| Company Name: |
Accela ChemBio Inc. |
| Tel: |
+1-858-6993322 +86-18019713315 |
| Email: |
info@accelachem.com |
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| | Methyl 3-nitropropionate 97 Basic information |
| Product Name: | Methyl 3-nitropropionate 97 | | Synonyms: | METHYL 3-NITROPROPIONATE 97%;Methyl 3-nitropropionate;Propanoic acid, 3-nitro-, methyl ester;2,4,7-Tribromo methyl benzoate;Methyl 3-Nitropropanoate;Methyl 3-nitropropionate 97 | | CAS: | 20497-95-4 | | MF: | C4H7NO4 | | MW: | 133.1 | | EINECS: | | | Product Categories: | | | Mol File: | 20497-95-4.mol |  |
| | Methyl 3-nitropropionate 97 Chemical Properties |
| Boiling point | 68 °C/1 mmHg(lit.) | | density | 1.249 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.4350(lit.) | | Fp | 110 °C | | pka | 7.67±0.29(Predicted) |
| | Methyl 3-nitropropionate 97 Usage And Synthesis |
| Uses |
Methyl 3-Nitropropanoate is used to nitroaldol additions, condensation reactions, and Michael additions involving the NO2-substituted
carbon; the α-carbonyl carbon in dilithionitronate enolates of the esters undergoes alkylations, double
alkylations, and aldol and Michael additions; elimination of HNO2 from the products gives α,β-
unsaturated esters with substituents in either the β- or the α-position, thus making the reagent a
synthetic equivalent of acrylate anions with d3 or d2 reactivity; precursor to nitrile oxide for [3 + 2]
cycloadditions; 3-nitropropanoyl chloride can be used for enolate acylation and five-membered ring
annulation.
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| | Methyl 3-nitropropionate 97 Preparation Products And Raw materials |
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