폭심
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폭심 속성
- 녹는점
- 5.55°C
- 끓는 점
- bp0.01 102°
- 밀도
- d420 1.176
- 증기압
- 2.1×10-3 Pa (20 °C)
- 굴절률
- nD20 1.5405
- 저장 조건
- 0-6°C
- 용해도
- 아세토니트릴(약간 용해됨), 클로로포름(약간 용해됨), 메탄올(약간 용해됨)
- 수용성
- 1.5mg l-1(20°C)
- 물리적 상태
- 액체
- 색상
- Colorless to light yellow
- 안정성
- 흡습성, 수분 민감성
- InChIKey
- ATROHALUCMTWTB-WYMLVPIESA-N
- CAS 데이터베이스
- 14816-18-3(CAS DataBase Reference)
- NIST
- Phoxim(14816-18-3)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xn;N,N,Xn | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 22-50/53-62-43 | ||
| 안전지침서 | 36-60-61-46-36/37 | ||
| 유엔번호(UN No.) | UN 2810 | ||
| WGK 독일 | 3 | ||
| RTECS 번호 | MD4740000 | ||
| 위험 등급 | 6.1(b) | ||
| 포장분류 | III | ||
| HS 번호 | 29269090 | ||
| 독성 | LD50 orally in mice: >2000 mg/kg (Vinopal, Fukuto) | ||
| 기존화학 물질 | KE-13465 |
| 그림문자(GHS): |
  
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| 신호 어: | Danger | ||||||||||||||||||||||||||||||||||||||||||
| 유해·위험 문구: |
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| 예방조치문구: |
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폭심 C화학적 특성, 용도, 생산
개요
Phoxim is a light yellow liquid, Solubility in water is 1.5 mg/L (20 ?C). It is readily soluble in most organic solvents and slightly in aliphatic hydrocarbons. Log Kow = 3.38. It is relatively slowly hydrolyzed in aqueous media; DT50 (22 ?C) at pH 4, 7, and 9 is 26.7, 7.2, and 3.1 d, respectively.화학적 성질
yellowish oily liquid, Specific gravity: 1.176 (20°C)용도
Phoxim is used to control stored product insect pests in silos and barns. It is also used to control household insects such as ants and other public health pests. Agricultural targets include caterpillars and soil insects in maize, vegetables, cotton and potatoes.Safety Profile
Poison by ingestion. An experimental teratogen. When heated to decomposition it emits very toxic fumes of CN-, NO,, PO,, and SO,. See also NITRILES.신진 대사 경로
The primary metabolic step in the metabolism of phoxim in most biological systems is hydrolysis to the oxime, which may occur either oxidatively or via oxidative desulfuration followed by hydrolysis of the oxon which is much more hydrolytically labile. Stage II metabolism in plants involves the oxime group of the oxaminophenylacetonitrile moiety being reduced to an amine followed by its conjugation with malonic acid. Phoxim is one of a quite large group of insecticidal organophosphates which generates tetraethyl pyrophosphate and its thio analogues under the influence of light. These are compounds which are very active as acetylcholinesterase inhibitors and highly toxic to mammals.신진 대사
Phoxim is oxidatively desulfurated to the oxon, which inhibits housefly AChE 270 times as quickly as bovine AChE. In mammals, the oxon is immediately hydrolyzed into diethyl hydrogen phosphate. The direct cleavage of the oxime ester bond of phoxim, the hydrolytic transformation of the nitrile group into carboxyl, and deethylation also contribute to the low mammalian toxicity. Elimination is very quick, 97% of the dose being excreted in the urine and feces in 24 h. Degradation in soils is also very rapid. By photochemical reactions, the thiooxime phosphate isomer, tetraethyl pyrophosphate, and its monothio analog are produced in small amounts on foliage.폭심 준비 용품 및 원자재
원자재
에틸알코올
염소(기체)
트리에틸아민
삼황화사인
물
티오포스포릴 염화물
페닐아세토나이트릴
아질산 나트륨
Ethanol 95%
디에틸 티오포스포릴 염화물
메틸알콜
Industrial ethanol
에틸 니트리트(아질산에틸)
2-Cyanobenzyloxime
Phosphine crude oil
황산
준비 용품
폭심 공급 업체
글로벌( 223)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Hebei Chuanghai Biotechnology Co., Ltd | +86-15531157085; +8615531157085 |
abby@chuanghaibio.com | China | 8807 | 58 |
| Hebei Mujin Biotechnology Co.,Ltd | +86 13288715578 +8613288715578 |
sales@hbmojin.com | China | 12788 | 58 |
| Qingdao Trust Agri Chemical Co.,Ltd | +8613573296305 |
aroma@qdtrustagri.com | China | 301 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 |
sales@capot.com | China | 29730 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21628 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 |
info@tnjchem.com | China | 2986 | 55 |
| career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29856 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22963 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49732 | 58 |