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(R)-(+)-1-(4-Methoxyphenyl)ethylamine

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(R)-(+)-1-(4-Methoxyphenyl)ethylamine Basic information
Product Name:(R)-(+)-1-(4-Methoxyphenyl)ethylamine
Synonyms:(1R)-1-(4-methoxyphenyl)ethanamine;(R)-p-Methoxyphenylethylamine;Benzenemethanamine, 4-methoxy-.alpha.-methyl-, (.alpha.R)-;(1R)-1-(4-Methoxyphenyl)ethylamine;(R)-(+)-4-Methoxy-alpha-MethylbenzylaMine ChiPros(R), produced by BASF, 99%;R - the Methoxy phenethylaMine;(R)-(+)-4-Methoxy-;(R)-(+)-1-(4-Methoxyphenyl)ethylamine, 99%, ee 99+%
CAS:22038-86-4
MF:C9H13NO
MW:151.21
EINECS:606-907-3
Product Categories:API intermediates;Amines (Chiral);Chiral Building Blocks;Synthetic Organic Chemistry;Amines and Derivatives;CHIRAL CHEMICALS
Mol File:22038-86-4.mol
(R)-(+)-1-(4-Methoxyphenyl)ethylamine Structure
(R)-(+)-1-(4-Methoxyphenyl)ethylamine Chemical Properties
Melting point <-20°C
Boiling point 65°C 0,4mm
alpha 32 º (neat)
density 1.024 g/mL at 20 °C(lit.)
refractive index n20/D 1.533
Fp 65°C/0.38mm
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form liquid
pka9.29±0.10(Predicted)
AppearanceColorless to light yellow Liquid
Water Solubility Soluble in water (10g/L).
Sensitive Air Sensitive
BRN 2413029
InChIInChI=1/C9H13NO/c1-7(10)8-3-5-9(11-2)6-4-8/h3-7H,10H2,1-2H3/t7-/s3
InChIKeyJTDGKQNNPKXKII-SSDOTTSWSA-N
SMILES[C@@H](C1C=CC(OC)=CC=1)(N)C |&1:0,r|
CAS DataBase Reference22038-86-4(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34-22
Safety Statements 26-36/37/39-45
RIDADR UN 2735 8/PG 3
WGK Germany 3
F 10-34
HazardClass 8
PackingGroup III
HS Code 29222990
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsAcute Tox. 4 Oral
Aquatic Chronic 3
Eye Dam. 1
Skin Corr. 1B
Skin Sens. 1A
MSDS Information
(R)-(+)-1-(4-Methoxyphenyl)ethylamine Usage And Synthesis
Chemical PropertiesColorless liquid
Uses(R)-(+)-1-(4-Methoxyphenyl)ethylamine use in diastereo-and enantioselective Michael addition reactions. Thiazoles has been prepared from (R)-(+)-1-(4-Methoxyphenyl)ethylamine.
Uses(R)-(+)-4-Methoxy-α-methylbenzylamine can be used as a reactant to prepare:
  • Enantiopure stereoisomers of hemicryptophanes, which are used for the recognition of glucopyranosides.
  • Bicyclic Geissman-Waiss lactone via intramolecular ring-closure reaction of the diastereomeric mixture of sulfonium salts.
  • N-[(1R)-1-(4-Methoxyphenyl)ethyl]-N′-methylthiourea by reacting with methyl isothiocyanate.

(R)-(+)-1-(4-Methoxyphenyl)ethylamine Preparation Products And Raw materials
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