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| | 1,2,4,5-Tetrazine, 3,6-bis(methylthio)- Basic information |
| Product Name: | 1,2,4,5-Tetrazine, 3,6-bis(methylthio)- | | Synonyms: | 3,6-bis(methylsulfanyl)-1,2,4,5-tetrazine;1,2,4,5-Tetrazine, 3,6-bis(methylthio)-;3,6-Bis(methylthio)-1,2,4,5-tetrazine >=95% (HPLC);Bis(methylsulfanyl)-1,2,4,5-tetrazine | | CAS: | 1672-34-0 | | MF: | C4H6N4S2 | | MW: | 174.25 | | EINECS: | | | Product Categories: | | | Mol File: | 1672-34-0.mol |  |
| | 1,2,4,5-Tetrazine, 3,6-bis(methylthio)- Chemical Properties |
| Melting point | 82-87 °C | | Boiling point | 370.1±25.0 °C(Predicted) | | density | 1.42±0.1 g/cm3(Predicted) | | storage temp. | -20°C | | pka | -1.01±0.10(Predicted) | | form | powder | | InChI | 1S/C4H6N4S2/c1-9-3-5-7-4(10-2)8-6-3/h1-2H3 | | InChIKey | ROUDTSAXQIBBFZ-UHFFFAOYSA-N | | SMILES | CSC1=NN=C(SC)N=N1 |
| WGK Germany | WGK 3 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | 1,2,4,5-Tetrazine, 3,6-bis(methylthio)- Usage And Synthesis |
| Uses | 3,6-Bis(methylthio)-1,2,4,5-tetrazine can be used as a versatile building block in the inverse elecron demand hetero Diels-Alder reactions. The Boger Research Group has reported this powerful approach in the synthesis of alkaloids.
It can also used to synthesize:
- Substituted indoles and indolines derivatives by sequential [4+2] cycloaddition reactions.
- 3-(Methylthio)-6-(4-morpholinyl)-1,2,4,5-tetrazine by aromatic nucleophilic substitution reaction.
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| | 1,2,4,5-Tetrazine, 3,6-bis(methylthio)- Preparation Products And Raw materials |
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