 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340;13818007232 307593986@qq.com China 475 58
Beijing Guofang Dingsheng Technology Co., Ltd. 18610472091 gfdskj@163.com China 496 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Amadis Chemical Company Limited 571-89925085 sales@amadischem.com China 131885 58
Aikon International Limited 025-66113011 19370895928 qzhang@aikonchem.com China 15390 58
Shanghai Anyinuo Biomedical Technology Co., Ltd. 021-34625901 420970979@qq.com China 5982 58
Zhengzhou Acme Chemical Co., Ltd. 0371-63315541 13323832564 1443871971@qq.com China 9895 58
Career Henan Chemica Co +86-0371-86658258 +86-13203830695 laboratory@coreychem.com China 30203 58
1,3-Bis(diphenylphosphinomethyl)benzene [1,3-Phenylenebis(methylene)]bis[diphenyl]phosphine α,α′-Bis(diphenylphosphino)-m-xylene Phosphine, 1,1'-[1,3-phenylenebis(methylene)]bis[1,1-diphenyl- 89756-88-7