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1-Methyl-2-propenylmagnesium chloride

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1-Methyl-2-propenylmagnesium chloride Basic information
Product Name:1-Methyl-2-propenylmagnesium chloride
Synonyms:1-Methyl-2-propenylmagnesium chloride 0.5M solution in THF;1-Methyl-2-propenylmagnesium chloride, 0.25 M in 2-MeTHF;1-Methyl-2-propenylmagnesium chloride, 0.25 M in THF;1-Methyl-2-propenylmagnesium chloride solution;1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE, 0 .5M SOLUTION IN TETRAHYDROFURAN;1-Methyl-2-propenylmagnesium chloride solution 0.5 in THF;1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF;chlorure de buten-2 ylmagnesium
CAS:21969-32-4
MF:C4H7ClMg
MW:114.86
EINECS:
Product Categories:Chemical Synthesis;Grignard Reagents;Organometallic Reagents;Alkyl;Grignard Reagents;Organometallic Reagents;Grignard Reagent
Mol File:21969-32-4.mol
1-Methyl-2-propenylmagnesium chloride Structure
1-Methyl-2-propenylmagnesium chloride Chemical Properties
Boiling point 67 °C
density 0.917 g/mL at 25 °C
Fp −4 °F
InChI1S/C4H7.ClH.Mg/c1-3-4-2;;/h3-4H,1H2,2H3;1H;/q;;+1/p-1
InChIKeyRTJGBPYEBKZQGE-UHFFFAOYSA-M
SMILESCC([Mg]Cl)C=C
Safety Information
Hazard Codes F,C,Xn
Risk Statements 11-14-19-20/21/22-34-40-36/37/38-14/15
Safety Statements 16-26-27-36/37/39-45-43-36/37
RIDADR UN 3399 4.3/PG 2
WGK Germany 3
HS Code 29319090
Storage Class4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard ClassificationsAcute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 2
MSDS Information
ProviderLanguage
SigmaAldrich English
1-Methyl-2-propenylmagnesium chloride Usage And Synthesis
Chemical PropertiesBrown liquid
Uses1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.
reaction suitabilityreaction type: Grignard Reaction
1-Methyl-2-propenylmagnesium chloride Preparation Products And Raw materials
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