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| | 1-Octanesulfonyl Chloride Basic information |
| | 1-Octanesulfonyl Chloride Chemical Properties |
| Melting point | 14℃ | | Boiling point | 75 °C/0.03 mmHg (lit.) | | density | 1.087 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.460(lit.) | | Fp | >230 °F | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | clear liquid | | color | Colorless to Light red to Green | | Sensitive | Moisture Sensitive | | BRN | 1763921 | | InChI | InChI=1S/C8H17ClO2S/c1-2-3-4-5-6-7-8-12(9,10)11/h2-8H2,1H3 | | InChIKey | WIVNTNLDTMNDNO-UHFFFAOYSA-N | | SMILES | C(S(Cl)(=O)=O)CCCCCCC | | CAS DataBase Reference | 7795-95-1(CAS DataBase Reference) | | EPA Substance Registry System | 1-Octanesulfonyl chloride (7795-95-1) |
| Hazard Codes | C | | Risk Statements | 34-37 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 3265 8/PG 2 | | WGK Germany | 3 | | TSCA | TSCA listed | | HazardClass | 8 | | PackingGroup | II | | HS Code | 29049095 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Skin Corr. 1B |
| | 1-Octanesulfonyl Chloride Usage And Synthesis |
| Chemical Properties | clear colorless to slightly yellow liquid | | Uses | 1-Octanesulfonyl chloride is suitable for use in the preparation of 1-alkyl-3-methylimidazolium alkylsulfonates (ionic liquids). | | Synthesis | A mixture of 1-Mercaptooctane (1 mmol), 30 percent H2O2 (3 mmol, 0.3 mL), and TiCl4 (1 mmol, 0.11 mL) was stirred in CH3CN at 25 °C. A white solid (TiO2) immediately precipitated. After completion of the reaction as indicated by TLC, the mixture was quenched by adding H2O (10 mL), extracted with EtOAc (4 .x. 5 mL), and the extract was dried over anhydrous MgSO4. The filtrate was evaporated under a vacuum to afford the analytically pure product 1-Octanesulfonyl Chloride. | | References | [1] Journal of Organic Chemistry, 2009, vol. 74, # 24, p. 9287 - 9291
[2] Synlett, 2009, # 17, p. 2773 - 2776
[3] Synthesis, 2012, vol. 2012, # 2, p. 316 - 322
[4] Tetrahedron Letters, 2012, vol. 53, # 3, p. 354 - 358
[5] Green Chemistry, 2017, vol. 19, # 9, p. 2286 - 2295 |
| | 1-Octanesulfonyl Chloride Preparation Products And Raw materials |
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