Ethyl 3-methyl-3-phenylglycidate manufacturers and suppliers

Ethyl 3-methyl-3-phenylglycidate suppliers

Properties

Boiling point:: 272-275 °C(lit.)

Density: 1.087 g/mL at 25 °C(lit.)

refractive index: n20/D 1.505(lit.)

FEMA: 2444 | ETHYL METHYLPHENYLGLYCIDATE

Flash point:: >230 °F

storage temp.: 2-8°C

form: clear liquid

color: Colorless to Light orange to Yellow

Odor: at 100.00 %. sweet fruity strawberry floral honey fatty

Odor Type: fruity

biological source: synthetic

JECFA Number: 1577

BRN: 12299

LogP: 2.43

CAS DataBase Reference: 77-83-8(CAS DataBase Reference)

NIST Chemistry Reference: Glycidic acid, 3-methyl-3-phenyl, ethyl ester(77-83-8)

EPA Substance Registry System: Ethyl methylphenylglycidate (77-83-8)

Safety Information

Symbol(GHS): GHS07,GHS09

Signal word: Warning

Hazard statements: H317-H411

Precautionary statements: P261-P272-P273-P280-P302+P352-P333+P313

Hazard Codes: Xi

Risk Statements: 10-36/37/38

Safety Statements: 16-26-36/37/39

RIDADR: UN 1993 3/PG 3

WGK Germany: 2

RTECS: MW5250000

TSCA: Yes

HS Code: 29189090

Hazardous Substances Data: 77-83-8(Hazardous Substances Data)

Toxicity: LD50 orally in Rabbit: 5470 mg/kg

Use

Ethyl 3-Methyl-3-phenylglycidate exists as two optically active pairs of cis- and trans-isomers; each isomer has a characteristic odor . The commercial product is a racemic mixture of all four isomers and has a strong, sweetish, strawberry odor. The cis/trans ratio obtained in the Darzens condensation of acetophenone (R==CH3) and ethyl chloroacetate depends on the base used in the reaction.

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