Cyclopropanecarboxaldehyde manufacturers and suppliers

Cyclopropanecarboxaldehyde suppliers

Properties

Boiling point:: 98-101 °C (lit.)

Density: 0.938 g/mL at 25 °C (lit.)

refractive index: n20/D 1.4298(lit.)

Flash point:: 45 °F

storage temp.: 2-8°C

solubility: soluble in Chloroform

form: clear liquid

color: Colorless to Light orange to Yellow

Water Solubility: Soluble in water.

Sensitive: Air Sensitive

BRN: 906781

Stability:: Volatile

InChIKey: JMYVMOUINOAAPA-UHFFFAOYSA-N

CAS DataBase Reference: 1489-69-6(CAS DataBase Reference)

NIST Chemistry Reference: Cyclopropanecarboxaldehyde(1489-69-6)

EPA Substance Registry System: Cyclopropanecarboxaldehyde (1489-69-6)

Safety Information

Symbol(GHS): GHS02,GHS05

Signal word: Danger

Hazard statements: H225-H314

Precautionary statements: P210-P233-P240-P280-P303+P361+P353-P305+P351+P338

Hazard Codes: F,C

Risk Statements: 11-34

Safety Statements: 16-26-36/37/39-45

RIDADR: UN 2924 3/PG 2

WGK Germany: 3

RTECS: GZ1005000

TSCA: Yes

HazardClass: 3

PackingGroup: II

HS Code: 29122990

Use

Cyclopropanecarboxaldehyde can react with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides. It is also used in the synthesis of eta(2)-enonenickel complexes by reacting with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) and to prepare a cyclopropylidene tetralone which underwent an enantioselective palladium-catalyzed [3+2] TMM cycloaddition providing a chiral spiro-fused cyclopentene1-2. It is also a reagent in the preparation of N-alkylphenylalaninamides of pyridinylphenyland oxobipyridinylamines as human GPR 142 agonists for potential use as anti-diabetic agents and the cytochrome P 450 inhibition3.

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