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| | 2-Benzylpyridine Basic information |
| | 2-Benzylpyridine Chemical Properties |
| Melting point | 8-10 °C (lit.) | | Boiling point | 276 °C (lit.) | | density | 1.054 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.579(lit.) | | Fp | 257 °F | | storage temp. | Store below +30°C. | | solubility | Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) | | pka | 5.13(at 25℃) | | form | liquid | | color | yellow | | Water Solubility | insoluble | | BRN | 115875 | | InChI | 1S/C12H11N/c1-2-6-11(7-3-1)10-12-8-4-5-9-13-12/h1-9H,10H2 | | InChIKey | PCFUWBOSXMKGIP-UHFFFAOYSA-N | | SMILES | C(c1ccccc1)c2ccccn2 | | LogP | 2.570 (est) | | CAS DataBase Reference | 101-82-6(CAS DataBase Reference) | | NIST Chemistry Reference | Pyridine, 2-(phenylmethyl)-(101-82-6) | | EPA Substance Registry System | Pyridine, 2-(phenylmethyl)- (101-82-6) |
| Hazard Codes | Xi,Xn | | Risk Statements | 36-36/37/38-22 | | Safety Statements | 26-37/39 | | RIDADR | 2810 | | WGK Germany | 3 | | RTECS | US2620000 | | TSCA | TSCA listed | | HS Code | 29333999 | | Storage Class | 10 - Combustible liquids | | Toxicity | LD50 scu-mus: 1500 mg/kg AEPPAE 227,129,55 |
| | 2-Benzylpyridine Usage And Synthesis |
| Chemical Properties | 2-Benzylpyridine is a clear yellow to brown liquid or pale straw-colored oily liquid. Poorly soluble
in water, soluble in alcohol and oils. Powerful green vegetable type odor with
considerable resemblance to the odor of raw
stringbeans (or “Haricots-verts”). The warm-herbaceous undertone is often accompanied
by traces of a protein-like terminal note, possibly impurity-odor. Moderate tenacity. | | Uses | 2-Benzylpyridine is a benzylpyridine with antifungal properties. 2-Benzylpyridine is also used as a chromogenic reagent for micro determination of Molybednum. | | Uses | 2-Benzylpyridine is used in organic synthesis. | | Synthesis Reference(s) | Journal of Heterocyclic Chemistry, 24, p. 1205, 1987 DOI: 10.1002/jhet.5570240453
Tetrahedron Letters, 24, p. 889, 1983 DOI: 10.1016/S0040-4039(00)81556-7 | | Safety Profile | Moderately toxic by subcutaneousroute. When heated to decomposition it emits toxicvapors of NOx. | | Purification Methods | Dry it with NaOH for several days, then distil it from CaO under reduced pressure, and redistil the middle fraction. [Beilstein 20/7 V 556.] |
| | 2-Benzylpyridine Preparation Products And Raw materials |
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