2-(Aminomethyl)-18-crown-6

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2-(Aminomethyl)-18-crown-6 Basic information
Product Name:2-(Aminomethyl)-18-crown-6
Synonyms:1,4,7,10,13,16-hexaoxacyclooctadecane-2-methanamine;2-AMinoMethyl-18-crown-6 95%;(1,4,7,10,13,16-Hexaoxacyclooctadecan-2-yl)methanamine;1-(1,4,7,10,13,16-hexaoxacyclooctadecan-2-yl)methanamine;2-(Aminomethyl)-18-crown-6
CAS:83585-61-9
MF:C13H27NO6
MW:293.36
EINECS:
Product Categories:
Mol File:83585-61-9.mol
2-(Aminomethyl)-18-crown-6 Structure
2-(Aminomethyl)-18-crown-6 Chemical Properties
Boiling point 135 °C/0.08 mmHg (lit.)
density 1.126 g/mL at 25 °C (lit.)
refractive index n20/D 1.479(lit.)
Fp 113 °C
pka9.11±0.29(Predicted)
form liquid
BRN 4184588
InChI1S/C13H27NO6/c14-11-13-12-19-8-7-17-4-3-15-1-2-16-5-6-18-9-10-20-13/h13H,1-12,14H2
InChIKeyBJUGHLWDFGGTGJ-UHFFFAOYSA-N
SMILESNCC1COCCOCCOCCOCCOCCO1
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
WGK Germany 3
Storage Class10 - Combustible liquids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
2-(Aminomethyl)-18-crown-6 Usage And Synthesis
Uses2-Aminomethyl-18-crown-6 (AM-18-C-6) can be used to prepare:
  • AM-18-C-6 bonded Merrifield peptide resin, which is used to study the absorption and the isotopic effect of magnesium.
  • Schiff base of gossypol with aminomethyl crown ether for complexation of monovalent cations.
  • Crown tagged triarylphosphine by reacting with triphenylphosphine carboxylic acid. These tagged triarylphosphine reagents are used in Mitsunobu and Heck reactions for the removal of phosphine derived by-products.
  • 1,16-hexadecanoyl-bis-(2-aminomethyl)-18-crown-6 (bola A-16), which is utilized as a vesicular carrier in a drug delivery system.

2-(Aminomethyl)-18-crown-6 Preparation Products And Raw materials
Tag:2-(Aminomethyl)-18-crown-6(83585-61-9) Related Product Information
15-Crown-5 2-[2-(3-aminopropoxy)ethoxy]ethanol 18-Crown-6 1-(2-Methyl-18-crown-6)-3-methylimidazolium hexafluorophosphate 2-(Aminomethyl)-18-crown-6 3-(2-Ethoxyethoxy)propylamine 1-Amino-3,6,9-trioxaundecanyl-11-ol