Molybdenum (VI) tetrachloride oxide

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Molybdenum (VI) tetrachloride oxide Basic information
Product Name:Molybdenum (VI) tetrachloride oxide
Synonyms:MOLYBDENUM(VI) OXYCHLORIDE;MOLYBDENUM OXYTETRACHLORIDE;Molybdenumtetrachlorideoxidemingreenpowder;Molybdenum(VI)tetrachlorideoxide,min.97%;Molybdenum (VI) tetrachloride oxide, Cl 55.3%;Molybdenum(VI) tetrachloride oxide, min. 97%;Molybdenum tetrachloride oxide;Molybdenum oxide chloride
CAS:13814-75-0
MF:Cl4MoO
MW:253.75
EINECS:
Product Categories:metal oxyhalide
Mol File:13814-75-0.mol
Molybdenum (VI) tetrachloride oxide Structure
Molybdenum (VI) tetrachloride oxide Chemical Properties
Melting point 100-101°C
storage temp. 2-8°C
form Powder
color green
Sensitive air sensitive, moisture sensitive, store cold
InChIInChI=1S/4ClH.Mo.O/h4*1H;;/q;;;;+4;/p-4
InChIKeyUYEGPKGLVUUIGD-UHFFFAOYSA-J
SMILES[Mo](Cl)(Cl)(Cl)(Cl)=O
CAS DataBase Reference13814-75-0
Safety Information
Hazard Codes Xi,C
Risk Statements 36/37/38-34
Safety Statements 26-37/39-45-36/37/39
RIDADR UN 3260 8/PG 3
WGK Germany 3
HS Code 2827499090
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsSkin Corr. 1B
MSDS Information
ProviderLanguage
SigmaAldrich English
Molybdenum (VI) tetrachloride oxide Usage And Synthesis
Chemical Propertiesgreen powder(s); sensitive to moisture; volatile at ordinary temp [KIR81] [STR93]
UsesMolybdenum(VI) tetrachloride oxide can be used:
  • To prepare a binary metal catalyst (MoOCl4-n-BuLi) for the living polymerization of various acetylenes.
  • As an oxidant in the aromatization of various Hantzsch-1,4-dihydropyridines.
  • As a molybdenum (Mo) precursor to prepare nafion-Mo composite material, which is used as a catalyst for the preparation of nitrones by reacting primary amines with aldehydes.

DefinitionChEBI: Tetrachloro(oxo)molybdenum is a molybdenum coordination entity.
reaction suitabilityreagent type: catalyst
core: molybdenum
Molybdenum (VI) tetrachloride oxide Preparation Products And Raw materials
Tag:Molybdenum (VI) tetrachloride oxide(13814-75-0) Related Product Information
Molybdenum(VI) dichloride dioxide MOLYBDENUM(V) CHLORIDE Rhodium(III) Chloride Sodium tungstate Ammonium molybdate tetrahydrate Molybdenum disulfide Molybdenum trioxide Titanium tetrachloride Cerium Nitrate Magnesium chloride Molybdenum carbide Zinc sulphate Barium sulfate Molybdenum (VI) tetrachloride oxide MOLYBDENUM (III) CHLORIDE Molybdenum MOLYBDENUM CHLORIDE molybdenum tetrachloride