- 2-IODOBENZOYL CHLORIDE
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- $15.00 / 1KG
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2021-08-12
- CAS:609-67-6
- Min. Order: 1KG
- Purity: 99%+ HPLC
- Supply Ability: Monthly supply of 1 ton
- 2-Iodobenzoyl Chloride
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- $15.00 / 1KG
-
2021-07-02
- CAS:609-67-6
- Min. Order: 1KG
- Purity: 99%+ HPLC
- Supply Ability: Monthly supply of 1 ton
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| | 2-IODOBENZOYL CHLORIDE Basic information |
| | 2-IODOBENZOYL CHLORIDE Chemical Properties |
| Melting point | 27-31 °C(lit.) | | Boiling point | 105-106 °C1 mm Hg(lit.) | | density | 1.932 | | Fp | >110°C | | storage temp. | Keep in dark place,Inert atmosphere,2-8°C | | solubility | soluble in Toluene | | form | powder to lump | | color | White to Light yellow to Dark green | | Water Solubility | Reacts with water. | | Sensitive | Moisture & Light Sensitive | | BRN | 2042672 | | InChIKey | MVIVDSWUOGNODP-UHFFFAOYSA-N | | CAS DataBase Reference | 609-67-6(CAS DataBase Reference) | | EPA Substance Registry System | Benzoyl chloride, 2-iodo- (609-67-6) |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3261 8/PG 2 | | WGK Germany | 3 | | F | 21-19 | | TSCA | TSCA listed | | HazardClass | 8 | | PackingGroup | II | | HS Code | 29163990 |
| | 2-IODOBENZOYL CHLORIDE Usage And Synthesis |
| Chemical Properties | white to pinkish or pale yellow crystalline | | Uses | 2-Iodobenzoyl chloride has been used in palladium-catalyzed synthesis of carbomethoxy functional group-induced isoindolin-1-ones, preparation of starting materials required for the synthesis of novel cyclic derivatives of pentavalent iodine, benziodazole oxides. | | Uses | 2-Iodobenzoyl chloride has been used in:
- palladium-catalyzed synthesis of carbomethoxy functional group-induced isoindolin-1-ones
- preparation of starting materials required for the synthesis of novel cyclic derivatives of pentavalent iodine, benziodazole oxides
| | Synthesis | General method: 2-iodobenzoic acid (1.0 mmol) was mixed with excess thionyl chloride (5 mL) and reacted at reflux for 2 hours. Upon completion of the reaction, the excess thionyl chloride was removed by vacuum concentration to give o-iodobenzoyl chloride in quantitative yield. | | References | [1] Journal of Medicinal Chemistry, 1994, vol. 37, # 12, p. 1737 - 1739
[2] Chinese Chemical Letters, 2013, vol. 24, # 8, p. 673 - 676
[3] Patent: WO2015/137750, 2015, A1. Location in patent: Paragraph 1245; 1246
[4] Organometallics, 2013, vol. 32, # 11, p. 3220 - 3226
[5] Synlett, 1999, # 11, p. 1763 - 1765 |
| | 2-IODOBENZOYL CHLORIDE Preparation Products And Raw materials |
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