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(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline)

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(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline) Basic information
Product Name:(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline)
Synonyms:2,2'-Methylenebis[(4S)-4-tert-butyl-4,5-dihydro-2-oxazole];Bis((4S)-4-tert-butyl-4,5-dihydrooxazol-2-yl)methane;bis((S)-4-(tert-butyl)-4,5-dihydrooxazol-2-yl)methane;(4S,4'S)-2,2'-methylenebis[4-(1,1-dimethylethyl)-4,5-dihydro-Oxazole;Oxazole, 2,2'-methylenebis[4-(1,1-dimethylethyl)-4,5-dihydro-, (4S,4'S)-;Bis[(S)-4-(tert-butyl)-4,5-dihydro-2-oxazolyl]methane;2,2′-Methylenebis[(4S)-4-tert-butyl-2-oxazoline];(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline)
CAS:132098-54-5
MF:C15H26N2O2
MW:266.38
EINECS:
Product Categories:
Mol File:132098-54-5.mol
(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline) Structure
(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline) Chemical Properties
Melting point 51-53 °C(lit.)
Boiling point 328.8±25.0 °C(Predicted)
density 1.08±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka5.39±0.70(Predicted)
AppearanceWhite to off-white Solid
Optical Rotation[α]20/D 118°, c = 0.5 in chloroform
BRN 4190673
InChIInChI=1S/C15H26N2O2/c1-14(2,3)10-8-18-12(16-10)7-13-17-11(9-19-13)15(4,5)6/h10-11H,7-9H2,1-6H3/t10-,11-/m1/s1
InChIKeyWCCCBUXURHZPQL-GHMZBOCLSA-N
SMILESC(C1=N[C@@H](C(C)(C)C)CO1)C1=N[C@@H](C(C)(C)C)CO1
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
F 10
MSDS Information
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SigmaAldrich English
(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline) Usage And Synthesis
UsesC2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.
(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline) Preparation Products And Raw materials
Preparation Products(S,S)-(-)-2,2'-Isopropylidenebis(4-tert-butyl-2-oxazoline)-->(4S,4'S)-2,2'-Cyclopropylidenebis[4-tert-butyl-4,5-dihydro oxazole],99%e.e.
Tag:(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline)(132098-54-5) Related Product Information
2,2'-METHYLENEBIS[(4R,5S)-4,5-DIPHENYL-2-OXAZOLINE] Bis((S)-4-isobutyl-4,5-dihydrooxazol-2-yl)methane (4R,4'R)-2,2'-methylenebis[4,5-dihydro-4-(phenylmethyl)-Oxazole Oxazole, 2,2'-methylenebis[4,5-dihydro-4-methyl-, (4S,4'S)- (4S,4'S,5R,5'R)-2,2'-methylenebis[4,5-dihydro-4,5-diphenyl-Oxazole (S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Bis((6-bromopyridin-3-yl)methyl)amine INDEX NAME NOT YET ASSIGNED (4S,4'S)-2,2'-methylenebis[4,5-dihydro-4-(phenylmethyl)-Oxazole 2,2'-methylenebis[(4S)-4-tert-butyl-2-oxazoline] 2,2-Bis[(4R)-4-isopropyl-2-oxazolin-2-yl]propane (S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE) (R,R)-(-)-2,2'-Isopropylidenebis(4-tert-butyl-2-oxazoline) (S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline) (R)-TERT-LEUCINOL 2-Ethyl-2-oxazoline (4R)-4-T-BUTYL-2-METHYL 2-OXAZOLINE