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Ethyl 2-oxo-1-cyclooctanecarboxylate

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Ethyl 2-oxo-1-cyclooctanecarboxylate manufacturers

Ethyl 2-oxo-1-cyclooctanecarboxylate Basic information
Product Name:Ethyl 2-oxo-1-cyclooctanecarboxylate
Synonyms:Ethyl 2-oxo-1-cyclooctane-carboxylate, 98+%;Cyclooctanecarboxylic acid, 2-oxo-, ethyl ester;Ethyl 2-oxo-1-cyclooctanecarboxylate 97%;ethyl2-oxocyclooctane-1-carboxylate;Ethyl 2-oxo-1-cyclooctanecarboxylate;2-oxycloctylalkanethyl formate;Ethyl 2-oxo-1-cyclooctanecarboxylate
CAS:4017-56-5
MF:C11H18O3
MW:198.26
EINECS:
Product Categories:Building Blocks;C10 to C11;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;C10 to C11;Carbonyl Compounds;Esters
Mol File:4017-56-5.mol
Ethyl 2-oxo-1-cyclooctanecarboxylate Structure
Ethyl 2-oxo-1-cyclooctanecarboxylate Chemical Properties
Boiling point 85-87 °C/0.1 mmHg (lit.)
density 1.04 g/mL at 25 °C (lit.)
refractive index n20/D 1.483(lit.)
Fp >230 °F
form Liquid
pka12.32±0.20(Predicted)
color Clear colorless
InChI1S/C11H18O3/c1-2-14-11(13)9-7-5-3-4-6-8-10(9)12/h9H,2-8H2,1H3
InChIKeyOJCDCHCBNASPBS-UHFFFAOYSA-N
SMILESCCOC(=O)C1CCCCCCC1=O
CAS DataBase Reference4017-56-5
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29183000
Storage Class10 - Combustible liquids
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
Ethyl 2-oxo-1-cyclooctanecarboxylate Usage And Synthesis
Chemical Propertiesclear colorless liquid
UsesEthyl 2-oxo-1-cyclooctanecarboxylate (2-carbethoxycyclooctanone) may be used in the synthesis of 2-carbethoxy-2-cyclooctenone.
General DescriptionEthyl 2-oxo-1-cyclooctanecarboxylate (2-carbethoxycyclooctanone) is a β-keto ester. It undergoes Michael addition with 3-buten-2-one (methyl vinyl ketone, MVK) in the presence of potassium bis(1,2-benzenediolato)phenylsilicate to afford the corresponding 1,4-adduct. It can be synthesized from cycloheptanone. Its boiling point, density and refractive index have been determined.
Ethyl 2-oxo-1-cyclooctanecarboxylate Preparation Products And Raw materials
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