3-Amino-4-chlorophenylboronic acid, pinacol ester
- CAS No.
- 850567-56-5
- Chemical Name:
- 3-Amino-4-chlorophenylboronic acid, pinacol ester
- Synonyms
- 2-Chloro-5-(4,4,5,5-tetram;3-Amino-4-chlorobenzeneboronic acid;3-Amino-4-chlorophenylboronic acid, pinacol ester;(3-AMINO-4-CHLORO)BENZENEBORONIC ACID, PINACOL ESTER;3-Amino-4-chlorobenzeneboronic acid, pinacol ester 95%;2-chloro-5-(tetraMethyl-1,3,2-dioxaborolan-2- yl)aniline;2-Chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl);2-Chloro-5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)aniline;6-Chloro-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline;2-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)anil...
- CBNumber:
- CB9729409
- Molecular Formula:
- C12H17BClNO2
- Molecular Weight:
- 253.53
- MDL Number:
- MFCD06659926
- MOL File:
- 850567-56-5.mol
- MSDS File:
- SDS
- TDS File:
- TDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Hazard Note | Irritant | |||||||||
| HS Code | 2931900090 | |||||||||
| NFPA 704 |
|
3-Amino-4-chlorophenylboronic acid, pinacol ester price More Price(39)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Apolloscientific | OR1336 | 3-Amino-4-chlorobenzeneboronic acid, pinacol ester 98% | 850567-56-5 | 250mg | $62 | 2026-06-04 | Buy |
| Apolloscientific | OR1336 | 3-Amino-4-chlorobenzeneboronic acid, pinacol ester 98% | 850567-56-5 | 1g | $170 | 2026-06-04 | Buy |
| Apolloscientific | OR1336 | 3-Amino-4-chlorobenzeneboronic acid, pinacol ester 98% | 850567-56-5 | 5g | $680 | 2026-06-04 | Buy |
| Matrix Scientific | 118397 | 3-Amino-4-chlorophenylboronic acid pinacolester | 850567-56-5 | 10.00g | $865 | 2026-05-18 | Buy |
| Synthonix | C56156 | 2-Chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 97% | 850567-56-5 | 1g | $29 | 2026-05-06 | Buy |
3-Amino-4-chlorophenylboronic acid, pinacol ester Chemical Properties, Uses, Production
Synthesis
913836-26-7
850567-56-5
General procedure for the synthesis of 3-amino-4-chlorophenylboronic acid pinacol ester from 2-(4-chloro-3-nitrophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane: Compound 1 (55.0 g, 190 mmol) was placed in a three-necked flask, and ethanol (500 mL), water (100 mL), and ammonium chloride (20.4 g, 390 mmol) were sequentially added. 390 mmol). Iron powder (49 g, 880 mmol) was added slowly with stirring at room temperature. The reaction mixture was heated to 105 °C and refluxed for 2 hours. After completion of the reaction, it was cooled to room temperature and filtered through diatomaceous earth to remove excess iron powder. Ethanol was removed by distillation under reduced pressure and water (100 mL) and saturated aqueous sodium bicarbonate solution (150 mL) were added. Extracted with ethyl acetate (200 mL x 3), the organic phases were combined, washed sequentially with saturated aqueous sodium bicarbonate (150 mL) and saturated brine (150 mL), dried over anhydrous sodium sulfate and filtered. The filtrate was rotary evaporated to dryness to give compound 2 (45.5 g, 179 mmol, 94% yield) in yellow liquid form.
References
[1] Patent: CN107383076, 2017, A. Location in patent: Paragraph 0005; 0008-0010
[2] Journal of Organic Chemistry, 2014, vol. 79, # 5, p. 1979 - 1988
3-Amino-4-chlorophenylboronic acid, pinacol ester Preparation Products And Raw materials
Raw materials
Preparation Products
3-Amino-4-chlorophenylboronic acid, pinacol ester Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| J & K SCIENTIFIC LTD. | 18210857532 18210857532 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006356688 18621169109 | market03@meryer.com | China | 40202 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30103 | 84 |
| Energy Chemical | 400-0056266 | sales8178@energy-chemical.com | China | 44850 | 61 |
| Wuhan Chemwish Technology Co., Ltd | 86-027-67849912 | sales@chemwish.com | China | 35884 | 56 |
| Chembon Pharmaceutical Co., Ltd. | 028-84252981 18583719936 | sales@chembon.com.cn | China | 854 | 64 |
| ShangHai YuanYe Biotechnology Co., Ltd. | 15026964105 | shyysw007@163.com | China | 4998 | 60 |
| Chengdu Forest Science and Technology Development Co., Ltd. | 18030648795 18030648795 | sales@cdforestchem.com | China | 1998 | 58 |
| Shanghai Aladdin Bio-Chem Technology Co.,LTD | 400-6206333 13167063860 | anhua.mao@aladdin-e.com | China | 29985 | 65 |
| Chembon Pharmaceutical Co., Ltd. | +86-28-8425-2981 | sales@chembon.com.cn | China | 20 | 60 |
View Latest Price from 3-Amino-4-chlorophenylboronic acid, pinacol ester manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2026-08-20 | 3-AMINO-4-CHLOROPHENYLBORONIC ACID, PINACOL ESTER
850567-56-5
|
$1.10 | 1g | 99.0% Min | 100 Tons | Dideu Industries Group Limited | |
 |
2020-01-05 | 3-AMINO-4-CHLOROPHENYLBORONIC ACID, PINACOL ESTER
850567-56-5
|
$1.00 | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- 3-AMINO-4-CHLOROPHENYLBORONIC ACID, PINACOL ESTER
850567-56-5
- $1.10
- 99.0% Min
- Dideu Industries Group Limited
-
- 3-AMINO-4-CHLOROPHENYLBORONIC ACID, PINACOL ESTER
850567-56-5
- $1.00
- 99%
- Career Henan Chemical Co
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