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Tri(propylene glycol) diacrylate

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Tri(propylene glycol) diacrylate manufacturers

Tri(propylene glycol) diacrylate Basic information
Preparation
Product Name:Tri(propylene glycol) diacrylate
Synonyms:TRPGDA;2-propenoicacid,(1-methyl-1,2-ethanediyl)bis(oxy(methyl-2,1-ethanediyl))es;2-Propenoicacid,(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)]ester;Photomer 4061;Tri(propylene glycol) diacrylate(TPGDA、TRPGDA);Tripropylene glycol diacrylate, 90%, mixture of isomers;Photomer 4061 G TF;Photomer 4061G
CAS:42978-66-5
MF:C15H24O6
MW:300.35
EINECS:256-032-2
Product Categories:Functional Monomer;Diacrylates & Dimethacrylates;Functional Materials;Reagent for High-Performance Polymer Research;42978-66-5
Mol File:42978-66-5.mol
Tri(propylene glycol) diacrylate Structure
Tri(propylene glycol) diacrylate Chemical Properties
Boiling point 361.58°C (rough estimate)
density 1.03 g/mL at 25 °C(lit.)
vapor density >1 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.45(lit.)
Fp >230 °F
storage temp. Amber Vial, Refrigerator, Under inert atmosphere
solubility Chloroform, Methanol (Slightly)
form Oil
color Colourless
Water Solubility 4g/L at 20℃
Stability:Light Sensitive
Cosmetics Ingredients FunctionsPLASTICISER
NAIL CONDITIONING
InChI1S/C15H24O6/c1-6-14(16)20-12(4)9-18-8-11(3)19-10-13(5)21-15(17)7-2/h6-7,11-13H,1-2,8-10H2,3-5H3
InChIKeyLJRSZGKUUZPHEB-UHFFFAOYSA-N
SMILESCC(COC(C)COC(=O)C=C)OCC(C)OC(=O)C=C
CAS DataBase Reference42978-66-5(CAS DataBase Reference)
EPA Substance Registry SystemTripropylene glycol diacrylate (42978-66-5)
Safety Information
Hazard Codes Xi,N
Risk Statements 36/37/38-43-51/53
Safety Statements 24-37-61
RIDADR UN 3082 9/PG 3
WGK Germany 2
RTECS AT4690000
TSCA TSCA listed
HazardClass 9
PackingGroup III
HS Code 29161290
Storage Class10 - Combustible liquids
Hazard ClassificationsAquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
Tri(propylene glycol) diacrylate Usage And Synthesis
Preparation

A direct esterification method for Tri(propylene glycol) diacrylate was employed to synthesize the product. Specifically, dipropylene glycol and C3H4O2 were reacted in a specific molar ratio with an acidic catalyst, a polymerization inhibitor, and a solvent at a controlled temperature. During the reaction, water generated was continuously removed from the reaction system through azeotropic extraction of the solvent and water. After the esterification reaction was complete, the acidic catalyst and residual C3H4O2 were removed from the reaction system by neutralization, and then the solvent was removed under vacuum to obtain the product.

DescriptionAs a cause of occupational contact dermatitis, tripropylene glycol diacrylate (TPGDA) was contained in dental resins, in UV-cured inks and in nail eosmetics.
UsesTripropylene glycol diacrylate is a diacrylate monomer for use in UV-curable flexographic and silk-screen inks, wood-finish varnishes, coatings on plastics, etc.
UsesTripropylene Glycol Diacrylate is a microparticle used to study continuous-flow lithography of high-throughput microparticle synthesis.
Flammability and ExplosibilityNon flammable
Toxics Screening LevelThe initial threshold screening level (ITSL) for tripropylene glycol diacrylate (TPGD) is 22 μg/m3 based on an annual averaging time.
Tri(propylene glycol) diacrylate Preparation Products And Raw materials
Tag:Tri(propylene glycol) diacrylate(42978-66-5) Related Product Information
Tripropylene glycol Ethylene glycol diacetate Methyl propiolate Oxybis(methyl-2,1-ethanediyl) diacrylate Poly(ethylene glycol) diacrylate Hexamethylene diacrylate Diethylene glycol diacrylate Dipropylene glycol 6-Benzylaminopurine 2-Methyl-2,4-pentanediol Propylene oxide 1,4-Butanediol Neopentyl glycol diacrylate Di(propylene glycol) dibenzoate 1-Methoxy-2-propyl acetate Ethylene glycol Propylene 2-Butoxyethanol