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ChemicalBook >> CAS DataBase List >> 1-Methyl-2-propenylmagnesium chloride

1-Methyl-2-propenylmagnesium chloride

$175 - $737
Product name: 1-Methyl-2-propenylmagnesium chloride
CAS: 21969-32-4
MF: C4H7ClMg
MW: 114.86
EINECS:
MDL Number:MFCD00216570
Synonyms:1-Methyl-2-propenylmagnesium chloride 0.5M solution in THF;1-Methyl-2-propenylmagnesium chloride, 0.25 M in 2-MeTHF;1-Methyl-2-propenylmagnesium chloride, 0.25 M in THF;1-Methyl-2-propenylmagnesium chloride solution;1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE, 0 .5M SOLUTION IN TETRAHYDROFURAN;1-Methyl-2-propenylmagnesium chloride solution 0.5 in THF;1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF;chlorure de buten-2 ylmagnesium

Price11 Properties Safety Information Description

11 prices

Selected condition：

Brand

Matrix Scientific
Rieke Metals
Sigma-Aldrich

Package

50ml
100ml
500ml

ManufacturerMatrix Scientific
Product number121864
Product description1-Methyl-2-propenylmagnesiumchloride 0.25MinTHF97%
Packaging50ml
Price$232
Updated2021-12-16
Buy

ManufacturerMatrix Scientific
Product number121862
Product description1-Methyl-2-propenylmagnesiumchloride 0.25Min2-MeTHF97%
Packaging50ml
Price$232
Updated2021-12-16
Buy

ManufacturerMatrix Scientific
Product number121862
Product description1-Methyl-2-propenylmagnesiumchloride 0.25Min2-MeTHF97%
Packaging100ml
Price$332
Updated2021-12-16
Buy

ManufacturerMatrix Scientific
Product number121864
Product description1-Methyl-2-propenylmagnesiumchloride 0.25MinTHF97%
Packaging100ml
Price$332
Updated2021-12-16
Buy

ManufacturerMatrix Scientific
Product number121862
Product description1-Methyl-2-propenylmagnesiumchloride 0.25Min2-MeTHF97%
Packaging500ml
Price$737
Updated2021-12-16
Buy

ManufacturerMatrix Scientific
Product number121864
Product description1-Methyl-2-propenylmagnesiumchloride 0.25MinTHF97%
Packaging500ml
Price$737
Updated2021-12-16
Buy

ManufacturerRieke Metals
Product numberG0381
Product description1-Methyl-2-propenylmagnesium chloride
Packaging50mL
Price$175
Updated2026-05-06
Buy

ManufacturerRieke Metals
Product numberT0381
Product description1-Methyl-2-propenylmagnesium chloride
Packaging50mL
Price$175
Updated2026-05-06
Buy

ManufacturerRieke Metals
Product numberG0381
Product description1-Methyl-2-propenylmagnesium chloride
Packaging100mL
Price$335
Updated2026-05-06
Buy

ManufacturerRieke Metals
Product numberT0381
Product description1-Methyl-2-propenylmagnesium chloride
Packaging100mL
Price$335
Updated2026-05-06
Buy

ManufacturerSigma-Aldrich
Product number420042
Product description1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF
Packaging100ml
Price$397
Updated2026-04-30
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
Matrix Scientific	121864	1-Methyl-2-propenylmagnesiumchloride 0.25MinTHF97%	50ml	$232	2021-12-16	Buy
Matrix Scientific	121862	1-Methyl-2-propenylmagnesiumchloride 0.25Min2-MeTHF97%	50ml	$232	2021-12-16	Buy
Matrix Scientific	121862	1-Methyl-2-propenylmagnesiumchloride 0.25Min2-MeTHF97%	100ml	$332	2021-12-16	Buy
Matrix Scientific	121864	1-Methyl-2-propenylmagnesiumchloride 0.25MinTHF97%	100ml	$332	2021-12-16	Buy
Matrix Scientific	121862	1-Methyl-2-propenylmagnesiumchloride 0.25Min2-MeTHF97%	500ml	$737	2021-12-16	Buy
Matrix Scientific	121864	1-Methyl-2-propenylmagnesiumchloride 0.25MinTHF97%	500ml	$737	2021-12-16	Buy
Rieke Metals	G0381	1-Methyl-2-propenylmagnesium chloride	50mL	$175	2026-05-06	Buy
Rieke Metals	T0381	1-Methyl-2-propenylmagnesium chloride	50mL	$175	2026-05-06	Buy
Rieke Metals	G0381	1-Methyl-2-propenylmagnesium chloride	100mL	$335	2026-05-06	Buy
Rieke Metals	T0381	1-Methyl-2-propenylmagnesium chloride	100mL	$335	2026-05-06	Buy
Sigma-Aldrich	420042	1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF	100ml	$397	2026-04-30	Buy

Properties

Boiling point :67 °C
Density :0.917 g/mL at 25 °C
Flash point :−4 °F
InChI :1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1
InChIKey :RTJGBPYEBKZQGE-UHFFFAOYSA-M
SMILES :CC([Mg]Cl)C=C

Safety Information

Symbol(GHS):

Signal word:

Danger

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	P-Codes
H225	Highly Flammable liquid and vapour	Flammable liquids	Category 2	Danger	P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261	In contact with water releases flammable gas	Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases	Category 2 Category 3	Danger Warning	P231+P232, P280, P370+P378,P402+P404, P501
H302	Harmful if swallowed	Acute toxicity,oral	Category 4	Warning	P264, P270, P301+P312, P330, P501
H314	Causes severe skin burns and eye damage	Skin corrosion/irritation	Category 1A, B, C	Danger	P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335	May cause respiratory irritation	Specific target organ toxicity, single exposure;Respiratory tract irritation	Category 3	Warning
H351	Suspected of causing cancer	Carcinogenicity	Category 2	Warning	P201, P202, P281, P308+P313, P405,P501

Precautionary statements:

P210	Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232	Handle under inert gas. Protect from moisture.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378	In case of fire: Use … for extinction.
P402+P404	Store in a dry place. Store in a closed container.
P403+P235	Store in a well-ventilated place. Keep cool.

Description

1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.

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Suppliers and manufacturers

Beijing Ouhe Technology Co., Ltd Shanghai Hanhong Scientific Co.,Ltd. Shandong Xiya Chemical Co., Ltd Shanghai T&W Pharmaceutical Co., Ltd. Shanghai Xingui Biotechnology Co., Ltd. Sigma-Aldrich Shanghai YuanYe Biotechnology Co., Ltd. Shandong Ono Chemical Co., Ltd. Shanghai Jizhi Biochemical Technology Co. Ltd. Hefei TNJ Chemical Industry Co.,Ltd.

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1-Methyl-2-propenylmagnesium chloride

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Description

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