ビス(p-アリルオキシフェニル)スルホン
ビス(p-アリルオキシフェニル)スルホン 物理性質
- 融点 :
- 141-142 °C(Solv: ethanol (64-17-5))
- 沸点 :
- 500.7±45.0 °C(Predicted)
- 比重(密度) :
- 1.171±0.06 g/cm3(Predicted)
- 貯蔵温度 :
- -20°C Freezer, Under inert atmosphere
- 溶解性:
- DMSO（微量）、メタノール（微量）
- 外見 :
- 個体
- 色:
- ホワイトからオフホワイト
- InChI:
- InChI=1S/C18H18O4S/c1-3-13-21-15-5-9-17(10-6-15)23(19,20)18-11-7-16(8-12-18)22-14-4-2/h3-12H,1-2,13-14H2
- InChIKey:
- JUNVYDTYJZSTKY-UHFFFAOYSA-N
- SMILES:
- S(C1=CC=C(OCC=C)C=C1)(C1=CC=C(OCC=C)C=C1)(=O)=O
- CAS データベース:
- 41481-63-4(CAS DataBase Reference)
安全性情報
- リスクと安全性に関する声明
- 危険有害性情報のコード(GHS)
| 化審法 |
新規公示化学物質（2011年3月31日以前届出） |
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| 絵表示（GHS） |
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| 注意喚起語 |
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| 危険有害性情報 |
| コード |
危険有害性情報 |
危険有害性クラス |
区分 |
注意喚起語 |
シンボル |
P コード |
| H302 |
飲み込むと有害 |
急性毒性、経口 |
4 |
警告 |
|
P264, P270, P301+P312, P330, P501 |
| H315 |
皮膚刺激 |
皮膚腐食性/刺激性 |
2 |
警告 |
|
P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
強い眼刺激 |
眼に対する重篤な損傷性/眼刺激 性 |
2A |
警告 |
|
P264, P280, P305+P351+P338,P337+P313P |
| H335 |
呼吸器への刺激のおそれ |
特定標的臓器毒性、単回暴露； 気道刺激性 |
3 |
警告 |
|
|
|
| 注意書き |
| P280 |
保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。 |
| P305+P351+P338 |
眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。 |
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ビス(p-アリルオキシフェニル)スルホン 価格
| メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
ビス(p-アリルオキシフェニル)スルホン 化学特性,用途語,生産方法
化学的特性
White crystalline powder
製造方法
The preparation of 1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene is as follows:2400g water, 216g caustic soda lye of 48% strength, 600g 4,4'-dihydroxydiphenyl sulfone and 204g Allyl chloride were mixed and the reaction was carried out at 55-60°C and autogenously generated pressure of 0.8-1. Okg/cm2 for 8 hours. 204g caustic soda lye of 48% strength was added in the reaction mixture, and maintained for 1 hour at 80°C thereafter filtered at 80°C to remove 4,4'-diallyloxydiphenyl sulfone. Further, the filtrate solution was treated with 5g activated carbon and 5g sequestering agent at 85- 90°C. The pH of filtrated solution was adjusted to 8.9 with 20% sulfuric acid and cooled to 35°C. The precipitate was separated by filtration and slurred in water. The pH was adjusted to 4.94 with 20% sulfuric acid and the precipitate was separated by filtration, and washed with water and dried to obtain 615g the product 4-allyloxy 4'-hydroxydiphenyl sulfone of 96% purity. The yield was 93.5% with respect to 4,4'-dihydroxydiphenyl sulfone. The wet cake of 4,4'-diallyloxydiphenyl sulfone was slurred in 100g of 5%w/v aqueous solution of sodium hydroxide and refluxed for 1 hour, then cooled to 80°C. The precipitate was filtered, washed with water and dried to obtain 45g of 4,4'-diallyloxy diphenyl sulfone of 91.9% purity. The yield was 6% with respect to 4,4'-dihydroxydiphenyl sulfone. pH of the mother liquor obtained after separation of 4-allyloxy 4'-hydroxydiphenyl sulfone, was adjusted to 4.5 with 20% sulfuric acid. The precipitate was separated by filtration, washed with water and dried to obtain 33g of 4,4'-dihydroxydiphenyl sulfone of 87.9% purity. The conversion of 4,4'-dihydroxydiphenyl sulfone was 94.50%.; 595g of 4-allyloxy 4'-hydroxydiphenyl sulfone of 96% purity was dissolved in 230g of 48% strength caustic soda lye and 1000g water, treated with 5g activated carbon and 5g sequestering agent at 85-90°C. The slurry was filtered and pH of the filtrate was adjusted to 8.95 with 20% sulfuric acid and then cooled to 35°C. The precipitate was separated by filtration, slurried in water and the pH was adjusted to 5.0 with 20% sulfuric acid. The slurry was filtrated and the precipitate was washed with water and dried to obtain 563g of 4- allyloxy 4'-hydroxydiphenyl sulfone of 99.273% purity.
ビス(p-アリルオキシフェニル)スルホン 上流と下流の製品情報
原材料
準備製品
ビス(p-アリルオキシフェニル)スルホン 生産企業
Global( 105)Suppliers
41481-63-4(ビス(p-アリルオキシフェニル)スルホン)キーワード:
- 41481-63-4
- 1-(benzenesulfonyl)-4-prop-2-enoxybenzene
- 1,1'-sulfonylbis[4-(2-propenyl)oxy-benzene]
- 1,1'-PHENYLSULFONYL-4,4'-DIENEPROPYL ETHER
- 1,1'-Phenylsulfonyl-4,4'-Dienepropyl(2)Ether
- Bis-[4-(2propenyloxy)-phenyl]-sulfone
- Bis(p-allyloxyphenyl) sulfone
- Sulfonylbis(4,1-phenylene)bis(allyl ether)
- 1-allyloxy-4-(4-allyloxyphenyl)sulfonyl-benzene
- 1-prop-2-enoxy-4-(4-prop-2-enoxyphenyl)sulfonyl-benzene
- BIS(4-ALLYLOXYPHENYL)SULFONE
- Diallyl Ether Bisphenol-S
- Benzene, 1,1'-sulfonylbis[4-(2-propen-1-yloxy)-
- 4,4'-Sulfonylbis((allyloxy)benzene)
- 1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene
- 1,1'-Sulfonylbis[4-(prop-2-en-1-yloxy)benzene
- 4,4'-Sulfonyldiphenolbis(allylether)
- スルホニルビス(4,1-フェニレン)ビス(アリルエーテル)
- ビス(p-アリルオキシフェニル)スルホン
- ビス[4-(アリルオキシ)フェニル]スルホン
- ビス(4-アリルオキシフェニル)スルホン
- ビスフェノルA ジアリルエテル
- ビス（4アリロキシフェニル）スルホン
- ビス（4-アリルオキシフェニル）＝スルホン
- 1-(プロパ-2-エン-1-イルオキシ)-4-[4-(プロパ-2-エン-1-イルオキシ)ベンゼンスルホニル]ベンゼン