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ChemicalBook >> CAS DataBase List >> (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis(R)-1phenylethyl]amine

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis(R)-1phenylethyl]amine

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis(R)-1phenylethyl]amine price.
  • $57 - $1059
  • Product name: (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis(R)-1phenylethyl]amine
  • CAS: 500997-69-3
  • MF: C33H32NO2P
  • MW: 505.59
  • EINECS:
  • MDL Number:MFCD08459342
  • Synonyms:(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1-PHENYLETHYL]AMINE;(S)-SIPHOS-PE;(R)-SIPHOS-PE;N-DI[(R)-1-PHENYLETHYL]-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE;N-DI[(R)-1-PHENYLETHYL]-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]-PHOSPHORAMIDITE;(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine,min.98%(R)-SIPHOS-PE;N-Di[(R)-1-phenylethyl]-[(R)-1,1'-spirobiindane-7,7'-diyl]-phosphoramidite ,98%;(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine
Price11 Properties Safety Information Description
11 prices
Selected condition：
Brand
  • aablocks
  • AK Scientific
  • ChemScene
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 50mg
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 5g
  • Manufactureraablocks
  • Product numberAA00DCK7
  • Product description(11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 98%
  • Packaging50mg
  • Price$57
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA00DCK7
  • Product description(11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 95%
  • Packaging100mg
  • Price$68
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA00DCK7
  • Product description(11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 95%
  • Packaging250mg
  • Price$85
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA00DCK7
  • Product description(11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 95%
  • Packaging1g
  • Price$212
  • Updated2026-05-28
  • Buy
  • Manufactureraablocks
  • Product numberAA00DCK7
  • Product description(11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 95%
  • Packaging5g
  • Price$1059
  • Updated2026-05-28
  • Buy
  • ManufacturerAK Scientific
  • Product number2465AQ
  • Product description(Ra,R,R)-SIPHOS-PE
  • Packaging50mg
  • Price$352.4
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0037331
  • Product description(R)-SIPHOS-PE ≥97.0%
  • Packaging50mg
  • Price$95
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-0037331
  • Product description(R)-SIPHOS-PE ≥97.0%
  • Packaging100mg
  • Price$185
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number700770
  • Product description(R)-SIPHOS-PE 97%
  • Packaging50mg
  • Price$190
  • Updated2022-05-15
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-5162
  • Product description(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (R)-SIPHOS-PE min.98%
  • Packaging100mg
  • Price$197
  • Updated2026-04-30
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-5162
  • Product description(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (R)-SIPHOS-PE min.98%
  • Packaging500mg
  • Price$776
  • Updated2026-04-30
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
aablocks AA00DCK7 (11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 98% 50mg $57 2026-05-28 Buy
aablocks AA00DCK7 (11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 95% 100mg $68 2026-05-28 Buy
aablocks AA00DCK7 (11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 95% 250mg $85 2026-05-28 Buy
aablocks AA00DCK7 (11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 95% 1g $212 2026-05-28 Buy
aablocks AA00DCK7 (11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine 95% 5g $1059 2026-05-28 Buy
AK Scientific 2465AQ (Ra,R,R)-SIPHOS-PE 50mg $352.4 2021-12-16 Buy
ChemScene CS-0037331 (R)-SIPHOS-PE ≥97.0% 50mg $95 2021-12-16 Buy
ChemScene CS-0037331 (R)-SIPHOS-PE ≥97.0% 100mg $185 2021-12-16 Buy
Sigma-Aldrich 700770 (R)-SIPHOS-PE 97% 50mg $190 2022-05-15 Buy
Strem Chemicals 15-5162 (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (R)-SIPHOS-PE min.98% 100mg $197 2026-04-30 Buy
Strem Chemicals 15-5162 (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (R)-SIPHOS-PE min.98% 500mg $776 2026-04-30 Buy

Properties

Melting point :98-100°C
alpha :+300° (c 1.0, CH2Cl2)
Boiling point :617.8±65.0 °C(Predicted)
storage temp. :-20°C
pka :0.40±0.20(Predicted)
form :solid
color :white
optical activity :[α]22/D +337°, c = 1 in chloroform
Sensitive :moisture sensitive
InChIKey :ZXLQLIDJAURBDD-HRPAVAKOSA-N

Safety Information

Symbol(GHS): Exclamation Mark (GHS07)
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(R)-SIPHOS-PE can be used as:
  • A catalyst in the preparation of tricyclic alkaloid (+)-aphanorphine via asymmetric carboamination and Friedel?Crafts reaction.
  • A ligand in the synthesis of chiral ketones via hydroacylation of olefins using salicylaldehyde derivatives.
  • A ligand in the enantioselective synthesis of substituted pyrrolidine derivatives via Pd-catalyzed alkene aminoarylation reactions.

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Suppliers and manufacturers

J & K SCIENTIFIC LTD. Meryer (Shanghai) Chemical Technology Co., Ltd. Tianjin Derchemist Science & Technology Co., Ltd. Bide Pharmatech Ltd. Sigma-Aldrich Shanghai Chiral bio-compound co., Ltd. ShangHai Angti Biotechnology Co., Ltd. Shanghai YuanYe Biotechnology Co., Ltd. Shanghai SuperLan Chemcial Technique Centre LaaJoo