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ChemicalBook >> CAS DataBase List >> Methyl alpha-bromoacrylate 95

Methyl alpha-bromoacrylate 95

Methyl alpha-bromoacrylate 95 price.
  • $16 - $1881
  • Product name: Methyl alpha-bromoacrylate 95
  • CAS: 4519-46-4
  • MF: C4H5BrO2
  • MW: 164.99
  • EINECS:200-258-5
  • MDL Number:MFCD08276754
  • Synonyms:2-Bromopropenoic acid methyl ester;Methyl 2-bromoprop-2-enoate;2-Propenoic acid, 2-broMo-, Methyl ester;Methyl alpha-bromoacrylate 95%;Methyl α-bromoacrylate, CAS 4519-46-4;2-bromopropyl-2-eneacidmethyl ester;methyl α-bromoacrylate;Methyl α-bromoacrylate
24 prices
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  • aablocks
  • ACHEMBLOCK
  • Ambeed
  • American Custom Chemicals Corporation
  • Apolloscientific
  • Chemenu
  • Sigma-Aldrich
  • Synthonix
  • TRC
Package
  • 100mg
  • 250mg
  • 1g
  • 5g
  • 10g
  • 25G
  • 100G
  • Manufactureraablocks
  • Product numberAA00356J
  • Product descriptionMethyl 2-Bromoacrylate 98%(stabilizedwithMEHQ)
  • Packaging250mg
  • Price$16
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA00356J
  • Product descriptionMethyl 2-Bromoacrylate 98%(stabilizedwithMEHQ)
  • Packaging1g
  • Price$19
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA00356J
  • Product descriptionMethyl 2-Bromoacrylate 98%(stabilizedwithMEHQ)
  • Packaging5g
  • Price$57
  • Updated2026-05-28
  • Buy
  • ManufacturerACHEMBLOCK
  • Product numberU107689
  • Product descriptionMethyl 2-bromoacrylate 95.00%
  • Packaging25G
  • Price$340
  • Updated2026-05-27
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  • ManufacturerACHEMBLOCK
  • Product numberU107689
  • Product descriptionMethyl 2-bromoacrylate 95.00%
  • Packaging100G
  • Price$965
  • Updated2026-05-27
  • Buy
  • ManufacturerAmbeed
  • Product numberA817668
  • Product descriptionMethyl2-bromoacrylate 98%(stabilizedwithMEHQ)
  • Packaging5g
  • Price$284
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA817668
  • Product descriptionMethyl2-bromoacrylate 98%(stabilizedwithMEHQ)
  • Packaging25g
  • Price$950
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA817668
  • Product descriptionMethyl2-bromoacrylate 98%(stabilizedwithMEHQ)
  • Packaging10g
  • Price$530
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA817668
  • Product descriptionMethyl2-bromoacrylate 98%(stabilizedwithMEHQ)
  • Packaging250mg
  • Price$37
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA817668
  • Product descriptionMethyl2-bromoacrylate 98%(stabilizedwithMEHQ)
  • Packaging1g
  • Price$92
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberHCH0098802
  • Product descriptionMETHYL ALPHA-BROMOACRYLATE 98.00%
  • Packaging1G
  • Price$937.46
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR941547
  • Product descriptionMethyl 2-bromoacrylate 99%
  • Packaging100g
  • Price$1881
  • Updated2026-06-04
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  • ManufacturerApolloscientific
  • Product numberOR941547
  • Product descriptionMethyl 2-bromoacrylate 99%
  • Packaging5g
  • Price$100
  • Updated2026-06-04
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR941547
  • Product descriptionMethyl 2-bromoacrylate 99%
  • Packaging1g
  • Price$22
  • Updated2026-06-04
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR941547
  • Product descriptionMethyl 2-bromoacrylate 99%
  • Packaging25g
  • Price$476
  • Updated2026-06-04
  • Buy
  • ManufacturerChemenu
  • Product numberCM343171
  • Product descriptionMethyl 2-bromoacrylate 95%+
  • Packaging10g
  • Price$163
  • Updated2026-05-26
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
aablocks AA00356J Methyl 2-Bromoacrylate 98%(stabilizedwithMEHQ) 250mg $16 2026-05-28 Buy
aablocks AA00356J Methyl 2-Bromoacrylate 98%(stabilizedwithMEHQ) 1g $19 2026-05-28 Buy
aablocks AA00356J Methyl 2-Bromoacrylate 98%(stabilizedwithMEHQ) 5g $57 2026-05-28 Buy
ACHEMBLOCK U107689 Methyl 2-bromoacrylate 95.00% 25G $340 2026-05-27 Buy
ACHEMBLOCK U107689 Methyl 2-bromoacrylate 95.00% 100G $965 2026-05-27 Buy
Ambeed A817668 Methyl2-bromoacrylate 98%(stabilizedwithMEHQ) 5g $284 2021-12-16 Buy
Ambeed A817668 Methyl2-bromoacrylate 98%(stabilizedwithMEHQ) 25g $950 2021-12-16 Buy
Ambeed A817668 Methyl2-bromoacrylate 98%(stabilizedwithMEHQ) 10g $530 2021-12-16 Buy
Ambeed A817668 Methyl2-bromoacrylate 98%(stabilizedwithMEHQ) 250mg $37 2021-12-16 Buy
Ambeed A817668 Methyl2-bromoacrylate 98%(stabilizedwithMEHQ) 1g $92 2021-12-16 Buy
American Custom Chemicals Corporation HCH0098802 METHYL ALPHA-BROMOACRYLATE 98.00% 1G $937.46 2021-12-16 Buy
Apolloscientific OR941547 Methyl 2-bromoacrylate 99% 100g $1881 2026-06-04 Buy
Apolloscientific OR941547 Methyl 2-bromoacrylate 99% 5g $100 2026-06-04 Buy
Apolloscientific OR941547 Methyl 2-bromoacrylate 99% 1g $22 2026-06-04 Buy
Apolloscientific OR941547 Methyl 2-bromoacrylate 99% 25g $476 2026-06-04 Buy
Chemenu CM343171 Methyl 2-bromoacrylate 95%+ 10g $163 2026-05-26 Buy

Properties

Boiling point :70-75 °C48 mm Hg(lit.)
Density :1.556 g/mL at 25 °C(lit.)
Flash point :134 °F
storage temp. :-20°C
Appearance :Colorless to light yellow Liquid
InChI :InChI=1S/C4H5BrO2/c1-3(5)4(6)7-2/h1H2,2H3
InChIKey :HVJXPDPGPORYKY-UHFFFAOYSA-N
SMILES :C(OC)(=O)C(Br)=C
CAS DataBase Reference :4519-46-4

Safety Information

Symbol(GHS): Flame (GHS02)Exclamation Mark (GHS07)
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1,1,2-tribromocyclopropanecarboxylate. It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity. These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates.

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