1-Benzyl-3-methylimidazolium hexafluorop

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1-Benzyl-3-methylimidazolium hexafluorop Basic information
Synthesis Application
Product Name:1-Benzyl-3-methylimidazolium hexafluorop
Synonyms:BzMIMPF6;1H-Imidazolium, 1-methyl-3-(phenylmethyl)-, hexafluorophosphate(1-);1-Benzyl-3-methyl-1H-imidazol-3-ium hexafluorophosphate(V);SKL1573;SKL1463;1-Benzyl-3-methylimidazolium hexafluorophosphate, ≥97.0%;1-BENZYL-3-METHYLIMIDAZOLIUM HEXAFLUOROP [BzMIm]PF6;1-Benzyl-3-methylimidazole hexafluorophosphate
CAS:433337-11-2
MF:C11H13N2.F6P
MW:318.2
EINECS:200-144-5
Product Categories:
Mol File:433337-11-2.mol
1-Benzyl-3-methylimidazolium hexafluorop Structure
1-Benzyl-3-methylimidazolium hexafluorop Chemical Properties
Melting point 130.6-131.7 °C
storage temp. Inert atmosphere,Room Temperature
form Solid
color White
Sensitive Moisture Sensitive
CAS DataBase Reference433337-11-2
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
3-10
HS Code 2933.29.4300
MSDS Information
1-Benzyl-3-methylimidazolium hexafluorop Usage And Synthesis
Synthesis

Synthetic route of 1-benzyl-3-methylimidazolium hexafluorophosphate

Benzyl bromide and methylimidazolium were added at a molar ratio of 1.1:1 to a round-bottom flask equipped with a magnetic stirrer, heating device, and condenser. The mixture was stirred and reacted at 60–90 °C for 8 h. After cooling, the supernatant was discarded, and the mixture was washed twice with ethyl acetate. The mixture was then cured in a refrigerator for 12 h. The cured product was dissolved in water and then subjected to ion exchange with ammonium hexafluorophosphate at a molar ratio of 1:1.2 at room temperature. After the exchange was completed, the product was filtered, washed with water and petroleum ether, and dried in a vacuum oven for later use.

Application1-Benzyl-3-methylimidazolium hexafluorophosphate is an ionic liquid. Ionic liquids possess unique solubility properties, allowing them to serve as green solvents to replace commonly used, environmentally harmful organic solvents. In certain reactions, they act as both solvents and co-catalysts, thereby promoting higher yields and better selectivity in many chemical reactions. Furthermore, the solubility of ionic liquids facilitates the separation of catalysts from products, enabling catalyst recycling.
1-Benzyl-3-methylimidazolium hexafluorop Preparation Products And Raw materials
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