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| | BORANE-N,N-DIETHYLANILINE COMPLEX Basic information |
| Product Name: | BORANE-N,N-DIETHYLANILINE COMPLEX | | Synonyms: | BORANE-N,N-DIETHYLANILINE;BORANE-N,N-DIETHYLANILINE COMPLEX;N,N-DIETHYLANILINE BORANE;n,n-diethylanilineborane,deanb;n-diethylbenzenamine)trihydro-((beta-4)-boro;(N,N-diethylaniline)trihydroboron;Borane-N,N-diethylaniline complex,97%;N, N diethylaniline borane complex | | CAS: | 13289-97-9 | | MF: | C10H18BN | | MW: | 163.07 | | EINECS: | 236-305-2 | | Product Categories: | B (Classes of Boron Compounds);Boranes;Reduction;Synthetic Organic Chemistry;Synthetic Reagents | | Mol File: | 13289-97-9.mol |  |
| | BORANE-N,N-DIETHYLANILINE COMPLEX Chemical Properties |
| Melting point | −30-−27 °C(lit.) | | density | 0.917 g/mL at 25 °C(lit.) | | refractive index | 1.5245-1.5265 | | Fp | 70 °F | | storage temp. | Refrigerator | | form | Liquid | | color | Clear colorless to yellow | | Water Solubility | MAY DECOMPOSE | | InChI | InChI=1S/C10H18BN/c1-3-12(11,4-2)10-8-6-5-7-9-10/h5-9H,3-4H2,1-2,11H3 | | InChIKey | YPWBYWNNJVSNPQ-UHFFFAOYSA-N | | SMILES | N(C1C=CC=CC=1)(CC)(CC)[B+3]([H-])([H-])[H-] | | CAS DataBase Reference | 13289-97-9(CAS DataBase Reference) | | EPA Substance Registry System | Boron, (N,N-diethylbenzenamine)trihydro-, (T-4)- (13289-97-9) |
| Risk Statements | 10-14-51/53-33-23/24/25-14/15 | | Safety Statements | 16-33-36/37/39-43-9-61-45-28A-8 | | RIDADR | UN 3398 4.3/PG 2 | | WGK Germany | 3 | | TSCA | TSCA listed | | HazardClass | 3.1 | | PackingGroup | II | | HS Code | 29299090 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Flam. Liq. 2
Water-react 2 |
| | BORANE-N,N-DIETHYLANILINE COMPLEX Usage And Synthesis |
| Chemical Properties | clear colorless to amber liquid | | Uses | Reactant for:
- Diastereoselective reduction of prochiral enone intermediates
- Borylation of aryl halides
- Reductions of ketones, acids, esters, amides, and nitriles
- Investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones
Reactant for synthesis of:
- Chromanol derivatives as CETP inhibitors for the treatment of cardiovascular disease
- Allylic alcohols via enantioselective reductions
- Pinacolboranes for one-pot synthesis of unsymmetrical biaryls
| | reaction suitability | reagent type: reductant |
| | BORANE-N,N-DIETHYLANILINE COMPLEX Preparation Products And Raw materials |
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