(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol

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(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol Basic information
Product Name:(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol
Synonyms:(S,S)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL;(S,S)-(-)-1,2-DI(1-NAPTHYL)-1,2-ETHANEDIOL;1,2-Ethanediol, 1,2-di-1-naphthalenyl-, (1S,2S)-;(1S,2S)-1,2-di(naphthalen-1-yl)ethane-1,2-diol;(S,S)-(?)-1,2-Di(1-naphthyl)-1,2-ethanediol;(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol
CAS:229184-99-0
MF:C22H18O2
MW:314.38
EINECS:
Product Categories:organic building block;Chiral Building Blocks;Organic Building Blocks;Polyols
Mol File:229184-99-0.mol
(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol Structure
(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol Chemical Properties
Melting point 149-151 °C (lit.)
storage temp. Store at 0-8 °C
Optical Rotation[α]23/D 25°, c = 1 in chloroform
InChI1S/C22H18O2/c23-21(19-13-5-9-15-7-1-3-11-17(15)19)22(24)20-14-6-10-16-8-2-4-12-18(16)20/h1-14,21-24H/t21-,22-/m0/s1
InChIKeyMNRCSHSTIWDUPJ-VXKWHMMOSA-N
SMILESO[C@H]([C@@H](O)c1cccc2ccccc12)c3cccc4ccccc34
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol Usage And Synthesis
Uses(S, S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol can be used as:
  • A ligand in the asymmetric sulfoxidation of dihydrothienopyrimidine.
  • A reactant for the preparation of (2S,2′S)-[(1S,2S)-1,2-bis(naphthalen-1-yl)ethane-1,2-diyl] bis[2-(dimethylamino)propanoate], a chiral bisester ligand via condensation reaction with N,N-dimethylamino acid using aldol-Tishchenko condensation catalyst.
  • A reactant to synthesize diol-SnCl4 chiral Bronsted acid complex, which is employed as a catalyst in the allylboration of aldehydes.

(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol Preparation Products And Raw materials
Tag:(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol(229184-99-0) Related Product Information
(S,S)-(-)-1,2-Di(1-naphthyl)-1,2-ethanediol 1,2-Bis(1-naphthyl)ethane (+/-)-Hydrobenzoin (R)-1-(Naphthalen-1-yl)ethanol