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2-IODOBENZALDEHYDE

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Products Intro: Product Name:2-Iodobenzaldehyde
CAS:26260-02-6
Purity:98%(Min,GC) Package:1G;1KG;100KG
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CAS:26260-02-6
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Products Intro: Product Name:2-Iodobenzaldehyde
CAS:26260-02-6
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CAS:26260-02-6
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2-IODOBENZALDEHYDE manufacturers

  • 2-Iodobenzaldehyde
  • 2-Iodobenzaldehyde pictures
  • $0.00 / 1g
  • 2026-02-02
  • CAS:26260-02-6
  • Min. Order: 10mg
  • Purity: 99%HPLC
  • Supply Ability: 2000tons
  • 2-Iodobenzaldehyde
  • 2-Iodobenzaldehyde pictures
  • $0.00 / 1KG
  • 2025-04-04
  • CAS:26260-02-6
  • Min. Order: 1KG
  • Purity: 98%
  • Supply Ability: 1Ton
  • 2-IODOBENZALDEHYDE
  • 2-IODOBENZALDEHYDE pictures
  • $6.60 / 1KG
  • 2020-01-03
  • CAS:26260-02-6
  • Min. Order: 1KG
  • Purity: 97%-99%
  • Supply Ability: 1kg -1000kg
2-IODOBENZALDEHYDE Basic information
Product Name:2-IODOBENZALDEHYDE
Synonyms:2-IODOBENZALDEHYDE;2-Iodobenzaldehyde o-Iodobenzaldehyde;2-Iodobenzaldehyde,98%;o-Iodobenzaldehyde;Benzaldehyde, 2-iodo-;2-Iodobenzaldehyde 97%
CAS:26260-02-6
MF:C7H5IO
MW:232.02
EINECS:
Product Categories:Aromatic Aldehydes & Derivatives (substituted);Aldehydes;Phenyls & Phenyl-Het;Benzaldehyde;Adehydes, Acetals & Ketones;Iodine Compounds;Phenyls & Phenyl-Het;C7;Carbonyl Compounds
Mol File:26260-02-6.mol
2-IODOBENZALDEHYDE Structure
2-IODOBENZALDEHYDE Chemical Properties
Melting point 36-39 °C (lit.)
Boiling point 129 °C (14 mmHg)
density 1.8576 (estimate)
Fp >230 °F
storage temp. 2-8°C
solubility soluble in Methanol
form Low Melting Crystalline Mass or Powder
color White to light beige
Sensitive Light Sensitive
BRN 1927296
InChIInChI=1S/C7H5IO/c8-7-4-2-1-3-6(7)5-9/h1-5H
InChIKeyWWKKTHALZAYYAI-UHFFFAOYSA-N
SMILESC(=O)C1=CC=CC=C1I
CAS DataBase Reference26260-02-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
HazardClass IRRITANT, AIR SENSITIVE, KEEP COLD
HS Code 29130000
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
2-IODOBENZALDEHYDE Usage And Synthesis
Chemical Propertieswhite to light beige low melting crystalline
Uses2-Iodo-benzaldehyde is a very useful synthetic intermediate. It is halogenated Benzaldehyde (B119740) which is mainly used as a precursor to other organic compounds, such as pharmaceuticals, and plastic additives.
Uses2-Iodobenzaldehyde may be used as a reactant in the synthesis of the following heterocycles:
  • 2,3-diaryl-1-indenones
  • indolo[1,2-a]quinazolines
  • Baylis-Hillman (BH) adducts
It may also be used in preparing:
  • 5-phenylindazolo[3,2-b]quinazolin-7(5H)-one
  • 4-(3-iodophenyl)-2,2:6,2-terpyridine
  • fluoren-9-one
  • 2-formyl-3′-methoxybiphenyl
General Description2-Iodobenzaldehyde (o-iodobenzaldehyde) is a 2-halobenzaldehyde derivative. Its crystals belong to the orthorhombic crystal system and P212121 space group.
Synthesis
2-Formylbenzeneboronic acid

40138-16-7

2-IODOBENZALDEHYDE

26260-02-6

General procedure for the synthesis of 2-iodobenzaldehyde from 2-formylphenylboronic acid: 2-formylphenylboronic acid (0.067 g, 0.4 mmol), copper powder (0.0052 g, 0.08 mmol), (CF3)2CFI (0.178 g, 0.6 mmol) and DMF (2 mL) were added to a closed tube with a rubber stopper. The reaction mixture was stirred at room temperature for 24 hours. Upon completion of the reaction, the resulting suspension was poured into water and extracted with ethyl acetate. The organic layers were combined, dried with anhydrous Na2SO4 and concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography using petroleum ether/ethyl acetate (20:1, v/v) as eluent to give 0.086 g of 2-iodobenzaldehyde as a light yellow solid (0.35 mmol, 87% yield).

References[1] Journal of Fluorine Chemistry, 2016, vol. 189, p. 59 - 67
Tag:2-IODOBENZALDEHYDE(26260-02-6) Related Product Information
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