Trifluoromethanesulfonic acid manufacturers and suppliers

Trifluoromethanesulfonic acid suppliers

Properties

Melting point:: -40 °C

Boiling point:: 162 °C (lit.)

Density: 1.696 g/mL at 25 °C (lit.)

vapor density: 5.2 (vs air)

vapor pressure: 8 mm Hg ( 25 °C)

refractive index: n20/D 1.327(lit.)

RTECS: PB2771000

Flash point:: None

storage temp.: Store below +30°C.

solubility: Miscible in H<sub>2</sub>O

pka: -14(at 25℃)

form: Fuming Liquid

color: slightly brown

Specific Gravity: 1.696

PH: <1 (H2O)

Water Solubility: SOLUBLE

Sensitive: Hygroscopic

Merck: 14,9676

BRN: 1812100

Stability:: Stable. Incompatible with acids, alkalis, metals.

InChIKey: ITMCEJHCFYSIIV-UHFFFAOYSA-N

LogP: 0.3 at 25℃

CAS DataBase Reference: 1493-13-6(CAS DataBase Reference)

NIST Chemistry Reference: CF3SO3H(1493-13-6)

EPA Substance Registry System: Methanesulfonic acid, trifluoro- (1493-13-6)

Safety Information

Symbol(GHS): GHS05,GHS07

Signal word: Danger

Hazard statements: H290-H302-H314-H335

Precautionary statements: P234-P261-P280-P301+P312-P303+P361+P353-P305+P351+P338

Hazard Codes: C

Risk Statements: 21/22-35-10

Safety Statements: 26-36/37/39-45

RIDADR: UN 3265 8/PG 2

WGK Germany: 2

F: 3-10

Hazard Note: Corrosive/Hygroscopic

TSCA: Yes

HazardClass: 8

PackingGroup: II

HS Code: 29049020

Toxicity: LD50 orally in Rabbit: 1605 mg/kg LD50 dermal Rat > 2000 mg/kg

Limited Quantities: 1.0 L (0.3 gallons) (liquid) or 1 Kg (2.2 lbs) (solid)

Excepted Quantities: Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)

Use

Trifluoromethanesulfonic acid is a hygroscopic, colorless liquid at room temperature. It is soluble in polar solvents such as dimethylformamide (DMF), dimethyl sulfoxide (DMSO), acetonitrile, and dimethyl sulfone. Addition of triflic acid to polar solvents can be dangerously exothermic. Trifluoromethanesulfonic acid is widely used especially as a catalyst and a precursor in organic chemistry. With an Ka = 8. 0 1014 (pKa ~ -15) mol/kg, HOTf qualifies as a superacid. Triflic acid owes many of its useful properties to its great thermal and chemical stability. Both the acid and its conjugate base CF3SO3-, known as triflate, resist oxidation/reduction reactions, whereas many strong acids are oxidizing, e. g. HClO4 and HNO3. The triflate anion is immune to attack by even strong nucleophiles. Because of its resistance to oxidation and reduction, triflic acid is a very useful and versatile reagent. Further recommending its use, triflic acid does not sulfonate substrates, which can be a problem with sulfuric acid, fluorosulfuric acid, and chlorosulfonic acid. Below is a prototypical sulfonation, which HOTf does not undergo: C6H6 + H2SO4 C6H5(SO3H) + H2O.

You can find Trifluoromethanesulfonic acid suppliers, manufacturers, and distributors from countries such as China, United States and the India here. Browse to the tetrahydrofuran product information displayed by the supplier, as well as the supplier's contact and capability information.